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61.
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Zhou SZ Sey M De Clercq PJ Milanesio M Viterbo D 《Angewandte Chemie (International ed. in English)》2000,39(16):2861-2863
63.
On the Mechanism of the Reactivity of 1,3‐Dialkylimidazolium Salts under Basic to Acidic Conditions: A Combined Kinetic and Computational Study 下载免费PDF全文
M. Sc. Daniel Rico del Cerro Prof. Raúl Mera‐Adasme Dr. Alistair W. T. King Dr. Jesus E. Perea‐Buceta Dr. Sami Heikkinen Prof. Tapio Hase Prof. Dage Sundholm Prof. Kristiina Wähälä 《Angewandte Chemie (International ed. in English)》2018,57(36):11613-11617
Comprehensive spectroscopic kinetic studies illustrate an alternative mechanism for the traditional free‐carbene intermediated H/D exchange reaction of 1,3‐dialkylimidazolium salts under neutral (D2O) and acidic conditions (DCl/D2O 35 wt % solution). The deuteration of high purity [bmim]Cl in D2O is studied at different temperatures, in absence of catalyst or impurities, to yield an activation energy. DFT transition‐state modelling, of a small water cluster and [bmim] cation, also yields an activation energy which strongly supports the proposed mechanism. The presence of basic impurities are shown to significantly enhance the exchange reaction, which brings into question the need for further analysis of technical purities of ionic liquids and the implications for a wide range of chemical reactions in such media. 相似文献
64.
Heikkinen S Toikka MM Karhunen PT Kilpeläinen IA 《Journal of the American Chemical Society》2003,125(14):4362-4367
A quantitative method to record (1)H-(13)C correlation NMR spectra (Q-HSQC) is presented. The suppression of (1)J(CH)-dependence is achieved by modulating the polarization transfer delays of HSQC. In addition, the effect of homonuclear couplings, as well as relaxation during the pulse sequence are discussed. We developed the Q-HSQC approach for the quantitative analysis of wood lignin, a complex polymer where it has been difficult to obtain reliable data on the relative amounts of different structural units. The current method is applicable to a variety of complex mixtures, where normal 1D (1)H- and (13)C-NMR methods fail. 相似文献
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Calderbank AR; Cameron PJ; Kantor WM; Seidel JJ 《Proceedings London Mathematical Society》1997,75(2):436-480
When m is odd, spreads in an orthogonal vector space of type+(2m + 2,2) are related to binary Kerdock codes and extremalline-sets in 2m + 1 with prescribed angles. Spreads in a 2m-dimensionalbinary symplectic vector space are related to Kerdock codesover Z4 and extremal line-sets in with prescribed angles. These connections involve binary, realand complex geometry associated with extraspecial 2-groups.A geometric map from symplectic to orthogonal spreads is shownto induce the Gray map from a corresponding Z4-Kerdock codeto its binary image. These geometric considerations lead tothe construction, for any odd composite m, of large numbersof Z4-Kerdock codes. They also produce new Z4-linear Kerdockand Preparata codes. 1991 Mathematics Subject Classification:primary 94B60; secondary 51M15, 20C99. 相似文献
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De Muynck H Madder A Farcy N De Clercq PJ Pérez-Payán MN Öhberg LM Davis AP 《Angewandte Chemie (International ed. in English)》2000,39(1):145-148
Recursive deconvolution of a 729-membered peptide library has identified three active sequences, in which both Ser and His are present in one of the two tripeptidic chains generated on a steroidal scaffold (see structural formula), for the cleavage of an activated p-nitrophenyl ester. This combinatorial approach aims at searching for serine-protease-like activity. 相似文献
70.
Toni Heikkinen Lizaveta Ihnatsyeva Heli Tuominen 《Journal of Fourier Analysis and Applications》2016,22(2):334-382
We show that a domain is an extension domain for a Haj?asz–Besov or for a Haj?asz–Triebel–Lizorkin space if and only if it satisfies a measure density condition. We use a modification of the Whitney extension where integral averages are replaced by median values, which allows us to handle also the case \(0<p<1\). The necessity of the measure density condition is derived from embedding theorems; in the case of Haj?asz–Besov spaces we apply an optimal Lorentz-type Sobolev embedding theorem which we prove using a new interpolation result. This interpolation theorem says that Haj?asz–Besov spaces are intermediate spaces between \(L^p\) and Haj?asz–Sobolev spaces. Our results are proved in the setting of a metric measure space, but most of them are new even in the Euclidean setting, for instance, we obtain a characterization of extension domains for classical Besov spaces \(B^s_{p,q}\), \(0<s<1\), \(0<p<\infty \), \(0<q\le \infty \), defined via the \(L^p\)-modulus of smoothness of a function. 相似文献