近场影响消除法测量声吸收系数

本文采用数值模拟方法理论研究了活塞式辐射器的辐射近场和采用“大”尺寸接收器接收对声场的平滑作用以及近场(及其过渡区域)对测量声吸收系数的影响.计算表明,在近场及其附近,用通常的方法测量声吸收系数将产生很大的误差.通过分析误差产生的原因,本文提出了近场影响消除法测量声吸收系数,并对a/λ=3、9,b=0、0.5a、a(a,b分别是辐射器和接收器半径)几种情况进行了数值模拟计算,结果表明,采用这种方法不仅能在近场区域进行测量,而且具有较高的测量精度。     

覆黏弹层加肋双层板的声反射

为评估覆盖层的吸声性能,研究黏弹层在无限大周期加肋双层板背衬下的声反射。首先通过弯曲波与Lamb波的比较,揭示了板近似理论不适用于黏弹性板的原因。为此采用(黏)弹性理论处理(黏)弹性板,而肋板的处理则采用板近似理论,并用Hull提出的方法解决肋板和平板的耦合问题,得到反射声场的解。与板近似理论计算加肋双层板声反射的结果进行比较验证了本文方法的正确性,对反射系数进行计算分析了背衬对声反射的影响,定义平均反射系数比较了不同覆盖层的性能。结果表明,频率较低时覆盖层无法有效抑制背衬的影响,板间流体层与双层板的耦合作用引起共振散射,肋板与双层板的耦合作用降低声反射。     

Palladium-catalyzed haloallylation of aromatic ynol ethers with allyl chlorides: a highly regio- and stereoselective approach to (1E)-α-chloroenol ethers

Described herein is a Pd-catalyzed haloallylation of aromatic ynol ethers and allyl chlorides, allowing facile access to (1E)-α-chloroenol ethers in a highly regio- and stereoselective manner. The synthetic utility of this method is demonstrated well by the synthesis of the stereodefined multisubstituted enol ethers and α-allylated carbonyl compounds.     

A Generalized Floating-Point Representation and Manipulation of Quantum Signals Based on IEEE-754

Quantum information processing has become increasingly attractive in the past few decades due to its extraordinary performance. However, few results of quantum signal and its related manipulations based on quantum computation have emerged in recent years. The paper proposes a generalized floating-point representation of quantum signals (GFPRQS), which is improved by represent an arbitrary quantum signal with p + q qubits. In a floating-point representation, although every number is approximated using three registers, this format allows to represent a much larger range of values with a given number of qubits than a fixed-pointing representation. Based on GFPRQS representation, we first present the quantum circuits to accomplish basic signal modules (i.e., multiplyby 2 module, halving module, comparator module, swap module, etc,). And then, we design a composite module (i.e., sort module). At the end of the paper, to indicate the usability of the model GFPRQS an example involving the mean filtering and its quantum circuit is given.

     

A Surface Enhanced Raman Scattering (SERS) microdroplet detector for trace levels of crystal violet

We report on a microfluidic platform that integrates a winding microdroplet chip and a surface-enhanced Raman scattering (SERS) detection system for trace determination of crystal violet (CV). Colloidal silver was applied to generate SERS. Compared to the continuous flow microfluidic system, the microdroplet based detection described here effectively eliminates any memory effects. Effects of flow pattern, droplet size, surfactant, and position of detection were optimized. Under optimal conditions, there is a linear correlation between signal and the concentration of CV in the 10 nM to 800 nM range, with a correlation coefficient (R²) of 0.9967. The limit of detection in water is 3.6 nM.

Monitor adsorption of acetone vapor to a room temperature ionic liquid 1-octyl-3-methylimidazolium bromide by a langasite crystal resonator

In this work, the responses of a Y-cut langasite crystal resonator (LCR) in liquid phases were investigated by an impedance analysis method. The resonant frequency (f_S) of the LCR decreases with increasing mass loading on the active surface of the resonator. The LCR can be operated at the resonant frequency that is down to about 60% of the fundamental frequency (f₀) under foreign mass loading. The frequency-mass coefficient of the Y-cut LCR is theoretically derived to be −1.282 × 10⁻⁶, which is supported by the experimental results. The resonant frequency of the LCR decreases linearly while its motional resistance (R_m) increases linearly with increasing (ρη)^1/2, where η and ρ are the viscosity and density of the liquid phase, respectively. The slopes of the plots of f_S versus (ρη)^1/2 and R_m versus (ρη)^1/2 are related to the region of (ρη)^1/2 because of the influence of surface roughness of the LCR. The changes in viscodensity of a room temperature ionic liquid (RTIL), 1-octyl-3-methylimidazolium bromide ([C₈MIM][Br]), were investigated in acetone vapor adsorption and ascending temperature processes by the LCR. The adsorption of acetone into [C₈MIM][Br] causes a significantly drop in viscosity of the [C₈MIM][Br] film, which induces an increase in f_S and a decrease in R_m for the RTIL modified LCR. When the thickness of [C₈MIM][Br] film is less than the decay distance of the thickness-shear wave, a mass effect model is observed in the early adsorption process. Based on the responses of the LCR, the viscodensity of the [C₈MIM][Br] film as well as the adsorbed amounts of acetone into film were monitored in real time during the adsorption or desorption processes.     

Improving the electrochemical performances of active carbon-based supercapacitors through the combination of introducing functional groups and using redox additive electrolyte

High-performance and low-cost electrochemical capacitors (ECs) are essential for large-scale applications in energy storage. In this work, the specific capacitance of active carbon (AC) electrode was significantly improved through the combination of introducing functional groups on the surface of AC and adding redox-active molecules (K₃Fe(CN)₆) into 2?M KOH aqueous electrolytes. The surface-oxygen functionalized AC (FAC) was synthesized using HNO₃ echoed as the electrode and 2?M KOH with 0.1?M K₃Fe(CN)₆ as the electrolyte. The surface functional groups of the AC not only contribute to the pseudocapacitance but also increase the active sites of the electrode/electrolyte interface, which enhances the electrochemical activity of the Fe(CN)₆^3?/Fe(CN)₆^4? redox pair, thus leading to high capacitance. In the redox electrolyte, the specific capacitance was much higher in 229.17?F?g^?1 (1?A?g^?1) achieved for those FAC than in raw AC (only 147.06?F?g^?1). Similarly, the FAC electrode suggested high energy density and extended cycling stability in the KOH?+?K₃Fe(CN)₆ electrolyte.     

高效液相色谱法测定伸筋丹中士的宁含量

采用高效液相色谱法（ＨＰＬＣ）测定了中成药伸筋丹中士的宁含量。色谱条件：氰基柱并加同种类预柱；流动相：甲醇－水－乙酸－三乙胺（９８００：１５５：３０：１５）；ｐＨ６．７；流速：１．０ｍＬ／ｍｉｎ；紫外检测，波长２５４ｎｍ；在４～２０ｍｇ／Ｌ浓度范围内，士的宁的峰面积Ａ与浓度Ｃ间的回归方程为：Ａ＝－７．０１×１０~３＋９．０８×１０~５Ｃ（ｒ＝０．９９９９）；外标法定量，方法精密度ＲＳＤ＝１．９１％（ｎ＝６）。     

Preparation of L-Cys–Au colloid self-assembled nanoarray electrode based on the microporous aluminium anodic oxide film and its application to the measurement of dopamine

A novel method for fabricating a nanoarray electrode combining the template technique with the self-assembled approach was developed. The glassy carbon electrode was modified with the Au nanoarray using micropores of aluminum anodic film as template. Then, the Au nanoarray electrode was self-assembled with L-cysteine (L-Cys) and gold colloid, respectively. In order to evaluate the electrochemical characteristics of L-Cys–Au colloid self-assembled nanoarray electrode, was chosen as molecule probe and cyclic voltammetry was used. In addition, the functional nanoarray electrode was applied to measuring dopamine (DA). The resulting L-Cys–Au colloid self-assembled nanoarray electrode demonstrated that the linear calibration range extended over three orders of magnitude of DA concentrations (1.0 × 10⁻⁹–1.0 × 10⁻⁶ mol/L) and the detection limit was 5.0 × 10⁻¹⁰ mol/L.     

二维圆周光综合孔径阵的优化排列及其成像特性研究

光综合孔径成像的原理是应用干涉原理在空间频率域中进行采样,并通过傅里叶反变换或其他数值变换方法得到空间分辨力远高于单个孔径成像系统的目标图像。由若干个相同的小孔径在二维圆周上优化排列组成的综合孔径成像系统可以在二维空间频率域中实现较为均匀分布的、具有无冗余度的采样点覆盖,为高质量实时成像提供了一个有效的途径。运用模拟退火算法对由7～16个子孔径组成的二维圆周综合孔径阵列进行优化排列。并依据光学衍射成像原理,从空域和频域两个方面详细分析了二维圆周上优化排列与均匀排列光综合孔径阵的成像特性。对7～16个子孔径组成的光综合孔径的仿真结果表明：无论是在空域还是频域上,子孔径直径增大、孔径数目增多以及综合孔径阵的优化排列都是有利于提高成像质量的。但综合后的子孔径的直径的增大,虽然能获得极高的角分辨力,却并不利于成像质量的提高。