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81.
Rodrigo París José Luis de la Fuente 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3538-3549
Different diblock copolymers constituted by one segment of a monomer supporting a reactive functional group, like allyl methacrylate (AMA), were synthesized by atom transfer radical polymerization (ATRP). Bromo‐terminated polymers, like polystyrene (PS), poly(methyl methacrylate) (PMMA), and poly(butyl acrylate) (PBA) were employed as macroinitiators to form the other blocks. Copolymerizations were carried out using copper chloride with N,N,N′,N″,N″‐pentamethyldiethylenetriamine (PMDETA) as the catalyst system in benzonitrile solution at 70 °C. At the early stage, the ATRP copolymerizations yielded well‐defined linear block copolymers. However, with the polymerization progress a change in the macromolecular architecture takes place due to the secondary reactions caused by the allylic groups, passing to a branched and/or star‐shaped structure until finally yielding gel at monomer conversion around 40% or higher. The block copolymers were characterized by means of size exclusion chromatography (SEC), 1H NMR spectroscopy, and differential scanning calorimetry (DSC). In addition, one of these copolymers, specifically P(BA‐b‐AMA), was satisfactorily modified through osmylation reaction to obtain the subsequent amphiphilic diblock copolymer of P(BA‐b‐DHPMA), where DHPMA is 2,3‐dihydroxypropyl methacrylate; demonstrating the feasibility of side‐chain modification of the functional obtained copolymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3538–3549, 2007 相似文献
82.
After a discussion of a space of test functions and the corresponding space of distributions, a family of Banach spaces (B, ∥ ∥B) in standard situation is described. These are spaces of distributions having a pointwise module structure and also a module structure with respect to convolution. The main results concern relations between the different spaces associated to B established by means of well-known methods from the theory of Banach modules, among them B0 and , the closure of the test functions in B and the weak relative completion of B, respectively. The latter is shown to be always a dual Banach space. The main diagram, given in Theorem 4.7, gives full information concerning inclusions between these spaces, showing also a complete symmetry. A great number of corresponding formulas is established. How they can be applied is indicated by selected examples, in particular by certain Segal algebras and the Ap-algebras of Herz. Various further applications are to be given elsewhere. 相似文献
83.
Hans Grauert 《Mathematische Zeitschrift》1989,200(2):149-168
Ohne ZusammenfassungHerrn E. Heinz zum 65. Geburtstag gewidmet 相似文献
84.
Ohne ZusammenfassungDiese Arbeit wurde während eines Aufenthaltes von Schmidt in der Bundesrepublik Deutschland als Preisträger der Alexander von Humboldt-Stiftung geschrieben. 相似文献
85.
In this Note, we give a necessary and sufficient condition for Lagrangians in a symplectic vector bundle to be deformed stably into transversal Lagrangians. In the case of three Lagrangians, we show that the associated Grothendieck group can be identified with a Hermitian K-theory group. To cite this article: M. Karoubi, M.L. Lapa de Souza, C. R. Acad. Sci. Paris, Ser. I 342 (2006). 相似文献
86.
87.
88.
Hans L. Bodlaender 《Discrete Applied Mathematics》2007,155(11):1348-1372
The Maximum Cardinality Search (MCS) algorithm visits the vertices of a graph in some order, such that at each step, an unvisited vertex that has the largest number of visited neighbours becomes visited. A maximum cardinality search ordering (MCS-ordering) of a graph is an ordering of the vertices that can be generated by the MCS algorithm. The visited degree of a vertex v in an MCS-ordering is the number of neighbours of v that are before v in the ordering. The visited degree of an MCS-ordering ψ of G is the maximum visited degree over all vertices v in ψ. The maximum visited degree over all MCS-orderings of graph G is called its maximum visited degree. Lucena [A new lower bound for tree-width using maximum cardinality search, SIAM J. Discrete Math. 16 (2003) 345-353] showed that the treewidth of a graph G is at least its maximum visited degree.We show that the maximum visited degree is of size O(logn) for planar graphs, and give examples of planar graphs G with maximum visited degree k with O(k!) vertices, for all k∈N. Given a graph G, it is NP-complete to determine if its maximum visited degree is at least k, for any fixed k?7. Also, this problem does not have a polynomial time approximation algorithm with constant ratio, unless P=NP. Variants of the problem are also shown to be NP-complete.In this paper, we also propose some heuristics for the problem, and report on an experimental analysis of them. Several tiebreakers for the MCS algorithm are proposed and evaluated. We also give heuristics that give upper bounds on the value of the maximum visited degree of a graph, which appear to give results close to optimal on many graphs from real life applications. 相似文献
89.
A. Ferreira da Silva I. Pepe S.A. Tomás W.M. de Azevedo R. Ahuja 《Applied Surface Science》2006,252(15):5365-5367
In this paper we present spectroscopic properties of doped and undoped titanium dioxide (TiO2) as nanofilms prepared by the sol-gel process with rhodamine 6G doping and studied by photoacoustic absorption, excitation and emission spectroscopy. The absorption spectra of TiO2 thin films doped with rhodamine 6G at very low concentration during their preparation show two absorption bands, one at 2.3 eV attributed to molecular dimmer formation, which is responsible for the fluorescence quenching of the sample and the other at 3.0 eV attributed to TiO2 absorption, which subsequently yields a strong emission band at 600 nm. The electronic band structure and optical properties of the rutile phase of TiO2 are calculated employing a fully relativistic, full-potential, linearized, augmented plane-wave (FPLAPW) method within the local density approximation (LDA). Comparison of this calculation with experimental data for TiO2 films prepared for undoped sol-gels and by sputtering is performed. 相似文献
90.
Hans Weber 《Order》2007,24(4):249-276
We study lattice theoretical properties of lattices of uniformities such as modularity, distributive laws and the existence
of (relative) complements. For this the concepts of permutable uniformities (see Definition 3.1) and independent uniformities
(see Definition 4.1) are important. Moreover, we show that e.g. the lattice of all lattice uniformities on a lattice L is a closed sublattice of the lattice of all uniformities on L. 相似文献