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141.
Khan Tahir Ali Hasan Syed Sirajul Varkey Saji P. Rather Manzoor Ahmad Jahan Nafees Shakir Mohammad 《Transition Metal Chemistry》1997,22(1):4-8
A new class of tetraiminetetraamide macrocyclic (Ph4[20]tetraene, N8O4, and Ph6[20]tetraene, N8O4) complexes have been prepared through the metal ion controlled reaction of 1,2-diphenylethane-1,2-dione dihydrazone (DPEDDH) with succinic acid [ML1X2] or phthalic acid [ML2X2] [M=Mn, Co, Ni, Cu or Zn; X=Cl or NO3]. The structures of the complexes have been elucidated on the basis of i.r, 1H-n.m.r, e.p.r. and electronic spectral data and conductance, as well as magnetic, properties. An octahedral geometry is assigned for all the complexes, involving coordination of the all-imine nitrogens. 相似文献
142.
Misbah Ul Hasan Christos P. Tsonis 《Journal of polymer science. Part A, Polymer chemistry》1984,22(6):1349-1355
13C-NMR Spectroscopy has been used for the structural characterization of polybenzyls synthesized from the polymerization of benzyl chloride catalyzed by arene chromium tricarbonyls. The 13C-chemical shifts for various mono-, di-, tri-, and tetrasubstituted phenyl groups in a polybenzyl have been calculated by the use of additivity parameters and compared with their observed shifts. Although from a theroetical point of view, polysubstitution on a phenyl ring gives rise to a number of isomers, the results indicate the preferential formation of only a few of them due to steric and electronic considerations. Based on quantitative 13C-NMR data, several important structural parameters including the percentage of mono-, di-, tri-, and tetrasubstituted phenyl rings in the polybenzyl can be calculated. The extent of branching in a number of polybenzyls prepared under different experimental conditions was determined. The results indicate an increase in branching with the increase in reaction temperature. 相似文献
143.
Semiclassical concepts are used to gain insight into α-transfer reactions. These reactions, interpreted as one-step direct reactions on the basis of DWBA analyses, are treated in analogy with single nucleon transfer reactions for which it is known that semiclassical methods are successful. In this case however the probability of transfer appears to be greatest at a distance of closest approach which is larger than the grazing distance by the order of the α-particle radius. This increase in the effective “grazing” distance is interpreted as a manifestation of the α-particle size at the time of transfer. Angular distributions are calculated semiclassically for the reactions 208Pb(16O, 12C)212Po at 93 MeV and 40Ca(12C, 8Be)44Ti at 45 MeV lab energy. They are seen to give a reasonable fit to experiment. Partial wave amplitudes for transfer are also studied. 相似文献
144.
Khan SB Azhar-Ul-Haq Afza N Malik A Khan MT Shah MR Choudhary MI 《Chemical & pharmaceutical bulletin》2005,53(1):86-89
Long-chain esters 1 and 2 have been isolated from the chloroform-soluble fraction of Amberboa ramosa and their structures assigned to be methyl 2beta(2S)-hydroxyl-7(E)-tritriacontenoate (1) and methyl 2beta(2S)-O-beta-D-galactopyranosyl-7(E)-tetratriacontenoate (2). In addition, tricontane (3) and apigenin (4) are also reported for the first time from this species. The structures were assigned on the basis of 1D and 2D NMR techniques. Compounds 1 and 2 showed strong to moderate inhibitory activity against tyrosinase. 相似文献
145.
146.
We demonstrate a method for generating flow within a microfluidic channel using an optically driven pump. The pump consists of two counter rotating birefringent vaterite particles trapped within a microfluidic channel and driven using optical tweezers. The transfer of spin angular momentum from a circularly polarised laser beam rotates the particles at up to 10 Hz. We show that the pump is able to displace fluid in microchannels, with flow rates of up to 200 microm(3) s(-1) (200 fL s(-1)). The direction of fluid pumping can be reversed by altering the sense of the rotation of the vaterite beads. We also incorporate a novel optical sensing method, based upon an additional probe particle, trapped within separate optical tweezers, enabling us to map the magnitude and direction of fluid flow within the channel. The techniques described in the paper have potential to be extended to drive an integrated lab-on-chip device, where pumping, flow measurement and optical sensing could all be achieved by structuring a single laser beam. 相似文献
147.
The ground state properties of the spherical nucleus ^40Ca have been investigated by using constrained spherical Hartree Fock (CSHF) approximation at equilibrium and under high radial compression in a six major shells. The effective baryon-baryon interaction that includes the △(1236) resonance freedom degrees to calculate nuclear properties is used. The nucleon-nucleon (N-N) interaction is based on Reid soft core (RSC) potential. The results of calculations show that much of increase in the nuclear energy generated under compression is used to create the massive △ particles. The number of △ 's can be increased to about 2.1% of constituents of nucleus when nuclear density reaches about 1.34 times of normal density. The single particle energy levels are calculated and their behavior under compression is also examined. △ good agreement has been found between current calculations and phenomenological shell model for low lying single-particle spectra. The gap between shells is very clear and L-S coupling become stronger as increasing the static load on the nucleus. The results show a considerable reduction in compressibility when freedom degrees of △'s are taken into account. It has been found that the total nuclear radial density becomes denser in the interior and less dense in the exterior region of nucleus. The surface of nucleus becomes more and more responsive to compression than outer region. 相似文献
148.
The 0+ ↔ 0− first-forbidden β decay transitions have been investigated for some spherical nuclei. The theoretical framework is based on a proton-neutron
quasiparticle random phase approximation (pnQRPA). The Woods-Saxon potential basis has been used in our calculations. The
transition probabilities have been calculated within the ξ approximation. The relativistic β moment matrix element has been calculated both directly without any assumption and assuming that it is proportional to the
non-relativistic one. 相似文献
149.
150.
Lai-Jiu Lin Qamrul Hasan Ansari 《Nonlinear Analysis: Theory, Methods & Applications》2010,72(3-4):1210-1220
In this paper, we introduce a system of quasi-variational relations (in short, SQVR) and present several examples which show that it is a very general and unified model of several problems. We establish the existence of solutions of SQVP, in general, and several other problems, in particular. As an application of our results, we derive maximal element theorems and a collectively fixed point theorem for a family of multivalued maps. As further applications, we study Ky Fan type inequality / inclusion problem for vector valued bifunctions which includes constrained Nash equilibrium problem as a special case. We also present a common fixed point theorem for a family of multivalued maps. The results of this paper improve and generalize several known results on (system of) quasi-equilibrium problems, (system of) quasi-variational inclusions, constrained Nash equilibrium problem, collectively fixed point theorem and KKM type theorems for a family of multivalued maps. Our results also contain several results which appeared in recent literature. 相似文献