Low-temperature liquid phase deposited TiO2 films on stainless steel for photogenerated cathodic protection applications

The low-temperature synthesis of anatase TiO₂ films was an imperative requirement for their application to corrosion prevention of metals. In this paper, a liquid phase deposition (LPD) technique was developed to prepare TiO₂ films on SUS304 stainless steel (304SS) at a relatively low temperature (80 °C). The as-prepared films were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), Raman spectroscopy and X-ray photon spectroscopy (XPS). It was observed that a dense and crack-free anatase TiO₂ film with a thickness about 300 nm was obtained. The film contained some fluorine and nitrogen elements, and the amounts of these impurities were greatly decreased upon calcination. Under the white light illumination, the electrode potential of TiO₂ coated 304SS rapidly shifted to a more negative direction. Moreover, the photopotential of TiO₂/304SS electrode showed more negative values with increased film thickness. In conclusion, the photogenerated cathodic protection of 304SS was achieved by the low-temperature LPD-derived TiO₂ film.     

稀土离子掺杂纳米TiO_2的太赫兹光谱研究

对sol-gel法制备的不同稀土元素(Ce,Nd,Sm)掺杂的纳米TiO2粒子进行研究。X射线衍射(XRD)和X射线光电子能谱(XPS)分析结果表明,稀土离子均以间隙的形式均匀分布在纳米TiO2晶格内。傅里叶变换红外光谱(FTIR)和太赫兹时域光谱(THz-TDS)显示,掺杂TiO2较纯TiO2具有更强的红外活性;在0.2~1.70 THz波段,TiO2的折射率随着频率的增加而减小,并呈现反常色散现象;Ce掺杂引起新的特征吸收,分别为1.35和1.58 THz,且造成太赫兹吸收谱的吸收边发生红移,Nd和Sm掺杂则造成吸收边蓝移。在0.2~1.7 THz范围内,Sm掺杂引起的介电损耗角正切值(taneδ)最小,其平均值为0.05。     

超声喷雾热解法制备SnS薄膜的物性研究

用超声喷雾热解法制备SnS多晶薄膜,对比了三种不同前驱液配比浓度对SnS薄膜性能的影响。XRD测试表明,当前驱液为硫脲(0.5 mol·L-1)+四氯化锡(0.5 mol·L-1)+去离子水时,SnO2的衍射峰强度比较大;当前驱液为硫脲(0.6 mol·L-1)+四氯化锡(0.5 mol·L-1)+去离子水时,SnS的衍射峰占主要地位,其中也含有一定量的SnO2;当前驱液为硫脲(0.7 mol·L-1)+四氯化锡(0.5 mol·L-1)+去离子水时,退火后的薄膜为单一的SnS薄膜,具有斜方晶系结构。SEM观测发现,薄膜均匀、致密,前驱液中硫脲浓度较大时,颗粒也较大。透过谱测试表明,浓度对薄膜透过率影响较小。结合器件的暗I-V和C-V测试,用三种前驱液配比浓度所制备的器件的结特性差异不大;当前驱液中硫脲浓度较大时,载流子浓度相对较大。     

基于环境星CCD数据的环境植被指数及叶面积指数反演研究

利用PROSAIL前向模型模拟的植被冠层光谱,在植被指数构造时,引入修正大气、土壤背景影响的蓝、绿波段,构建了避免过早饱和的环境植被指数(environmental vegetation index,EVI)。基于多个典型冬小麦生育期的地面观测数据,建立基于EVI-LAI长时间序列反演模型,并对模型进行不同品种间的交叉检验。研究表明,EVI建立的叶面积指数(leaf area index,LAI)反演模型精度优于同类植被指数模型,并具有较好的普适性,能应用于冬小麦遥感多时相长势监测及LAI反演。     

射流影响下气固两相流动试验的定量分析

为了研究受限空间内的射流影响下的气固两相流动,本文采用数码颗粒图像测速仪（DpIV）系统测量颗粒分布,并开发了一套用于处理DPIV颗粒图片的算法,可用于准确地定量分析通道内的颗粒分布。使用该算法能够获得颗粒在拍摄平面内的二维相对浓度数据,定量分析该数据发现,在同样的流场条件下,射流对气流场和不同粒径颗粒的影响区域存在明...     

有机/无机复合功能材料倒脊型波导热光开关

利用溶胶-凝胶技术自主合成了一种具有优良光学特性和高热稳定性的有机/无机复合芯层材料.这种功能材料的分子中含有有机柔性侧链,可形成环氧交联.与无机SiO2-TiO2体系相比,具有较高的热光系数(量级为10-4/K),以及更好的成膜性和可加工性.通过与实验室自行配制的P(MMA-GMA)包层材料相匹配,设计制备了基于这种有机/无机复合功能材料的倒脊型波导马赫-曾德尔型热光开关.器件的波导与热电极性能良好.插入损耗为10dB,驱动功率15mW,开关时间小于1ms,消光比15dB.     

Traveling wave solutions for two nonlinear evolution equations with nonlinear terms of any order

In this paper, based on the known first integral method and the Riccati sub-ordinary differential equation (ODE) method, we try to seek the exact solutions of the general Gardner equation and the general Benjamin-Bona-Mahoney equation. As a result, some traveling wave solutions for the two nonlinear equations are established successfully. Also we make a comparison between the two methods. It turns out that the Riccati sub-ODE method is more effective than the first integral method in handling the proposed problems, and more general solutions are constructed by the Riccati sub-ODE method.     

GaN基低色温高显色白光LED

采用440nm短波长InGaN/GaN基蓝光LED芯片激发高效红、绿荧光粉制得高显色性白光LFD,研究了不同胶粉配比对LED发光性能的影响,结果表明,A胶、B胶、绿粉、红粉比重在0.5∶0.5∶0.2∶0.03时,在440 m蓝光激发下呈现了有两个谱带组成的发光光谱,分别是峰值为535 nm的特征光谱和643nm的特征光谱,胶粉通过均匀调配后能够有效的进行混光产生低色温白光,实验中最低色温可达3 251K,显色指数高达88.8,这比传统蓝光激发YAG荧光粉制得的白光LED色温更低,显色指数提高了26%.     

辐射驱动条件下冲击波速度直接测量技术

 针对超高压下透明材料的高压离化机理,分析了透明材料中冲击波直接诊断技术的基本方法。利用Drude自由电子气模型,分析了不同冲击压力下冲击波阵面反射率的变化。设计了专门的实验,将探测器致盲区与信号区错开,获得了蓝宝石中冲击波阵面反射的信号。结果表明:冲击波速度为32 km/s时,其波阵面的反射率约为35%,致盲效应出现时间与激光脉冲峰值到达时刻相同,持续时间也与激光脉宽相同。分析了致盲应产生的原因,并提出了解决办法。给出了加蓝宝石窗口后的测速公式,经过和实验对比,确认了测速公式的正确性。     

Application of quantitative structure-activity relationship to the determination of binding constant based on fluorescence quenching

Quantitative structure-activity relationship (QSAR) model was used to predict and explain binding constant (log K) determined by fluorescence quenching. This method allowed us to predict binding constants of a variety of compounds with human serum albumin (HSA) based on their structures alone. Stepwise multiple linear regression (MLR) and nonlinear radial basis function neural network (RBFNN) were performed to build the models. The statistical parameters provided by the MLR model (R²=0.8521, RMS=0.2678) indicated satisfactory stability and predictive ability while the RBFNN predictive ability is somewhat superior (R²=0.9245, RMS=0.1736). The proposed models were used to predict the binding constants of two bioactive components in traditional Chinese medicines (isoimperatorin and chrysophanol) whose experimental results were obtained in our laboratory and the predicted results were in good agreement with the experimental results. This QSAR approach can contribute to a better understanding of structural factors of the compounds responsible for drug-protein interactions, and can be useful in predicting the binding constants of other compounds.