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11.
Ch Yan Poon 《Tetrahedron letters》2004,45(14):2985-2988
An efficient synthesis of the unique indolizino[7,6-c]quinoline carboskeleton of isaindigotidione has been achieved. This strategy employed l-proline and isatin as the main building blocks in the construction of the framework. Four transformations occurred in a one-pot operation to furnish the tetracyclic nucleus. 相似文献
12.
Th. Münzel A. Wynter Blyth Kützing Ch. Girard 《Analytical and bioanalytical chemistry》1882,21(1):436-438
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NH chemical shift temperature coefficients have been measured in a large series of N-substituted-3-piperidinethiopropionamides in which the NN distances are short but of varied length, as well as in a couple of the corresponding amides and in some simpler amides and thioamides. Geometries are calculated by means of ab initio DFT methods. The N-substituted-3-piperidinethiopropionamides show in most cases strong intramolecular N–HN hydrogen bonds according to IR spectra and ab initio calculations. For compounds with rather short NN distances the S=C–N–H moiety is non-planar. Dihedral angles as small as 160° are found. The NH chemical shift coefficients measured in non-polar solvents in all the N-substituted-3-piperidinethiopropionamides are more negative (−8 to −17 ppb/K) than in non-hydrogen bonded thioamides. For the latter in non-polar solvents like CDCl3 and toluene the temperature coefficients are as small as −1 to −4 ppb/K. The large negative effects can be related not only to the non-planarity of the thioamide group in a way that the more pronounced the non-planarity the more negative the temperature coefficients, but also to strong hydrogen bonding and the fact that the acceptor is a nitrogen. For similar amides with non-planar amide groups and nitrogen acceptor large negative temperature coefficients are likewise seen. In polar solvents like DMF the effects in simple thioamides are uniform and close to −6 ppb/K, whereas in the more complex compound like 4p(t) the temperature coefficient is close to 0. An essential feature of measuring temperature coefficients of compounds without strong intramolecular hydrogen bonds in non-polar solvents and at low temperatures is to keep the concentration low enough to avoid dimerisation. 相似文献
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T.M. Mishonov N. Chéenne D. Robbes J.O. Indekeu 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,26(3):291-296
The generation of harmonics of the voltage response is considered when an AC current is applied through a superconducting
film above Tc. It is shown that almost at all temperatures the mechanism of the temperature oscillations created by the AC current and
the temperature dependence of the resistance dominates over the isothermal nonlinear electric conductivity. Only in a narrow
critical region close to Tc the latter is essential for the generation of the harmonics. A detailed investigation of harmonics generation provides an
accurate method for measuring the thermal boundary conductance between the film and the insulating substrate. The critical
behaviour of the third harmonic will give a new method for the determination of the lifetime of metastable Cooper pairs above
Tc. The comparison of the calculated fifth harmonics of the voltage with the experiment is proposed as an important test for
the applicability of the employed theoretical models.
Received 8 September 2001 相似文献
18.
O. A. Sadygov Kh. M. Alimardanov Ch. A. Chalabiev 《Russian Journal of Applied Chemistry》2006,79(6):949-956
The features of induced bromination of aromatic hydrocarbons in the NaBr(KBr)-HX-H2O2(NaOCl) system were studied. 相似文献
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K. K. Kadyrzhanov S. Khazhekber S. N. Lukashenko V. P. Solodukhin I. V. Kazachevskiy V. L. Poznyak B. B. Knyazev Ch. Rofer 《Czechoslovak Journal of Physics》2003,53(1):A39-A44
Data on the spatial distribution of radionuclides (241Am, 239Pu, 137Cs and 152Eu) formed during nuclear explosions of different types near P2 SNTS test site are presented. Radionuclide contamination induced by the explosions varies in the concentrations of individual radionuclides, their proportions and species. Examination of the variations is a crucial task to plan remediation activities as well as those aimed at decrease of radiation risk for population and prevention of repeated contamination. Concentrations of 241Am and 239+240Pu that are the most toxic radionuclides in the area lie in hundred thousands of Bqkg?1. The most contaminated areas are classified by the radionuclide concentration, ratio and form present in soil. 相似文献