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81.
82.
M Mayer R Heikkinen T Omtoft 《Journal of the International Federation of Clinical Chemistry》1996,8(1):20-21
Laboratory cost management deals with the economical use of laboratory resources such as capital, equipment and manpower. Cost analysis is a tool for cost management, by means of which the laboratory manager can properly set priorities, choose appropriate test procedures, set personnel policies and make better investments of his resources. This article sets out some important aspects of cost analysis, such as the construction of cost curves, the factors that enter into cost analysis, the context in which cost analysis is used, and the limitations of this type of analysis. 相似文献
83.
Koskela H Kilpeläinen I Heikkinen S 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2004,170(1):121-126
An improvement of the GBIRD-filter is presented. The current approach utilizes Carr-Purcell-Meiboom-Gill type pulse train during the BIRD delay. The method enables recording of purely absorptive 1D spectrum using only one isotope editing element. In the current method, the parent signal leakage due to JHH evolution during the BIRD delay is considerably smaller than in the conventional approach. As a consequence, the t1-noise is smaller also in 2D applications, such as GBIRD-filtered HSQC. 相似文献
84.
The effect of ion acoustic harmonic production on stimulated Brillouin scattering is studied by solving numerically the coupled wave equations. Time and space dependent model includes the detuning and linear damping of the ion harmonic cascade and the mismatch due to density gradient. Several new interesting aspects in the behaviour of stimulated Brillouin scattering are discovered. 相似文献
85.
86.
Heikkinen S Kilpeläinen I 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2001,151(2):314-319
A three-dimensional approach for measuring 15N relaxation times is described. Instead of selecting particular values for the relaxation period, in the proposed method the relaxation period is incremented periodically in order to create a 3D spectrum. This additional frequency domain of the transformed spectrum contains the relaxation time information in the T1 and T2 linewidths, and thus the longitudinal and transverse 15N relaxation times can be measured without determination of 2D cross peak volumes/intensities and subsequent curve fitting procedures. 相似文献
87.
Heikkinen S Aitio H Permi P Folmer R Lappalainen K Kilpeläinen I 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1999,137(1):243-246
A new method for the measurement of homonuclear 3J(HNHalpha) coupling constants in 15N-labeled small proteins is described. The method is based on a modified sensitivity enhanced HSQC experiment, where the 3J(HNHalpha) couplings are multiplied in the f1-dimension. The J-multiplication of homonuclear 3J(HNHalpha) couplings is based on simultaneous incrementation of 15N chemical shift and homonuclear coupling evolution periods. The time increment for the homonuclear coupling evolution period is chosen to be a suitable multiple (2N x t1) of the corresponding increment for 15N-shift evolution. This results in the splitting of the HSQC correlation in the f1-dimension by 2N x 3J(HNHalpha). Because the pulse sequence has good sensitivity and water suppression properties, it is particularly useful for natural abundance samples. 相似文献
88.
Harri Koskela Outi Heikkil? Ilkka Kilpel?inen Sami Heikkinen 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2010,202(1):24-33
The finite RF power available on carbon channel in proton–carbon correlation experiments leads to non-uniform cross peak intensity response across carbon chemical shift range. Several classes of broadband pulses are available that alleviate this problem. Adiabatic pulses provide an excellent magnetization inversion over a large bandwidth, and very recently, novel phase-modulated pulses have been proposed that perform 90° and 180° magnetization rotations with good offset tolerance. Here, we present a study how these broadband pulses (adiabatic and phase-modulated) can improve quantitative application of the heteronuclear single quantum coherence (HSQC) experiment on high magnetic field strength NMR spectrometers. Theoretical and experimental examinations of the quantitative, offset-compensated, CPMG-adjusted HSQC (Q-OCCAHSQC) experiment are presented. The proposed experiment offers a formidable improvement to the offset performance; 13C offset-dependent standard deviation of the peak intensity was below 6% in range of ±20 kHz. This covers the carbon chemical shift range of 150 ppm, which contains the protonated carbons excluding the aldehydes, for 22.3 T NMR magnets. A demonstration of the quantitative analysis of a fasting blood plasma sample obtained from a healthy volunteer is given. 相似文献