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31.
We report the evolution of the high power THz source program at Jefferson Lab. The source is based on coherent synchrotron radiation in which short bunches of relativistic electrons radiate when traversing a dipolar magnetic field. In our first accelerator we produced 20 W of broadband THz light. Our upgraded accelerator with higher current and improved THz extraction optics will considerably enhance the output power to >100 W. In this paper we describe the source in some detail and present theoretical calculations for the upgrade. 相似文献
32.
Benjamin M. NugentAmie L. Williams E.N. PrabhakaranJeffrey N. Johnston 《Tetrahedron》2003,59(45):8877-8888
The complete scope of free radical-mediated vinyl amination is described, using 5-exo-trig cyclizations of vinyl radicals to the nitrogen of azomethines. The focus is primarily on N,N-dialkyl enamines since their nucleophilicity renders them the most challenging enamines to synthesize using redox conditions. These studies establish several encouraging precedents for the broader application of this strategy. 相似文献
33.
A. K. Ghosh A. D. Williams J. M. Zucker J. L. Mathews N. Spinhirne 《Experimental Mechanics》2008,48(2):139-152
In nature, shape and structure evolve from the struggle for better performance. Often, biological structures combine multiple
beneficial properties, making research into mimicking them very complex. Presented here is a summary of observations from
a series of experiments performed on a material that closely resembles the human skull bone’s cancellous structure under acoustic
loads. Transmission loss through flat and curved open-cell polyurethane foam samples is observed using air and water as the
two interstitial fluids. Reduction in strength and stiffness caused by porosity can be recovered partially by filling the
interstitial pores with a fluid. The test findings demonstrate the influence of the interstitial fluid on the mechanical characteristics
of a porous structure in a quantitative manner. It is also demonstrated that the transmission loss does not depend only on
the mass per unit area of the structure as predicted by acoustic mass law. Current tests also demonstrate that the transmission
loss is more sensitive to the interstitial fluid than the shape and support conditions of the structures. Test observations
thus support the concepts of “moisture-sensitivity of biological design” and the “law of hierarchy in natural design”. 相似文献
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Lakshmi N. Roy Rabindra N. Roy Cole E. Denton Sean R. LeNoue Chandra N. Roy Shahaf Ashkenazi Thomas B. Williams Daniel R. Church Michael S. Fuge Kartik N. Sreepada 《Journal of solution chemistry》2006,35(4):605-624
The values of the second dissociation constant, K
2, and related thermodynamic quantities of the ampholyte bis[(2-hydroxyethyl)amino]acetic acid (BICINE) have been determined at temperatures from 5 to 55 ∘C. The pH values of six equimolal buffer solutions, and four buffer solutions having ionic strengths (I = 0.16 mol⋅kg−1) similar to those in blood plasma, have been evaluated at 12 temperatures from 5 to 55 ∘C using the Bates–Guggenheim convention. The liquid junction potentials (E
j
) between the buffer solutions of BICINE and saturated KCl solution of the calomel electrode at 25 and 37 ∘C have been estimated by measurement with a flowing junction cell. These values of E
j
have been used to ascertain the operational pH values at 25 and 37 ∘C. The pK
2 values at 25 and 37 ∘C are 8.333 and 8.156, respectively. The thermodynamic quantities associated with the second acid dissociation have been calculated from the values of pK
2 as a function of temperature. The zwitterionic buffer BICINE was shown to be useful as a pH standard in the region close to that of blood serum. 相似文献
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J D Griffiths Z F Lawson J E Williams 《The Journal of the Operational Research Society》2006,57(12):1413-1424
Advances in recent treatments for HIV/AIDS patients have shown dramatic outcomes in extending the incubation period and AIDS survival time, while also providing significant improvements in the quality of patients' lives. A compartmental model is proposed to analyse the effects of the various treatment regimens which have been introduced. The results produced are in good agreement with routinely collected data relating to levels of HIV/AIDS incidence and prevalence in the UK homosexual population. Some parameter values within the model are obtained from surveys, census results, etc, but others are derived using a maximum likelihood estimation procedure. Finally, the model is used to project levels of incidence and prevalence over the next few years, and to investigate several possible scenarios. 相似文献