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81.
Yong‐Jin Kim Jin‐Woong Kim Jung‐Eun Lee Jee‐Hyun Ryu Junoh Kim Ih‐Seop Chang Kyung‐Do Suh 《Journal of polymer science. Part A, Polymer chemistry》2004,42(22):5627-5635
Mesoporous polymer microspheres with gold (Au) nanoparticles inside their pores were prepared considering their surface functionality and porosity. The Au/polymer composite microspheres prepared were characterized by transmission electron microscope (TEM), X‐ray diffraction (XRD), and Brunauer–Emmett–Teller (BET) techniques. The results showed that the adsorption of Au nanoparticles could be increased by imparting the pore structure and surface‐functional groups into the supporting polymer microspheres (in this study, poly (ethylene glycol dimethacrylate‐co‐acrylonitrile) and poly (EGDMA‐co‐AN) system). Above all, from this study, it was established that the porosity of the polymer microspheres is the most important factor that determines the distribution and adsorption amount of face‐centered cubic (fcc) Au nanoparticles in the final products. Our study showed that the continuous adsorption of Au nanoparticles with the aid of the large surface area and surface interaction sites formed more favorably the Au/polymer composite microspheres. The BET measurements of Au/poly(EGDMA‐co‐AN) composite microspheres reveals that the adsorption of Au nanoparticles into the pores kept the pore structure intact and made it more porous. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5627–5635, 2004 相似文献
82.
Yong Joon Park Min Gyu KimYoung-Sik Hong Xianglan WuKwang Sun Ryu Soon Ho Chang 《Solid State Communications》2003,127(7):509-514
Li[NixLi(1/3−2x/3)Mn(2/3−x/3)]O2 (X=0.17, 0.25, 0.33, 0.5) compounds are prepared by a simple combustion method. The Rietvelt analysis shows that these compounds could be classified as having the α-NaFeO2 structure. The initial charge-discharge and irreversible capacity increases with the decrease of x in Li[NixLi(1/3−2x/3)Mn(2/3−x/3)]O2. Indeed, Li[Ni0.50Mn0.50]O2 compound shows relatively low initial discharge capacity of 200 mAh/g and large capacity loss during cycling, with Li[Ni0.17Li0.22Mn0.61]O2 and Li[Ni0.25Li0.17Mn0.58]O2 compounds exhibit high initial discharge capacity over 245 mAh/g and stable cycle performance in the voltage range of 4.8 -2.0 V. On the other hand, XANES analysis shows that the oxidation state of Ni ion reversibly changes between Ni2+ and about Ni3+, while the oxidation state of Mn ion sustains Mn4+ during charge-discharge process. This result does not agree with the previously reported ‘electrochemistry model’ of Li[NixLi(1/3−2x/3)Mn(2/3−x/3)]O2, in which Ni ion changes between Ni2+ and NI4+. Based on these results, we modified oxidation-state change of Mn and Ni ion during charge-discharge process. 相似文献
83.
Yu-hai WU~ 《中国科学A辑(英文版)》2007,50(7):925-940
This paper concerns the number and distributions of limit cycles in a Z_2-equivariant quintic planar vector field.25 limit cycles are found in this special planar polynomial system and four different configurations of these limit cycles are also given by using the methods of the bifurcation theory and the qualitative analysis of the differential equation.It can be concluded that H(5)≥25=5~2, where H(5)is the Hilbert number for quintic polynomial systems.The results obtained are useful to study the weakened 16th Hilbert problem. 相似文献
84.
85.
Deguang Han 《应用数学学报(英文版)》1994,10(2):213-219
In this paper we will prove some theorems on theM-ideals of compact operators and the best approximation of quasitriangular operator algebras. These results improve and extend the known results in [4, 5, 7].This work is supported in part by the National Natural Science Foundation of China. 相似文献
86.
A transient molecular network model is built to describe the nonlinear viscoelasticity of polymers by considering the effect
of entanglement loss and regeneration on the relaxation of molecular strands. It is an extension of previous network theories.
The experimental data on three thermoplastic polymers (ABS, PVC and PA6) obtained under various loading conditions are used
to test the model. Agreement between the theoretical and experimental curves shows that the suggested model can describe successfully
the relaxation behavior of the thermoplastic polymers under different loading rates by using relatively few relaxation modes.
Thus the micromechanism responsible for strain-rate dependence of relaxation process and the origin of nonlinear viscoelasticity
may be disclosed.
The project supported by the National Natural Science Foundation of China and Doctorial Fund 相似文献
87.
The activity coefficients of NaBr in the NaBr–NaPropionate–H2O and NaBr–NaButyrate–H2O systems were determined from EMF measurements at constant total ionic strength of 0.1 0.5 1.0 1.5 2.0 and 2.5 mol-kg–1 and at 25° C. The activity coefficients were fitted using Scatchard, Pitzer and Lim equations. Finally the excess Gibbs free energy of these mixtures were also calculated. 相似文献
88.
89.
Weimin Han 《Mathematical Methods in the Applied Sciences》1994,17(7):487-508
The paper is devoted to a posteriori quantitative analysis for errors caused by linearization of non-linear elliptic boundary value problems and their finite element realizations. We employ duality theory in convex analysis to derive computable bounds on the difference between the solution of a non-linear problem and the solution of the linearized problem, by using the solution of the linearized problem only. We also derive computable bounds on differences between finite element solutions of the nonlinear problem and finite element solutions of the linearized problem, by using finite element solutions of the linearized problem only. Numerical experiments show that our a posteriori error bounds are efficient. 相似文献
90.
微腔激光器的发展与应用 总被引:1,自引:0,他引:1
本文探讨了微腔激光器的分类、基本原理及特点,并简单介绍了目前几种微型激光器的发展及应用。 相似文献