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排序方式: 共有463条查询结果,搜索用时 25 毫秒
41.
Sadia Ameen Vazid Ali M. Zulfequar M. Mazharul Haq Mushahid Husain 《Central European Journal of Chemistry》2006,4(4):565-577
The temperature dependence of direct current (dc) conductivity was studied for various samples of polyaniline-polyvinylchloride
(PANI-PVC) blended films. Polyaniline was doped with different concentrations of sulfamic acid in aqueous tetrahydrofuran
(THF) and the blended films were prepared by varying the amount of doped PANI relative to a fixed amount of PVC. The dc conductivity
of PANI-PVC blended films was measured to determine the effect of sulfamic acid (dopant) in the temperature range (300–400K).
The mechanism of conduction is explained by a two-phase model. In order to evaluate the effect of the dopant, conductivity-derived
parameters such as the pre-exponential factor (σ
o) and the activation energy (ΔE) were calculated. The structural changes of polyaniline-PVC blended films were characterized
by FTIR spectroscopy that explores information about the suitability of the dopant in the chemical doping process. 相似文献
42.
In this paper a procedure of construction of β-expectation tolerance regions in the framework of the structural method of inference has been developed. The procedure has been applied to the generalized multivariate model and the β-expectation tolerance region for this case has been constructed assuming the normal distribution for the error variables of the model. 相似文献
43.
Statistical spectroscopy methods are used to calculate level densities for one-body Hamiltonians in the space of 440 single particle states. Comparisons are made with combinatorial counting and Fermi gas model. Possibilities to arrive at a more realistic level density formula including two-body effects are discussed. 相似文献
44.
45.
Surface Structure and Electronic Property of InP(001)-(2×1)S Surface: A First-Principles Study 下载免费PDF全文
The surface structure and electronic property of InP(001)-(2 ×1)S surface under S-rich condition are investigated based on first-principles simulations. The analyses of phase transition show that the 3B model is the most stable structure and the S-S dimer is difficult to form. The geometry of the 3B structure agrees well with the experiments. It is also found that the 3B structure has a good passivation with a band gap of about 1.24eV. The results indicate that the 3B structure is the best candidate for the sulfur-rich InP(001)(2 × 1)A phase. 相似文献
46.
祖培福 《数学的实践与认识》2010,40(14)
对候选基因的关联检验,都是针对性状在候选基因内使用多个SNP标记,并通过检验SNP单倍型来完成的,众所周知,多标记单倍型方法往往要比单标记方法表达出更多的信息,但是,单倍型的数量往往会随着所标记的SNP的数目增多而急剧的增加,这又会大大增加检验统计量的自由度,使用统计学中的主成分分析法来降低单倍型空间的维数,并构造关联检验来检验一个数量性状与多个单倍型的关联情况,模拟结果显示,此检验方法是较合理的. 相似文献
47.
This paper studies a meshfree technique for the numerical solution of the two-dimensional reaction–diffusion Brusselator system along with Dirichlet and Neumann boundary conditions. Combination of collocation method using the radial basis functions (RBFs) with first order accurate forward difference approximation is employed for obtaining meshfree solution of the problem. Different types of RBFs are used for this purpose. The method is shown to converge to the only equilibrium point of the system. Performance of the proposed method is successfully tested in terms of various error norms. In the case of non-availability of exact solution, performance of the new method is compared with the results obtained from the existing methods [7] and [8]. The elementary stability analysis is established theoretically and is also supported by numerical results. 相似文献
48.
49.
采用后嫁接法制备了不同铝负载量的Al-MCM-41分子筛。运用XRD、N2吸附-脱附、NH3-TPD、Py-FTIR等方法对分子筛进行物性表征,利用固定床评价其对噻吩的吸附性能。通过将分子筛吸附噻吩能力与分子筛的酸性质及织构性质进行关联,考察烯烃存在对Al-MCM-41活性位物种吸附脱硫机制的影响。结果表明,铝物种的引入即产生了B酸中心,也同时产生了两种类型的L酸中心L1和L2。引入低含量铝物种利于形成B酸中心和L1型酸中心,引入高含量铝物种利于形成L2型酸中心。其中,L2型酸中心对噻吩的吸附效果最佳。烯烃和噻吩在B酸中心发生竞争吸附和催化转化反应,且催化转化反应占主导地位。L2酸中心的存在促进了B酸中心上的催化转化反应,其所生成的大分子硫化物取代噻吩吸附在分子筛酸活性中心上提高了Al-MCM-41分子筛的饱和吸附硫容量。 相似文献
50.
Habib Aqsa Iqbal Muhammad Adnan Bhatti Haq Nawaz Shahid Muhammad 《Transition Metal Chemistry》2019,44(5):431-443
Transition Metal Chemistry - A series of bidendate 5,6-dimethyl benzimidazolium-based N-heterocyclic carbene (NHC) proligands and their silver complexes were synthesized. The synthetic approaches... 相似文献