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101.
Dr. Alexey S. Kiryutin Dr. Grit Sauer Dr. Daniel Tietze Martin Brodrecht Stephan Knecht Prof. Dr. Alexandra V. Yurkovskaya Prof. Dr. Konstantin L. Ivanov Dr. Olga Avrutina Prof. Dr. Harald Kolmar Prof. Dr. Gerd Buntkowsky 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(16):4025-4030
Two-dimensional NMR spectroscopy is one of the most important spectroscopic tools for the investigation of biological macromolecules. However, due to the low sensitivity of NMR spectroscopy, it takes usually from several minutes to many hours to record such spectra. Here, the possibility of detecting a bioactive derivative of the sunflower trypsin inhibitor-1 (SFTI-1), a tetradecapeptide, by combining parahydrogen-induced polarization (PHIP) and ultrafast 2D NMR spectroscopy is shown. The PHIP activity of the inhibitor was achieved by labeling with O-propargyl-l -tyrosine. In 1D PHIP experiments a signal enhancement of a factor of approximately 1200 compared to standard NMR was found. This enhancement permits measurement of 2D NMR correlation spectra of low-concentrated SFTI-1 in less than 10 seconds, employing ultrafast single-scan 2D NMR detection. As experimental examples PHIP-assisted ultrafast single-scan TOCSY spectra of SFTI-1 are shown. 相似文献
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Pim R. Linnebank Stephan Falcão Ferreira Alexander M. Kluwer Prof. Dr. Joost N. H. Reek 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(37):8214-8219
Regioselective catalytic transformations using supramolecular directing groups are increasingly popular as it allows for control over challenging reactions that may otherwise be impossible. In most examples the reactive group and the directing group are close to each other and/or the linker between the directing group is very rigid. Achieving control over the regioselectivity using a remote directing group with a flexible linker is significantly more challenging due to the large conformational freedom of such substrates. Herein, we report the redesign of a supramolecular Rh–bisphosphite hydroformylation catalyst containing a neutral carboxylate receptor (DIM pocket) with a larger distance between the phosphite metal binding moieties and the DIM pocket. For the first time regioselective conversion of internal and terminal alkenes containing a remote carboxylate directing group is demonstrated. For carboxylate substrates that possess an internal double bond at the Δ-9 position regioselectivity is observed. As such, the catalyst was used to hydroformylate natural monounsaturated fatty acids (MUFAs) in a regioselective fashion, forming of an excess of the 10-formyl product (10-formyl/9-formyl product ratio of 2.51), which is the first report of a regioselective hydroformylation reaction of such substrates. 相似文献
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Stieghorst Christian Hampel Gabriele Karches Barbara Krenckel Patricia Kudějová Petra Plonka Christian Révay Zsolt Riepe Stephan Welter Katharina Wiehl Norbert 《Journal of Radioanalytical and Nuclear Chemistry》2018,317(1):307-313
Journal of Radioanalytical and Nuclear Chemistry - For the optimization of the manufacturing process of multicrystalline silicon (mc-Si) for solar cells in order to reduce energy consumption and... 相似文献
107.
The Reductive Dehydration of Cellulose by Solid/Gas Reaction with TiCl4 at Low Temperature: A Cheap,Simple, and Green Process for Preparing Anatase Nanoplates and TiO2/C Composites
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Sandrine Plumejeau Dr. Matthieu Rivallin Prof. Stephan Brosillon Prof. André Ayral Dr. Laurent Heux Prof. Bruno Boury 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(48):17262-17268
Metal oxides and metal oxide/carbon composites are entering the development of new technologies and should therefore to be prepared by sustainable chemistry processes. Therefore, a new aspect of the reactivity of cellulose is presented through its solid/gas reaction with vapour of titanium(IV) chloride in anhydrous conditions at low temperature (80 °C). This reaction leads to two transformations both for cellulose and titanium(IV) chloride. A reductive dehydration of cellulose is seen at the lowest temperature ever reported and results in the formation of a carbonaceous fibrous solid as the only carbon‐containing product. Simultaneously, the in situ generation of water leads to the formation of titanium dioxide with an unexpected nanoplate morphology (ca. 50 nm thickness) and a high photocatalytic activity. We present the evidence showing the evolution of the cellulose and the TiO2 nanostructure formation, along with its photocatalytic activity. This low‐temperature process avoids any other reagents and is among the greenest processes for the preparation of anatase and also for TiO2/carbon composites. The anisotropic morphology of TiO2 questions the role of the cellulose on the growing process of these nanoparticles. 相似文献
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We present preliminary results on the Stark effect of the hyperfine levels of the molecular ion HD+. 相似文献
109.
Gerhard Gompper Clemens Bechinger Stephan Herminghaus Rolf Isele-Holder U. Benjamin Kaupp Hartmut Löwen Holger Stark Roland G. Winkler 《The European physical journal. Special topics》2016,225(11-12):2061-2064
Locomotion of autonomous microswimmers is a fascinating field at the cutting edge of science. It combines the biophysics of self-propulsion via motor proteins, artificial propulsion mechanisms, swimming strategies at low Reynolds numbers, the hydrodynamic interaction of swimmers, and the collective motion and synchronisation of large numbers of agents. The articles of this Special Issue are based on the lecture notes of an international summer school, which was organized by the DFG Priority Programme 1726 “Microswimmers – From Single Particle Motion to Collective Behaviour” in the fall of 2015. The minireviews provide a broad overview of the field, covering both elementary and advanced material, as well as selected areas from current research. 相似文献
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