Rational construction of 3D pillared metal-organic frameworks: synthesis, structures, and hydrogen adsorption properties

In our efforts toward rational design and systematic synthesis of 'pillar-layer' structure MOFs, three porous MOFs have been constructed based on [Zn(4)(bpta)(2)(H(2)O)(2)] (H(4)bpta = 1,1'-biphenyl-2,2',6,6'-tetracarboxylic acid) layers and three different bipyridine pillar ligands. The resulted MOFs show similar structures but different pore volume and window size depending on the length of pillar ligands which resulted in distinct gas adsorption properties. In the three MOFs, [Zn(4)(bpta)(2)(4,4'-bipy)(2)(H(2)O)(2)]·(DMF)(3)·H(2)O (1) (DMF = N,N'-dimethylformamide and 4,4'-bipy = 4,4'-bipyridine) reveals selective adsorption of H(2) over N(2) and O(2) as the result of narrow pore size. [Zn(4)(bpta)(2)(azpy)(2)(H(2)O)(2)]·(DMF)(4)·(H(2)O)(3) (2) and [Zn(4)(bpta)(2)(dipytz)(2)(H(2)O)(2)]·(DMF)(4)·H(2)O (3) (azpy =4,4'-azopyridine, dipytz = di-3,6-(4-pyridyl)-1,2,4,5-tetrazine) reveal pore structure change upon different activation conditions. In addition, the samples activated under different conditions show distinct adsorption behaviors of N(2) and O(2) gases. Furthermore, hydrogen adsorption properties of activated 1-3 were studied. The results indicated that the activation process could affect the hydrogen enthalpy of adsorption.     

飞秒激光诱导水光学击穿阈值

为了研究飞秒激光诱导水光学击穿阈值随激光脉冲参数的变化关系,采用四阶RungeKutta方法对飞秒激光诱导水光学击穿的椭球体模型进行了不同脉宽(40～540fs)、波长(400～1200nm)和光斑尺寸(0～200μm)下的数值模拟。通过控制变量法得出阈值光强与这些激光脉冲参数的关系曲线图,据此定性分析了阈值光强与激光脉冲参数的变化特征趋势。应用光强与功率、能量、辐照曝光量和电场强度之间的关系,得到了它们随激光脉冲参数脉宽、波长和光斑尺寸的动态关系,这为进一步研究飞秒激光与水和含水介质的相互作用提供了理论依据。     

高温超导薄膜J_c与微波非线性相关性研究

采用微带谐振器技术研究高温超导薄膜的微波非线性问题,介绍了微波非线性的测试方法,描述了测试现象,定量表征了微波功率非线性。将微波非线性与临界电流密度Jc大小的关联性进行分析研究,发现两者关联性弱;同时验证了功率压缩测试方法对高温超导薄膜微波非线性的研究是可行的。     

Further Results on the Drazin Inverse of Tensors via Einstein Product

In this paper,we give further results on the Drazin inverse of tensors via the Einstein product.We give a limit formula for the Drazin inverse of tensors.By using this formula,the representations for the Drazin inverse of several block tensor are obtained.Further,we give the Drazin inverse of the sum of two tensors based on the representation for the Drazin inverse of a block tensor.     

LD-pumped passively Q-switched Nd:YVO/LBO red laser with V:YAG

An LD-pumped Nd:YVO₄ passively Q-switched by V:YAG and intracavity frequency doubled by LBO red pulse laser at 671 nm was presented. With 1.6 W incident pump power, average output power of 53 mW, pulse duration (FWHM) of 29.5 ns, pulse repetition rate of 37.2 kHz, peak power of 48.3 W and single-pulse energy of 1.43 μJ were obtained. The stability of pulse energy and repetition rate was better than 3% for 4 h.     

The exchange bias and coercivity of FM/AFM films: Monte Carlo simulation

The exchange bias (H_E) and coercivity (H_C) of the ferromagnet/antiferromagnet (FM/AFM) films have been simulated with Monte Carlo method. The simulated results indicate that, the value of H_E decreases with increasing temperature, and the values of H_E and the blocking temperature T_b at which H_E=0 reduce evidently with decreasing absolute value of interlayer exchange coupling JI. It also is found that for the large absolute values of JI, the maximum in H_C occurs very close to T_b. At the same time, it is observed that the diluted ratio of FM at FM/AFM interface influences clearly the value of H_E. The simulated results are consistent with the experimental facts. The maximum behaviour in the H_C−T curves has been explained by the interplay of the softening of some fraction of the spins in the AFM layer near T_N′ and the disorder of the spins in FM layer near Curie temperature T_C.     

多时滞线性切换系统的稳定性及其反馈镇定

研究了具有多时滞线性切换系统的稳定性及其反馈镇定问题,利用完备性条件、矩阵分解与二次Lyapunov泛函,给出了多时滞切换系统渐近稳定的充分条件和切换律设计方法.在此基础上,研究了这类系统的镇定控制问题,设计了保证系统时滞独立渐近镇定的控制器.     

Design, synthesis, and characterization of indole derivatives

In this work, two novel indole–hydrazone analogues were prepared by condensation reactions between 5-methoxyindole-3-carboxaldehyde and isobutyric acid hydrazide or hydrazine hydrate, respectively. The structural properties of the synthetic products were confirmed by FT-IR, ¹H NMR, and elemental analysis, while the thermal stabilities and purities were measured by melting point determination. The inhibition effect of compounds was predicted by quantum treatment. The results showed that these compounds can be used as inhibitors.     

SUMMATION OF FOURIER SERIES WITH PARAMETER BY LAPLACE TRANSFORMS

In this paper,the theorems concerning the summation of Fourier series withparameter are given by using the Laplace transforms.By means of the known result ofLaplace transforms,many new,important problems of summation of Fourier serieswith parameter in mechanics can be solved.