Catalytic properties of mesoporous materials supported heteropoly acids for Baeyer-Villiger oxidation of cyclic ketones

Three mesoporous molecular sieves loaded silicotungstic acids, named HSiW/SBA-15, HSiW/MCM-41, HSiW/MCM-48, were prepared and characterised by XRD, FT-IR, TEM and SEM. The catalytic performance of the prepared materials for the Baeyer-Villiger oxidation of cyclic ketones was carried out in the presence of 30%H₂O₂ under mild conditions. These loading materials were proved to be efficient and reusable catalysts, they all exhibited excellent catalytic performance for the Baeyer-Villiger oxidation of cyclic ketones with 30% H₂O₂ as oxidant. Many cyclic ketones were efficiently converted to the corresponding lactones with up to 90% conversions and high selectivities under the optimum reaction conditions.

Cyclic ketones were efficiently oxidised by mesoporous materials sopported silicotungstic acid to the corresponding lactones with 30%H₂O₂ as oxidant. All of the catalysts showed promising recyclability in the reactions.     

无绝缘高温超导双饼线圈的瞬态电热特性分析

无绝缘高温超导线圈具有良好的电热稳定性和机械紧凑性,但其充电过程中却有明显的磁场延迟现象。为详细了解无绝缘高温超导线圈励磁过程的瞬态特性,建立了无绝缘高温超导线圈的同轴圆环等效电路模型。通过绕制一个670匝的无绝缘高温超导双饼线圈,在液氮温度下进行不同充电速率的励磁实验,初步验证了等效电路模型的正确性。基于该模型,针对线圈励磁过程的充电和恒流阶段,仿真得到了线圈各匝的径向电流分布规律和电热损耗特性。     

Investigation of active-region doping on InAs/GaSb long wave infrared detectors

The eight-band κ·p model is used to establish the energy band structure model of the type-II InAs/GaSb superlattice detectors with a cut-off wavelength of 10.5μm,and the best composition of M-structure in this type of device is calculated theoretically.In addition,we have also experimented on the devices designed with the best performance to investigate the effect of the active region p-type doping temperature on the quantum efficiency of the device.The results show that the modest active region doping temperature(Be:760℃)can improve the quantum efficiency of the device with the best performance,while excessive doping(Be:>760℃)is not conducive to improving the photo response.With the best designed structure and an appropriate doping concentration,a maximum quantum efficiency of 45% is achieved with a resistance-area product of 688?·cm^2,corresponding to a maximum detectivity of 7.35×10^11cm·Hz^1/2/W.     

Cryopreservation of in vitro grown shoot tips of Diospyros kaki thunb. using different methods

The objective of this study was to compare the potential of different cryopreservation strategies for in vitro shoot tips of Diospyros kaki Thunb. The treatments consisted of three different cryopreservation methods: vitrification, droplet-vitrification and modified droplet-vitrification. The following variables were assessed: cold acclimation, sucrose concentration in the preculture medium and PVS2 treatment time. A higher average survival level was obtained using the modified droplet-vitrification method compared to the other two methods.     

Embedding color watermarks in color images based on Schur decomposition

In this paper, a blind dual color image watermarking scheme based on Schur decomposition is introduced. This is the first time to use Schur decomposition to embed color image watermark in color host image, which is different from using the binary image as watermark. By analyzing the 4 × 4 unitary matrix U via Schur decomposition, we can find that there is a strong correlation between the second row first column element and the third row first column element. This property can be explored for embedding watermark and extracting watermark in the blind manner. Since Schur decomposition is an intermediate step in SVD decomposition, the proposed method requires less number of computations. Experimental results show that the proposed scheme is robust against most common attacks including JPEG lossy compression, JPEG 2000 compression, low-pass filtering, cropping, noise addition, blurring, rotation, scaling and sharpening et al. Moreover, the proposed algorithm outperforms the closely related SVD-based algorithm and the spatial-domain algorithm.     

Photonic crystal fiber with high birefringence and low confinement loss

In this paper, a highly birefringent index-guiding photonic crystal fiber with low confinement loss is proposed by enlarging the central row of air holes in the structure. By employing the multipole method, properties of this structure, including the effective index, birefringence and confinement loss, are investigated. Simulation results indicate that high birefringence of 1.65 × 10⁻³ can be reached at the wavelength of 1.55 μm, and a low confinement loss on the order of 10⁻⁶ dB/km can be achieved at the same wavelength. Moreover, the impacts of air hole sizes on birefringence and confinement loss are also analyzed in detail.     

A blind color image watermarking based on DC component in the spatial domain

Color image watermarking has become essential and important copyright protection or authentication scheme. It is noted that most of the existing color image watermarking algorithms are performed only in the single domain (spatial domain or frequency domain), and not to integrate these merits of the different domains. By utilizing the generating principle and distribution feature of the direct current (DC) coefficient, a novel blind watermarking algorithm is proposed for color host images in this paper. Firstly, the Y luminance of host image is divided into 8 × 8 sub-blocks and the DC coefficients of each block are directly calculated in the spatial domain without DCT transform. Secondly, according to the watermark information and the quantization step, the DC coefficients are calculated and their increments are further utilized to modify directly the values of all pixels in the spatial domain instead of the DCT domain to embed watermark. When watermark extraction, only the watermarked image and the quantization step are needed in the spatial domain. Experimental results show that the proposed method not only can resist both traditional signal processing attacks and geometric attacks, but also has more efficient in computational complexity. Comparisons also demonstrate the advantages of the method.     

Titanium carbonitride films on cemented carbide cutting tool prepared by pulsed high energy density plasma

Hard films prepared by pulsed high energy density plasma (PHEDP) are characterized by high film/substrate adhesive strength, and high wear resistance. Titanium carbonitride (TiCN) films were deposited onto YG11C (ISO G20) cemented carbide cutting tool substrates by PHEDP at room temperature. XRD, XPS, SEM, AES, etc. were adopted to analyze the phases (elements) composition, microstructure and the interface of the films, respectively. The results show that, the uniform dense films are composed of grains ranging from 70 to 90 nm. According to the AES result, there is a broad transition layer between the film and the substrate, due to the ion implantation effect of the PHEDP. The transition layer is favorable for the film/substrate adhesion.     

Li2O-2B2O3熔体的物性研究

系统测量了四硼酸锂(Li2O-2B2O3)熔体的密度ρ、表面张力γ随着温度的变化规律,实验结果表明在1100K到1500K范围内Li2O-2B2O3高温熔体的密度和表面张力随着温度的升高均线性减小.通过实验数据拟合得出熔体密度与温度关系为ρ(T)=2.574-4.89×10-4T,熔点处LiO-2B2O3熔体的密度为1.992g/cm3;熔体表面张力与温度关系的拟合公式为γ=262.8-4.59×10-2T.     

Room temperature continuous wave operation of 1.33-μm InAs/GaAs quantum dot laser with high output power

Continuous wave operation of a semiconductor laser diode based on five stacks of InAs quantum dots (QDs) embedded within strained InGaAs quantum wells as an active region is demonstrated. At room temperature, 355-Mw output power at ground state of 1.33-1.35μm for a 20-μm ridge-waveguide laser without facet coating is achieved. By optimizing the molecular beam epitaxy (MBE) growth conditions,the QD density per layer is raised to 4 × 1010 cm-2. The laser keeps lasing at ground state until the temperature reaches 65 ℃.