Fast Optical Healing of Crystalline Polymers Enabled by Gold Nanoparticles

A general method for very fast and efficient optical healing of crystalline polymers is reported. By loading a very small amount of gold nanoparticles (AuNPs) in either poly(ethylene oxide) (T_m ≈ 63 °C) or low‐density polyethylene (T_m ≈ 103 °C), the heat released upon surface plasmon resonance (SPR) absorption of 532 nm light by AuNPs can melt crystallites in the interfacial region of two polymer pieces brought into contact; and the subsequent recrystallization of polymer chains on cooling merges the two pieces into one. The fracture strength of such repaired sample can reach the level of the undamaged polymer after 10 s laser exposure. Moreover, in addition to an ability of long‐distance remote and spatially selective healing, the optical method also works for polymer samples immersed in water.

     

Modeling and analysis of dynamic characteristics of multi-stable waterbomb origami base

Origami has recently received wide attention, and the study on its dynamic characteristics remains a nascent field. The waterbomb origami is a common subtype of origami, and its base structure is treated as a bi-stable configuration in the literature. The systematical framework for modeling, simulation and dynamic analysis of the vibration for the waterbomb origami base is established in this paper. In the presented model, the motion of the waterbomb origami base is divided into two working patterns according to its geometric characteristic. The nonlinear governing equation of motion of the waterbomb origami base is formulated based on the Lagrange’s equation. The base’s free and forced responses can be calculated by using the fourth-order Runge–Kutta method. The developed model is validated by the results predicted by the simulation in ADAMS. With the developed theoretical framework, the base’s vertical effective stiffness and natural frequency of its linearized system are discussed to reveal their programmability with respect to the base’s structure and design parameters. Remarkably, the bifurcations of its equilibria, including the pitchfork, transcritical and (special) saddle-node bifurcations, are analyzed. Unlike the bi-stable configuration reported in the literature, the mono- and tri-stable configurations can also be realized by the base due to gravity. Furthermore, the complex nonlinear dynamic behaviors, including chaos, are revealed.

     

基于ZigBee的低延时PDA网络系统设计与实现

传统的自助信息服务系统（PDA）终端平台设备只具有简单的读写功能,网络互动能力较差,在文件传输中出现较大的数据流时会造成明显的网络延时;设计并实现了基于ZigBee网络的终端PDA平台系统设计;在平台设计中,引入了主从CPU轮流方式,分担设备交互中产生的海量数据流,在外围电路中,设计了专用的SD存储卡,便于数据移植;在原有的平台无线传输模块中,进行了链路升级,采用分级路由机制,有效降低数据包的路由延时。并以教学PDA为例进行开发与试验,系统测试表明：文章设计的自助信息服务系统PDA网络下行发送数据在10 ms可以完成,误码率为0001%,上行发送数据成功率高达997%;证明该系统具有稳定的网络性能与实用性;具有较高的网络稳定性和很强的实用价值。     

Hinged bis-porphyrin scaffolds I. The synthesis of a new porphyrin diene and its role in constructing hinged porphyrin dyads and cavity systems

Norbornene building BLOCKs formed by the reaction of porphyrin 1,3-dienes with norbornadiene or dimethyl tricyclo[4.2.1.0^2,5]nona-2,7-diene-3,4-dicarboxylate were coupled with an ester-activated cyclobutene epoxide BLOCK to afford the first examples of hinged porphyrin-spacer-acceptor dyads. Similar dual coupling with a bis-(cyclobutene epoxide) formed doubly hinged POR-spacer-POR scaffolds separated by up to 16σ-bonds. The ability of the doubly hinged ZnPOR-16σ-ZnPOR scaffold to adopt cavity-shaped conformations was indicated by semiempirical AM1 calculations of these conformationally flexible bis-porphyrin scaffolds.     

Flanking Sequence Determination and Event Specific Detection of Transgenic Wheat B72-8-11b Strain

Exogenous fragment sequence and flanking sequence between exogenous fragment and recombinant chromosome of transgenic wheat B72-8-11b were successfully acquired through PCR amplification with cross-matched primers from exogenous genes. Newly acquired exogenous fragment covered the full-length sequence of transformed genes such as transformed plasmid and corresponding functional genes including marker uidA, promoter ubiquitin, lacZ, 1Dx5, and part of sequence of the wheat genome. A specific PCR detection method for transgenic wheat B72-8-11b strain was established on the basis of primers designed according to flanking sequence. The designed primers revealed specific amplification of 132 bp product of transgenic wheat B72-8-11b strain. This method is characteristics of high specificity, high reproducibility, rapid identification, and excellent accuracy for the identification of transgenic wheat B72-8-11b strain.     

改性消石灰吸收剂用于干法脱除HCI的研究

特定浓度的NaOH、Na     

L3实验测量τ寿命的拟合方法及其误差讨论

对测量τ寿命的碰撞参数法中碰撞参数的符号作了研究后,把碰撞参数为负值的几率放入拟合公式进行L3实验数据的τ寿命拟合,并利用L3结构特别的中心径迹室研究了主要由漂移速度和零时间刻度产生的τ寿命测量系统误差.     

基于小波变换在线结构损伤检测分析研究

传统的傅立叶变换只能确定一个函数奇异性的整体性质,而难以确定奇异点在空间的位置及分布情况,小波变换具有空间局部化性质,利用小波变换来分析信号的奇异性及奇异性位置和奇异度的大小是比较有效的,在结构发生损伤时,结构的刚度发生了变化,因此结构动力响应的在线监测信号相应的发生了间断点,由于小波分析具有刻划信号局部特征的作用,通过对结构响应进行小波分解以后可以确定结构是否出现损伤以及确定损伤发生的时刻。     

Green Synthesis of 2‐Substituted Imidazolines using Hydrogen Peroxide Catalyzed by Tungstophosphoric Acid and Tetrabutylammonium Bromide in Water

Various 2‐substituted imidazolines were constructed from aromatic aldehydes with ethylenediamine using hydrogen peroxide as an oxidant in water. Tungstophosphoric acid (HPW) was found to be active for this transformation due to its ubiquitous catalytic and oxidative nature, and further combination of tetrabutylammonium bromide (TBAB) made this transformation more efficient and attractive. It was found that the yields of the corresponding 2‐substituted imidazolines were markedly influenced by the position and nature of the substituents on the phenyl ring. A plausible mechanism was also proposed to clarify this catalytic oxidative system.     

Polymerization rate and mechanism of ultrasonically initiated emulsion polymerization of n-butyl acrylate

The factors affecting the induction period and polymerization rate in ultrasonically initiated emulsion polymerization of n-butyl acrylate (BA) were investigated. The induction period takes only an instant in ultrasonically initiated emulsion polymerization of BA without any added initiator by enhancing the N2 flow rate. Increasing temperature, power output and SDS concentration, decreasing the monomer concentration results in further decreasing induction period and enhanced polymerization rate. Under optimized reaction conditions the conversion of BA reaches 92% in 11 min. The polymerization rate can be controlled by varying reaction parameters. The apparatus of ultrasonically initiated semi-continuous and continuous emulsion polymerization were set up and the feasibility was first studied. Based on the experimental results, a free radical polymerization mechanism for ultrasonically initiated emulsion polymerization was proposed, including the sources of the radicals, the process of radical formation, the locus of polymerization and the polymerization process. Compared with conventional emulsion polymerization, where the radicals come from thermal decomposition of a chemical initiator, ultrasonically initiated emulsion polymerization has attractive features such as no need for a chemical initiator, lower reaction temperature, faster polymerization rate, and higher molecular weight of the polymer prepared.