Relations between polarization observables and complete sets for deuteron photodisintegration

The polarization observables for deuteron photodisintegration are given as Hermitean forms of theT-matrix elementst _i . By inversion we are able to express a given productt _i ^* t _j in terms of polarization observables. This allows (i) to derive linear relations between observables for unpolarized, circularly and linearly polarized photons, (ii) to construct explicitly complete sets of polarization observables, and (iii) to derive quadratic relations between observables.Supported by the Deutsche Forschungsgemeinschaft (SFB 201)     

Contributions to the electromagnetic form factors of the deuteron from isobar configurations

A nonrelativistic calculation of the elastic electron deuteron scattering has been performed in which the effects arising from nucleon polarization have been systematically investigated. These effects have been taken into account by admixing isobar configurations into the deuteron wave function. Explicit expressions for the various contributions to the respective deuteron form factors have been given. At higher momentum transfers inclusion of the isobar configurations leads to a substantial increase in the form factors which qualitatively appears to account for at least some of the discrepancies between theory and experiment.     

A gauge-invariant exchange current for the Paris potential

A gauge-invariant exchange-current model is constructed for the parametrized form of the Paris potential. The influence of this current is studied for photo- and electro-disintegration of the deuteron. A comparison with a regularized π-exchange current shows significant differences for the γ-asymmetry in photodisintegration, for the transverse interference structure function in electrodisintegration and also for d(e, e′)np near threshold at higher momentum transfer. But further inclusion of a regularized ρ-exchange current with proper parametrization almost identical to the ρ-parameters of the Bryan-Gersten potential leads to results very similar to the present calculation.     

Imaging of the formerly bonded area of individual fibre to fibre joints with SEM and AFM

Besides the determination of the force and the energy needed to break individual fibre to fibre joints, the investigation of the formerly bonded area (FBA) is of essential importance to learn more about the failure mechanisms of fibre–fibre bonds in general. In this study the surfaces of paper fibres and the FBA of fibre–fibre joints after the determination of the breaking force as well as the bonding energy were analysed by means of low voltage scanning electron microscopy and atomic force microscopy. A comparison between the contact zone of fibres broken at different loading rates as well as under cyclic loading showed that there seems to be no significant difference in the appearance of the FBA in these cases. Only minor delamination of the cell wall could be found in the bonding zone, which indicates no mechanical interlocking of fibrils in the bonding zone. Furthermore, it is shown that some glues used for specimen preparation of fibre–fibre bond strength measurement are forming a glue film on the fiber surface and migrate into the bonding region.     

The synthesis of azadirachtin: a potent insect antifeedant

We describe in full the first synthesis of the potent insect antifeedant azadirachtin through a highly convergent approach. An O-alkylation reaction is used to unite decalin ketone and propargylic mesylate fragments, after which a Claisen rearrangement constructs the central C8-C14 bond in a stereoselective fashion. The allene which results from this sequence then enables a second critical carbon-carbon bond forming event whereby the [3.2.1] bicyclic system, present in the natural product, is generated via a 5-exo-radical cyclisation process. Finally, using knowledge gained through our early studies into the reactivity of the natural product, a series of carefully designed steps completes the synthesis of this challenging molecule.     

Click Chemistry: Diverse Chemical Function from a Few Good Reactions

Examination of nature's favorite molecules reveals a striking preference for making carbon–heteroatom bonds over carbon–carbon bonds—surely no surprise given that carbon dioxide is nature's starting material and that most reactions are performed in water. Nucleic acids, proteins, and polysaccharides are condensation polymers of small subunits stitched together by carbon–heteroatom bonds. Even the 35 or so building blocks from which these crucial molecules are made each contain, at most, six contiguous C−C bonds, except for the three aromatic amino acids. Taking our cue from nature's approach, we address here the development of a set of powerful, highly reliable, and selective reactions for the rapid synthesis of useful new compounds and combinatorial libraries through heteroatom links (C−X−C), an approach we call “click chemistry”. Click chemistry is at once defined, enabled, and constrained by a handful of nearly perfect “spring‐loaded” reactions. The stringent criteria for a process to earn click chemistry status are described along with examples of the molecular frameworks that are easily made using this spartan, but powerful, synthetic strategy.     

Hadron structure studied with the electromagnetic probe —from giant resonances to meson production

The development of theoretical photonuclear physics over the last 40 years is illustrated by a few selected examples highlighting a number of important issues like collective motion in nuclei, the role of subnuclear degrees of freedom, relativity and meson production.     

Polarization observables in elastic electron deuteron scattering including parity- and time-reversal-violating contributions

The general formalism for polarization observables in elastic electron deuteron scattering is extended to incorporate parity- and time-reversal-violating contributions. Parity-violating effects arise from the interference of γ and Z exchange as well as from the hadronic sector via a small parity-violating component in the deuteron. In addition we have allowed for time-reversal-invariance-violating contributions in the hadronic sector. Formal expressions for the additional structure functions are derived, and their decomposition into the various multipole contributions are given explicitly. Received: 19 December 2000 / Accepted: 14 February 2001     

Energy-weighted M1 sum rule with explicit δ degrees of freedom

The influence of Δ degrees of freedom on the energy-weighted M1 sum rule is investigated and applied to ²H and ⁴He. Using π- and ρ-exchange potentials a reduction of the potential contribution of the order of 50% is obtained. The absolute value of the sum rule is strongly dependent on the short-range behaviour of the nuclear wave function. Furthermore, the contribution of c.m. effects is evaluated and found to be of the order of 5–10%.