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71.
The current investigation highlights the mixed convection slip flow and radiative heat transport of uniformly electrically conducting Williamson nanofluid yield by an inclined circular cylinder in the presence of Brownian motion and thermophoresis parameter.A Lorentzian magnetic body force model is employed and magnetic induction effects are neglected.The governing equations are reduced to a system of nonlinear ordinary differential equations with associated boundary conditions by applying scaling group transformations.The reduced nonlinear ordinary differential equations are then solved numerically by Runge-Kutta-Fehlberg fifth-order method with shooting technique.The effects of magnetic field,Prandtl number,mixed convection parameter,buoyancy ratio parameter,Brownian motion parameter,thermophoresis parameter,heat generation/absorption parameter,mass transfer parameter,radiation parameter and Schmidt number on the skin friction coefficient and local Nusselt are analyzed and discussed.It is found that the velocity of the fluid decreases with decrease in curvature parameter,whereas it increases with mixed convection parameter.Further,the local Nusselt number decreases with an increase in the radiation parameter.The numerical comparison is also presented with the existing published results and found that the present results are in excellent agreement which also confirms the validity of the present methodology. 相似文献
72.
Let L be a Lie superalgebra with its enveloping algebra U(L) over a field F. A polynomial identity is called non-matrix if it is not satisfied by the algebra of 2×2 matrices over F. We characterize L when U(L) satisfies a non-matrix polynomial identity. We also characterize L when U(L) is Lie solvable, Lie nilpotent, or Lie super-nilpotent. 相似文献
73.
74.
Ayman I. Madbouly Amin Y. Noaman Abdul Hamid M. Ragab Ahmed M. Khedra Ayman G. Fayoumi 《Applied Acoustics》2016
In this paper, a new classroom acoustics assessment model (CAAM) based on analytic hierarchy process (AHP) for enhancing speech intelligibility and learning quality is proposed. The model is based on five main criteria that affect the learning process and related to classrooms acoustical properties. These include classroom specifications, noise sources inside and outside the classroom, teaching style, and vocal effort. The priority and weights of these major criteria along with their alternatives are identified using the views of students, staff, education consultants, and expertise by using a developed questionnaire, and the AHP methodology. This model can be considered as a helpful framework enabling universities decision makers to take effective decisions on classroom acoustics treatment issues. It also provides colleges’ higher authorities the suitable guidelines that help for determining necessary requirements that help to raise the quality and efficiency of the educational environment; in order to reach an excellent learning environment; and hence increasing students learning outcomes. 相似文献
75.
Coordination compounds of Cu (II), Y (III), Zr (IV) and La (III) with the tetradentate Schiff base (H2L) obtained through the condensation of p‐phenylenediamine with salicylaldehyde under reflux conditions. The complexes were characterized by elemental analysis, magnetic susceptibility, molar conductance and also, with various spectroscopic techniques such as 1H NMR, UV–Vis., IR and XRD techniques. Electrolytic nature of complexes was ascertained by molar conductance values. In these four complexes, the ligand chelates act in a tetradentate manner via azomethine nitrogen and oxygen atoms of phenolic groups. Electronic spectroscopic data are in agreement with an octahedral geometrical structure. Thermal degradation analyses in nitrogen gas were used to investigate the number and location of water molecules. The chemical formulae of metal complexes were confirmed by microanalytical data. The activation thermodynamic parameters, such as, E*, ΔH*, ΔS* and ΔG* were calculated from the DTG curves using Coats Redfern (CR) and Horowitz–Metzeger (HM) methods at n = 1 or n ≠ 1. Nematicidal activities indicate that the ligand exhibit greater activity when compared to its complexes. In addition metal complexes displayed good moderate nematicidal activities. 相似文献
76.
A series of dinuclear cycloplatinated(II) complexes with general closed formula of [Pt2Me2(C^N)2(μ‐P^P)] (C^N = 2‐vinylpyridine (Vpy), 2,2′‐bipyridine N‐oxide (O‐bpy), 2‐(2,4‐difluorophenyl)pyridine (dfppy); P^P = 1,1‐bis(diphenylphosphino)methane (dppm), N,N‐bis(diphenylphosphino)amine (dppa)) are reported. The complexes were characterized by means of NMR spectroscopy. Due to the presence of dppm and dppa with short backbones as bridging ligands, two platinum centres are located in front of each other in these complexes so a Pt…Pt interaction is established. Because of this Pt…Pt interaction, the complexes have bright orange colour under ambient light and are able to strongly emit red light under UV light exposure. These strong red emissions originate from a 3MMLCT (metal–metal‐to‐ligand charge transfer) electronic transition. In most of these complexes, the emissions have unstructured bell‐shaped bands, confirming the presence of large amount of 3MMLCT character in the emissive state. Only the complexes bearing dfppy and dppa ligands reveal dual luminescence: a high‐energy structured emission originating from 3ILCT/3MLCT (intra‐ligand charge transfer/metal‐to‐ligand charge transfer) and an unstructured low‐energy band associated with 3MMLCT. In order to describe the nature of the electronic transitions, density functional theory calculations were performed for all the complexes. 相似文献
77.
Justin L. Poklis Maciej M. Gonek Carl E. Wolf Hamid I. Akbarali William L. Dewey 《Biomedical chromatography : BMC》2019,33(4)
Carbenoxolone is a derivative of glycyrrhetinic acid found in the root of Glycyrrhiza glabra, colloquially known as licorice. It has been used as a treatment for peptic and oral ulcers. In recent years, carbenoxolone has been utilized in basic research for its ability to block gap junctional communication. Better understanding the distribution of carbenoxolone after systemic administration can lead to a better understanding of its potential sites of action. Presented is an ultra high‐performance liquid chromatography tandem mass spectrometer (UHPLC–MS/MS) method for the identification and quantification of carbenoxolone in mouse blood and brain tissue. Twenty mice were injected intraperitoneally with 25 mg/kg carbenoxolone and brain tissue and blood were collected for analysis. Blood concentrations (mean ± SD) at 15, 30, 60 and 120 min were determined to be (n = 5) 5394 ± 778, 2636 ± 836, 1564 ± 541 and 846 ± 252 ng/mL, respectively. Brain concentrations (mean ± SD) at 15, 30, 60 and 120 mins were determined to be (n = 5) 171 ± 62, 102 ± 35, 55 ± 10 and 27 ± 9 ng/g, respectively. The analysis of these specimens at the four different time points resulted in blood and brain half‐lives in mice of ~43 and 41 min, respectively. The UHPLC–MS/MS method was determined to be sensitive and robust for quantification of carbenoxolone. 相似文献
78.
Bioassay‐guided Isolation and Antioxidant Activity of Sulfur‐containing Compounds from Clinacanthus nutans 下载免费PDF全文
Hazrulrizawati Abd Hamid Izzah Hayati Yahya Mashitah M. Yusoff Seema Zareen 《中国化学会会志》2016,63(12):1033-1037
Clinacanthus nutans has been used in traditional herbal medicine for cancer prevention, but the specific bioactive compounds responsible for the observed activities have not been explored. Different polar solvents such as methanol, chloroform, ethyl acetate, and hexane were used for the extraction. The extracts, fractions, and isolated compounds were subjected to DPPH and ferric reducing antioxidant potential (FRAP) assays. Methanol extracts show significant free‐radical scavenging activity of 69.09% in DPPH and 56.49% FRAP. Purification of MeOH extracts afforded the fraction FB28 and two new sulfur‐containing compounds, named clinamide D and E ( 1 , 2 ). Compound ( 1 ) proved to be more active with an IC50 value for DPPH radical scavenging of 118.27 ± 0.01 µg/mL and reduction of Fe3+–TPTZ complex of 386.24 ± 0.02, higher than that of the standard ascorbic acid. Sulfur‐containing compounds isolated from C. nutans is a potential natural antioxidant. 相似文献
79.
80.
Mostafa M. Amini Amirreza Azadmher Hamid Reza Bijanzadeh Nasser Hadipour 《Journal of inclusion phenomena and macrocyclic chemistry》2006,54(1-2):77-80
Behavior of {[(CH3)2SnCl2·H2O]2·18-crown-6}n in solution have been investigated by HMBC NMR. The results show that coordination of water to tin containing species and
its hydrogen bonding to crown ether remains intact in non-coordinating solvent in contrast to coordinating solvent. H-NMR
reveals that the chemical shift of water in complex varies by solvent of crystallization. 相似文献