亚大气压六相交流电弧等离子体射流特性研究:实验测量

以临近空间高超声速飞行器以及航天器再入大气环境飞行过程"黑障"问题的研究为背景,进行了多相交流电弧放电实验装置的物理设计,建立了六相交流电弧等离子体实验平台(MPX-2015),在背景压力为500 Pa的亚大气压条件下获得了最大直径和长度分别达到14.0 cm和60.0 cm的等离子体射流.研究了工作气体流量、真空腔压强、电极间距以及弧电流等因素对等离子体自由射流和冲击射流特性的影响规律.结果表明:在实验参数范围内,真空腔压强对等离子体的射流特性影响最为显著,等离子体自由射流的长度和直径以及冲击钝体条件下的鞘套有效工作长度和厚度均随着压强的降低而增大;提高沿电极环缝注入的工作气体流量或弧电流亦有利于等离子体鞘套尺寸的增加.上述工作有助于进一步开展临近空间飞行器与其周围复杂介质环境间复杂的气动热效应和"黑障"问题的研究.     

四角晶相HfO2(001)表面原子和电子结构研究

采用基于第一性原理的密度泛函理论研究了四角晶相二氧化铪(t-HfO₂)体相及 其(001)表面的原子几何与电子结构.理论计算结果表明，t-HfO₂(001)表面不会 产生重构现象.与体相电子结构相比, t-HfO₂(001)表面态密度明显高于体相态 密度.其次，表面原子的态密度更靠近费米能级(E_F)，价带往低能量处移动，并 有表面态产生.计算结果表明了t-HfO₂表面禁带宽度明显低于体相的禁带宽度. t-HfO₂(001)的表面态产生以及表面禁带宽度减小是由于Hf原子与O原子的配位 数减少，表面原子周围的环境发生变化而引起的. 关键词： 密度泛函理论 2(001)')" href="#">t-HfO₂(001) 表面电子结构     

压电复合材料层合板自适应结构的振动控制

本文针对板壳型自适应结构,研究了压电材料作为作动器的自适应结构的振动控制。利用四节点压电复合材料层合板单元进行自适应结构的有限元动力分析;采用模态控制方法,将结构的各阶模态的阻尼比作为控制目标,并以此计算出各压电片的控制电压,达到控制结构振动的目的。算例给出了数值计算的结果。     

Coral reef-like polyanaline nanotubes prepared by a reactive template of manganese oxide for supercapacitor electrode

Coral reef-like PANI nanotubes composed of nanopaticles were successfully synthesized by a reactive template of manganese oxide.The structure was characterized by using SEM,TEM,and FT-IR,and the supercapacitive behaviors of these nanotubes were investigated with cyclic voltammetry（CV）,and charge-discharge tests,respectively.A maximum specific capacitance of 533 F/g could be achieved in 1mol/L aqueous H₂SO₄ with the potential range of -0.2 to 0.8 V（vs.the saturated calomel electrode） in a half-cell setup configuration for PANI electrode,suggesting its potential application in the electrode material for electrochemical capacitors.     

相位修正的耦合模理论用于计算光纤Bragg光栅法布里-珀罗腔透射谱

基于光纤Bragg光栅(FBG)反射复振幅相移对FBG法布里-珀罗腔透射谱的影响,分析了传统耦合模理论计算均匀FBG反射复振幅相移产生误差的原因.引入折射率分布初始相位参数描述FBG折射率分布纵向的微小偏移,用真实的反透射系数代替简明形式的反透射系数,对传统耦合模理论进行了修正,增加了与折射率分布初始相位参数有关而与波长无关的相位因子.在此基础上进一步对计算非均匀FBG的传输矩阵法的相位进行了修正.修正后的快速计算结果用于FBG法布里-珀罗腔透射谱的计算,可反映折射率分布初始相位参数对透射峰波长位置的影响,与Rouard 算法及实验值均有较好的一致性. 关键词： 光纤Bragg 光栅 法布里-珀罗腔 耦合模理论     

Cytotoxic and NF-κB inhibitory sesquiterpene lactones from Piptocoma rufescens

Six new (1-6) and eight known germacranolide-type sesquiterpene lactones, along with several known phenylpropanol coumarates and methylated flavonoids, were isolated from the leaves of Piptocoma rufescens, collected in the Dominican Republic. The new compounds were identified by analysis of their spectroscopic data, with the molecular structure of 3 being established by single-crystal X-ray diffraction. The absolute configurations of the sesquiterpene lactones isolated were determined from their CD and NOESY NMR spectra, together with the analysis of Mosher ester reactions. Bioassay screening results showed the majority of the sesquiterpene lactones isolated (1-13) to be highly cytotoxic toward the HT-29 human colon cancer cell line, with the most potent compound being 15-deoxygoyazensolide (10, IC(50), 0.26 μM). In addition, several of the sesquiterpene lactones exhibited NF-κB (p65) inhibitory activity.     

A Germanate Compound Constructed from Dissymmetric Ge7 Chains and Metal Complexes

Abstract. A novel germanate compound, |[Ni(dien)₂]₃(H₂O)₃|[Ge₇O₁₃F₅]₂(designated JU‐85, dien = diethylenetriamine), was solvothermally synthesized. The structure of JU‐85 was determined by single‐crystal X‐ray diffraction and further characterized by powder X‐ray diffraction, inductively coupled plasma, infrared spectroscopy, elemental analysis, and thermogravimetric analysis. JU‐85 has dissymmetric chains constructed from diagonally linked Ge₇ building units and various Ni(dien)₂²⁺ complexes formed in situ during the synthesis. Compared with its structural analogue, FJ‐6, JU‐85 contains less complex cations and different host‐guest assembly. Besides the diagonal linkage in JU‐85, other dissymmetric linkages of Ge₇ building units were enumerated, which could be used as the stereogenic centers for the design of novel chiral germanate compounds.     

LC Coupled with TOFMS for Metabonomics Study of Mini-pigs with Atherosclerosis

In this study, serum metabolic profiles of mini-pigs with atherosclerosis (AS) were analyzed by LC–TOFMS. Partial least-squares to latent structure-discriminant analysis and orthogonal projection to latent structure-discriminant analysis were used for group differentiation and selection of potential biomarkers. The mini-pig disease models were constructed by feeding a high-fat diet and inducing coronary injury, in accordance with the mechanism of AS pathogenesis. To characterize the development of AS, serum samples were collected and analyzed at two time points (two and ten weeks). Separate distinct clustering of results from normal and model mini-pigs could be observed for both the two and ten-week samples. With the development of AS, the metabolism of the model mini-pigs was more substantially disturbed. Major metabolites contributing to the discrimination were fatty acids, lysophosphatidylcholines, and bile acids. These potential biomarkers are related with inflammation, oxidative stress, and abnormal lipid and energy metabolism.

     

(E)-2-Benzylidenebenzocyclanones: Part VII. Investigation of the conjugation reaction of two cytotoxic cyclic chalcone analogues with glutathione: an HPLC–MS study

Abstract  

The non-enzyme-catalyzed reaction of reduced glutathione (GSH) with two tumor cell cytotoxic cyclic chalcone analogues was investigated by reversed-phase high-performance liquid chromatography (RP-HPLC). HPLC analysis of the reaction mixtures indicated the formation of two diastereomeric chalcone–GSH adducts in each case, whose structural assignments were supported by MALDI-TOF-MS and HPLC–MS with electrospray ionization (ESI) measurements. Such reactivity accounts for the previously observed effect of the two cyclic chalcone analogues on the in vivo cellular thiol level of Jurkat T cells.