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41.
Hakan Durmaz Aydan Dag Duygu Gursoy A. Levent Demirel Gurkan Hizal Umit Tunca 《Journal of polymer science. Part A, Polymer chemistry》2010,48(7):1557-1564
Multiarm star triblock terpolymers were obtained by using two different click reactions sequentially: Cu(I) catalyzed azide–alkyne and Diels–Alder. The synthetic strategy is described as follows: (poly(methyl methacrylate))n‐(polystyrene)m‐poly(divinyl benzene)) ((PMMA)n‐(PS)m‐polyDVB) multiarm star diblock copolymer was first obtained from an azide–alkyne click reaction of (alkyne‐PS)m‐polyDVB multiarm star polymer with α‐anthracene‐ω‐azide PMMA (anth‐PMMA‐N3), followed by a Diels–Alder click reaction of the anthracene groups at the star periphery with α‐maleimide poly (tert‐butyl acrylate) (PtBA‐MI) or α‐maleimide poly(ethylene glycol) (PEG‐MI) leading to target (PtBA)k‐(PMMA)n‐(PS)m‐polyDVB and (PEG)p‐(PMMA)n‐(PS)m‐polyDVB multiarm star triblock terpolymers. The hydrodynamic diameter of individual multiarm star triblock terpolymers were measured by dynamic light scattering (DLS) to be ~24–27 nm in consistent with the atomic force microscopy (AFM) images on silicon substrates. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 1557–1564, 2010 相似文献
42.
Perturbation theory in a framework of iteration methods 总被引:1,自引:0,他引:1
In a previous paper [J. Phys. A 36 (2003) 11807], we introduced the ‘asymptotic iteration method’ for solving second-order homogeneous linear differential equations. In this Letter, we study perturbed problems in quantum mechanics and we use the method to find the coefficients in the perturbation series for the eigenvalues and eigenfunctions directly, without first solving the unperturbed problem. 相似文献
43.
Ertuğrul Gazi Sağlam Sevcan Erden Özgür Tutsak Dilek Eskiköy Bayraktepe Zehra Yazan Durmuş Hakan Dal 《Phosphorus, sulfur, and silicon and the related elements》2017,192(3):322-329
Some 1,3-dithiadiphosphetane 2,4-disulfides (X2P2S4, X: Fc, FcLR; X: CH3O?C6H4?, LR) were allowed to react with alcohols to obtain dithiophosphonic acids (X(OR)PS2H). These were converted to the corresponding ammonium salts. The salts were of the structures [Fc(OR)PS2]?[NH4]+, R: 3-methyl-1-butyl- for I; 1-phenyl-1-propyl- for II; 3-pentyl- for III; 3-phenyl-1-propyl- for IV and [CH3O?C6H4(OR)PS2]?[NH4]+, R: 3-methyl-1-butyl- for V and 1-phenyl-1-propyl- for VI. To the best of our knowledge, all the compounds except V were prepared for the first time.The compounds synthesized were characterized by elemental analysis, NMR (1H, 13C, 31P), MS, FTIR, and Raman spectroscopies. Electrochemical behaviors of I–VI at disposable pencil graphite electrode (PGE) were investigated by using cyclic voltammetry (CV) and square-wave voltammetry (SWV). Adsorption and diffusion patterns of all the compounds on the PGE were also studied.Two electroactive groups were identified in the compounds I–IV and only one in V and VI. The ferrocenyl groups of I-IV were oxidized at around 0.4 V. The same compounds display a second, more intense CV band at 0.8 V. The corresponding band for the compounds V–VI appears at around 0.6 V with a much weaker intensity. It is suggested that the ferrocenyl group introduced into the structures stabilizes the radical species formed as the product of the oxidation of the dithiophosphonato group. 相似文献
44.
We have theoretically investigated the low energy conformers of neutral glycine (NH(2)CH(2)COOH) and its isomer methylcarbamic acid (CH(3)NHCOOH) in the gas phase. A total of 16 different levels of the theory, including CCSD(T), MP2 and B3LYP methods with various Pople and Dunning type basis sets with and without polarization and diffuse functions were used. We found eight low energy glycine conformers, where the heavy atoms in three have a planar backbone, and four low energy methylcarbamic acid conformers all with non-planar backbones. Interestingly at all levels of theory, we found that the most stable methylcarbamic acid conformer is significantly lower in energy than the lowest energy glycine conformer. The MP2 level and single point CCSD(T) calculations show the lowest energy methylcarbamic acid conformer to be between 31 to 37 kJ mol(-1) lower in energy than the lowest energy glycine conformer. These calculations suggest that methylcarbamic acid might serve as a precursor to glycine formation in the Interstellar Medium (ISM). We also report the theoretical harmonic vibrational frequencies, infrared intensities, moment of inertia, rotational constants and dipole moments for all of the conformers. In order to understand how glycine or methylcarbamic acid might be formed in the ISM, larger calculations which model glycine or its isomer interacting with several surrounding molecules, such as water, are needed. We demonstrate that B3LYP method should provide a reliable and computationally practical approach to modeling these larger systems. 相似文献
45.
Hakan Sayinc Mateusz Wysmolek Jose M. Chavez Boggio Roger Haynes Martin M. Roth Uwe Morgner Jörg Neumann Dietmar Kracht 《Applied physics. B, Lasers and optics》2013,110(3):299-302
To our knowledge, efficient generation of broadband four-wave mixing cascades centered at 1 μm and spanning 600 nm is experimentally demonstrated for the first time. This frequency comb is generated from a two-tone seed with a maximum peak power of 25 W in a low-dispersion photonic crystal fiber. It consists of up to 44 new idler waves generated symmetrically around the seed. 相似文献
46.
A simply supported Euler-Bernoulli beam with an intermediate support is considered. Non-linear terms due to immovable end conditions leading to stretching of the beam are included in the equations of motion. The concept of non-ideal boundary conditions is applied to the beam problem. In accordance, the intermediate support is assumed to allow small deflections. An approximate analytical solution of the problem is found using the method of multiple scales, a perturbation technique. Ideal and non-ideal frequencies as well as frequency-response curves are contrasted. 相似文献
47.
The purpose of the study was to examine the effectiveness of the Iowa Chautauqua Professional Development Program in terms of changes in concept mastery, use of process skills, application of science concept and skills, student attitudes toward science, student creativity, and student perceptions regarding their science classrooms. Participants were 12 teachers who agreed to participate in an experimental study where an inquiry approach was utilized with one section and traditional strategies in another section. A total of 24 sections of students were enrolled in inquiry sections (365 students) and traditional sections (359 students). The data collected were analyzed using quantitative methods. The results are tabulated and contrasted for students enrolled in the two sections for each teacher. The results indicate that student use and understanding of science skills and concepts in the inquiry sections increased significantly more than they did for students enrolled in typical sections in terms of process skills, creativity skills, ability to apply science concepts, and the development of more positive attitudes. 相似文献
48.
Hakan Yeti?kin 《Applied mathematics and computation》2010,216(7):1896-1902
The existence and uniqueness for the solution of the problem of determining the v(x,t) potential in the Schrödinger equation from the measured final data ψ(x,T)=y(x) is investigated. For the objective functional , it is proven that the problem has at least one solution for α?0, and has a unique solution for α>0. The necessary condition for solvability the problem is stated as the variational principle. 相似文献
49.
We study the accumulation of an elliptic fixed point of a real analytic Hamiltonian by quasi-periodic invariant tori. We show that a fixed point with Diophantine frequency vector ω 0 is always accumulated by invariant complex analytic KAM-tori. Indeed, the following alternative holds: If the Birkhoff normal form of the Hamiltonian at the invariant point satisfies a Rüssmann transversality condition, the fixed point is accumulated by real analytic KAM-tori which cover positive Lebesgue measure in the phase space (in this part it suffices to assume that ω 0 has rationally independent coordinates). If the Birkhoff normal form is degenerate, there exists an analytic subvariety of complex dimension at least d + 1 passing through 0 that is foliated by complex analytic KAM-tori with frequency ω 0. This is an extension of previous results obtained in [1] to the case of an elliptic fixed point. 相似文献
50.
Selimefendigil Fatih Oztop Hakan F. Chamkha Ali J. 《Journal of Thermal Analysis and Calorimetry》2019,135(1):325-340
Journal of Thermal Analysis and Calorimetry - In this study, fluid flow and heat transfer in a vertical lid-driven CuO–water nanofluid filled square cavity with a flexible fin attached to its... 相似文献