首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   33866篇
  免费   6016篇
  国内免费   3695篇
化学   24259篇
晶体学   481篇
力学   2044篇
综合类   227篇
数学   3894篇
物理学   12672篇
  2024年   67篇
  2023年   749篇
  2022年   1024篇
  2021年   1305篇
  2020年   1518篇
  2019年   1465篇
  2018年   1213篇
  2017年   1080篇
  2016年   1659篇
  2015年   1713篇
  2014年   1960篇
  2013年   2517篇
  2012年   3240篇
  2011年   3296篇
  2010年   2181篇
  2009年   2146篇
  2008年   2318篇
  2007年   2068篇
  2006年   1874篇
  2005年   1544篇
  2004年   1128篇
  2003年   845篇
  2002年   808篇
  2001年   593篇
  2000年   578篇
  1999年   621篇
  1998年   517篇
  1997年   503篇
  1996年   512篇
  1995年   402篇
  1994年   344篇
  1993年   273篇
  1992年   267篇
  1991年   216篇
  1990年   188篇
  1989年   162篇
  1988年   111篇
  1987年   125篇
  1986年   106篇
  1985年   96篇
  1984年   57篇
  1983年   46篇
  1982年   37篇
  1981年   20篇
  1980年   12篇
  1979年   10篇
  1978年   7篇
  1976年   11篇
  1975年   11篇
  1957年   6篇
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
201.
In the inverse scattering transform (IST), the reflectionless Jost solutions are combined by their analytic properties in the complex spectrum parameter plane, and then can be shown to satisfy the two Lax equations indeed by Liouville theorem. So the corresponding soliton solutions certainly satisfy the nonlinear equation by compatibility condition. Especially the multi-soliton solutions of DNLS equation can be demonstrated in this way. PACS Numbers: 05.45.Yv, 02.30.-f, 11.10.Ef  相似文献   
202.
CrNx thin films have attracted much attention for semiconductor IC packaging molding dies and forming tools due to their excellent hardness, thermal stability and non-sticking properties (low surface free energy). However, few data has been published on the surface free energy (SFE) of CrNx films at temperatures in the range 20-170 °C. In this study CrNx thin films with CrN, Cr(N), Cr2N (and mixture of these phases) were prepared using closed field unbalanced magnetron sputtering at a wide range of Cr+2 emission intensity. The contact angles of water, di-iodomethane and ethylene glycol on the coated surfaces were measured at temperatures in the range 20-170 °C using a Dataphysics OCA-20 contact angle analyzer. The surface free energy of the CrNx films and their components (e.g., dispersion, polar) were calculated using the Owens-Wendt geometric mean approach. The influences of CrNx film surface roughness and microstructure on the surface free energy were investigated by atomic force microscopy (AFM) and X-ray diffraction (XRD), respectively. The experimental results showed that the lowest total SFE was obtained corresponding to CrN at temperature in 20 °C. This is lower than that of Cr(N), Cr2N (and mixture of these phases). The total SFE, dispersive SFE and polar SFE of CrNx films decreased with increasing surface temperature. The film roughness has an obvious effect on the SFE and there is tendency for the SFE to increase with increasing film surface roughness.  相似文献   
203.
腺嘌呤及其β-环糊精包结物的光谱研究   总被引:4,自引:0,他引:4  
通过紫外光谱的摩尔比法确定了腺嘌呤与β-环糊精(β-CD)包结物的包结比为1:1,通过紫外光谱和荧光光谱研究了腺嘌呤在酸性,中性,及碱性条件下的光谱变化及与β-CD包结物的光谱变化,分别求得了它们与β-CD包结的平衡常数。  相似文献   
204.
偶氮苯衍生物三阶非线性的四波混频研究   总被引:7,自引:0,他引:7  
黄燕萍  王深义 《光学学报》1998,18(10):290-1294
用皮秒Nd:YAG激光器的倍频光(532nm)对具有离域π-共轭电子云结构的偶氮苯类样品材料作简并四波混频补给,测得三阶非线性电极化率x^(3)和它们的时间响应分别为10^-9esu和20ps,并对影响x^(3)的瞬时光栅作用和x^(3)的响应时间人了讨论。  相似文献   
205.
声流现象的研究及其应用   总被引:5,自引:0,他引:5       下载免费PDF全文
钱盛友  王鸿樟  孙福成 《应用声学》1997,16(6):38-42,25
本文从声流产生的机理出发,综合了影响声流的诸因素,介绍了声流现象的检测方法及声流效应的应用。  相似文献   
206.
测定了二个顺磁性化合物(Ph_1P)[V_2(mp)_6](Ⅰ)和(Ph_4P)_2[NaV(mp)_3 (MeCN)(MeOH)](Ⅱ)(H_2mp=邻巯基苯酚,o-HO_1C_6H_4SH)的固态和/或溶液中的顺磁波谱。(Ⅰ)的77K固态谱及(Ⅱ)的室温固态谱均经模拟计算,认为它们的钒原子处在S=l/2的Ⅰ=7/2状态,(Ⅱ)的低温(77K)溶液谱(乙腈)与Ⅱ的固态谱相同,均有特征的八条精细结构,认为非配对电子基本上定域在钒原子的周围。  相似文献   
207.
通过测定平带电位,澄清了OH~-离子在CdSe电极上的吸附情况,发现在S、S~(2-)、OH~-溶液中S~(2-)离子优先吸附,结合旋转环盘电极测量,证明n-CdSe电极在多硫溶液界面上的电荷转移过程。  相似文献   
208.
Optical properties and microstructure of Ag film on glass substrate with Cr intermediate layer were studied by using spectrophotometer and XRD. The spectra results showed that introducing Cr intermediate layer reduced the surface roughness and promoted the reflectivity of Ag film. The XRD analysis showed that the crystalline grains increased and the stress decreased. The adhesion was also improved by using the tape test method.  相似文献   
209.
Films of polytetrafluoroethylene (PTFE) were exposed to sodium naphthalenide (Na/naphtha) etchant so as to defluorinate the surface for obtaining hydroxyl functionality. Surface-initiators were immobilized on the PTFE films by esterification of 4,4′-azobis(4-cyanopentanoic acid) (ACP) and the hydroxyl groups covalently linked to the surface. Grafting of polymer brushes on the PTFE films was carried out by the surface-initiated free radical polymerization. Homopolymers brushes of methyl methacrylate (MMA) were prepared by free radical polymerization from the azo-functionalized PTFE surface. The chemical composition and topography of the graft-functionalized PTFE surfaces were characterized by X-ray photoelectron spectroscopy (XPS), attenuated total reflectance (ATR) FT-IR spectroscopy and atomic force microscopy (AFM). Water contact angles on PTFE films were reduced by surface grafting of MMA.  相似文献   
210.
We consider in this paper the Lagrangian dual method for solving general integer programming. New properties of Lagrangian duality are derived by a means of perturbation analysis. In particular, a necessary and sufficient condition for a primal optimal solution to be generated by the Lagrangian relaxation is obtained. The solution properties of Lagrangian relaxation problem are studied systematically. To overcome the difficulties caused by duality gap between the primal problem and the dual problem, we introduce an equivalent reformulation for the primal problem via applying a pth power to the constraints. We prove that this reformulation possesses an asymptotic strong duality property. Primal feasibility and primal optimality of the Lagrangian relaxation problems can be achieved in this reformulation when the parameter p is larger than a threshold value, thus ensuring the existence of an optimal primal-dual pair. We further show that duality gap for this partial pth power reformulation is a strictly decreasing function of p in the case of a single constraint. Dedicated to Professor Alex Rubinov on the occasion of his 65th birthday. Research supported by the Research Grants Council of Hong Kong under Grant CUHK 4214/01E, and the National Natural Science Foundation of China under Grants 79970107 and 10571116.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号