Characteristics and formation of [AlO_4Al_(12)(OH)_(24)(H_2O)_(12)]~(7+) in electrolysis process

[AlO4Al12(OH)24(H2O)12] + (Al13) formation in electrolysis process is studied. The results detected by27Al NMR spectroscopy show that high content of Al13 polymer is formed in the partially hydrolyzed aluminum solution prepared by controlled electrolysis process. In the produced electrolyte of total Al concentration ([AlT]) 2.0 mol · L-1 with a basicity (B = OH/Al molar ratios) of 2.0, the content of Al13 polymer is over 60% of total Al. Dynamic light scattering shows that the size distribution of the final electrolyte solutions ([AlT] = 2.0 mol · L-1) is trimodal with B = 2.0 and bimodal with B = 2.5. The aggregates of Al13 complexes increase the particle size of partially hydrolyzed aluminum solution.     

The Enantiomer Separations of Allethrone and Propargyllone Using Two Long Chain Acylated b-Cyclodextrin Derivatives as CGC Capillary Stationary Phases

For high bioactivity of chiral pesticides, more and more chiral isomers are prepared by enantiomer resolution or asymmetric synthesis, and the sales of chiral pesticides continuously increase in recent years1. 1S-Allethrone I and 1S-propargyllone II are indispensable intermediates for synthesizing 1S-bioallethrin and prallethrin respectively, which are representatives of chiral pesticides. Usually, 1S enantiomers of allethrone and propargyllone are more active than their 1R enantiomers wh…     

MODIFICATION OF TRYPTOPHAN RESIDUES OF IgGRF AND ITS EFFECT ON THE ADSORPTION CAPACITY

1. INTRODUCTION Rheumatoid arthritis (RA) is one of the typical autoimmune diseases characterized by destructive joint inflammation and the excessively production of rheumatoid factors (RFs) [1~3]. It is evident that RFs play an important role in RA, whi…     

Total Synthesis of Two 4, 5-Dioxo-seco-eudesmane Sesquiterpenes

A facile synthetic route to two seco-eudesmane, 4, 5-dioxo-10-epi-4, 5-seco-γ-eudesmane (1) and 4, 5-dioxo-10-epi-4, 5-seco-γ-eudesmol (2) from ( )-dihydrocarvone has been described. Avoiding expensive reagents, this highly economic method especially suits for the synthesis of 4, 5-seco-eudesman-type and ophianon-type sesquiterpenes with a double bond at position 11 and 12.     

截短的单重合码对降低FFH-OCDMA系统差拍噪音的研究

在相同的系统结构下,提出一种截短的单重合码来有效降低差拍噪音对快跳频光码分多址(FFH-OCDMA)系统误码率性能的影响,并对其进行了理论分析和数值模拟.结果表明,当同时用户数较多时,该方案能显著改善FFH-OCDMA系统的误码率性能.     

聚焦微波浸取-C18反相色谱柱分离-流动注射-电感耦合等离子体质谱联用技术测定龙胆草浸取液中的金属离子及其结合态

采用聚焦微波样品处理系统对中草药龙胆草进行水浸取处理，通过C18反相色谱柱对浸取液进行分离，此后采用流动注射－ICP－MS对其中的9种元素的游离态及结合态进行了测定，并研究了浸取条件对浸出率的影响。利用正交设计对微波浸取的条件（时间、温度、料液比）进行了优化。     

Steinberg triality groups acting on 2 - (v, k, 1) designs

A 2 - (v,k,1) design D = (P, B) is a system consisting of a finite set P of v points and a collection B of k-subsets of P, called blocks, such that each 2-subset of P is contained in precisely one block. Let G be an automorphism group of a 2- (v,k,1) design. Delandtsheer proved that if G is block-primitive and D is not a projective plane, then G is almost simple, that is, T ≤ G ≤ Aut(T), where T is a non-abelian simple group. In this paper, we prove that T is not isomorphic to 3D4(q). This paper is part of a project to classify groups and designs where the group acts primitively on the blocks of the design.     

原子束计算全息片的设计与制作研究

在分析原子束计算全息片特点的基础上,提出采用罗曼Ⅲ型傅里叶变换计算全息图设计原子束计算全息片,给出设计步骤,然后提出采用电子束光刻编码矩孔图形,ICP各向异性刻蚀SiN薄膜的全息片制作方案,对全息片的制作工艺流程详细予以介绍,最后给出制作完成的SiN薄膜计算全息片.     

New Eudesmenes from Erigeron annus

Chemical investigation of Erigeron annus afforded two new eudesmenes, which were identified as 1β, 5α-dihydroxyeudesma-4(15)-en (1) and 1β, 7α-dihydroxyeudesma-4(15)-en (2).Their structures were established by spectroscopic methods including 2D NMR experiments.     

平面变线距光栅衍射场的解析表达式

利用多缝干涉原理计算了平面变线距光栅的衍射场分布,给出了它的主极大位置、半宽度等物理量.讨论了该光栅在成像参量变化时对光栅衍射场的影响,得到了变线距光栅单色器参量变化的限制范围.