Supraleitung in Seltenerdmetall-Carbidhalogeniden des Typs SE2X2C2

Superconductivity in Rare Earth Metal Carbide Halides of the Type SE₂X₂C₂ The metallic nature of the carbide halides Y₂X₂C₂ is due to Y? C covalency. The superconductivity of the compounds is attributed to a pairwise attraction of conduction electrons by C₂-π* states at the Fermi level. The hypothesis is followed by experiments and band structure calculations. – Neutron powder diffraction reveals d(C? C) = 128(1) pm for Y₂Br₂C₂. X-ray single crystal investigations on Y₂Br₂C₂ and Y₂I_1.5Br_0.5C₂ show a characteristic variation of the coordination of the C₂ unit. Systematic changes of the average halide radius in Y₂(X,X′)₂C₂ (X,X′ = Br, Cl I, Cl and I, Br) lead to a monotonic increase of T_c = 2.3 K (X = Cl) via T_c = 5.05 K (X = Br) to a maximum T_c = 11.2 K for Y₂I_1.6Br_0.4C₂. No isotope effect for ¹²C/¹³C could be detected. Photoelectron spectra of Y₂Br₂C₂ (excitation energies between 40 and 140 eV) are compared with the results of band structure calculations (LMTO, E.H.). The electronic structure reveals two bands crossing the Fermi level. One of them has C₂-π*-Y-d_xz,yz character and exhibits a saddle-point at E_F. The other intersects the Fermi level with large dispersion and has exclusively Y-d character at the crossing point. The results are discussed with respect to theoretical models (van Hove singularity, local pairs and itinerant electrons).     

Cation mobility upon adsorption of methanol in NaY faujasite type zeolite: A molecular dynamics study compared to dielectric relaxation experiments

Molecular Dynamics simulations have been carried out to address the question of cation migration upon adsorption of methanol in NaY Faujasite system as a function of the loading. It has been shown that at low and intermediate loadings, SII cations can migrate toward the center of the supercage due strong interaction with the adsorbates, followed by hopping of SI' cations from the sodalite cage into the supercage to fill vacant SII sites. SI cations mainly remain trapped in their initial sites whatever the loading. At higher loading, only limited motion is observed for SII cations due to steric effects induced by the adsorbates within the supercage. These simulated results are in good agreement with those extracted by Complex Impedance Spectroscopy measurements, which provided the evolution of the number of extraframework cations in the different crystallographic sites as a function of the treatment temperature.     

Substitutionen und insertionen an stannylierten inethern

Stannylethynyl ethers $\text{1}$ react with acyl halides or some elemental halides under substitution of the stannyl group; the carbonyl group of ketenes insert into the single bond between the acetylenic carbon atom and the stannyl group.     

Thermodynamic properties of the superconducting state in YC2

We characterise the superconducting state of the binary carbide YC₂ by means of magnetisation and specific heat measurements. The thermodynamic properties reveal weak coupling superconductivity close to the type I limit (κ_GL ≈ 0.8). The specific heat data in the superconducting state, as well as the¹²C/¹³C-isotope shift are in excellent agreement with weak coupling BCS predictions.