Penicillones A and B, two novel polyketides with tricyclo [5.3.1.0] undecane skeleton, from a marine-derived fungus Penicillium terrestre

Two novel polyketides, penicillones A (1) and B (2), with tricyclo [5.3.1.0^3,8] undecane skeleton, were isolated from Penicillium terrestre. Their structures and relative stereochemistries were determined on the basis of spectroscopic methods. The absolute configuration of 2 was established by the modified Mosher’s method, while that of 1 was deduced from the similar CD absorptions of 1 and 2. Compound 1 showed weak cytotoxicities against P338 and A-549 cell lines, while 2 was inactive against P388.     

Synthesis and Crystal Structure of 4,7‐Diaryl‐5‐oxo‐4H‐benzo[b]pyran Derivatives

A green and convenient approach to the synthesis of a series of 4,7‐diaryl‐5‐oxo‐4H‐benzo[b]pyran derivatives from appropriate aromatic aldehydes and 5‐aryl‐1,3‐cyclohexanedione with malononitrile in the presence of dilute HCl as catalyst (30 mmol/L) is described. This method provides several advantages such as environmental friendliness, low cost, high yields, and simple work up procedure. The structures of all compounds were characterized by infrared (IR), mass spectrometry (MS), ¹H NMR, and elemental analysis. The crystal structure of trans/cis‐2‐amino‐3‐cyano‐7‐(4′‐methoxo‐phenyl)‐4‐phenyl‐5‐oxo‐4H‐benzo[b]pyran, g , was determined by single crystal X‐ray diffraction analysis. The crystal of compound g belongs to monoclinic with space group P 21/c, a = 8.477(3) nm, b = 18.948(6) nm, c = 24.915(7) nm, α = 90.00°, β = 107.388(11)°, γ= 90.00°, Z = 8, V = 3.819(2) nm³, R₁ = 0.0754, wR₂ = 0.2042.     

求解一类二阶非线性偏微分方程的新算法

在再生核空间中给出一类二阶非线性偏微分方程的一个新的求解方法,近似解un(x)是通过在再生核空间中截断精确解u(x)而得到的,最后,通过一个数值算例来说明该方法是有效的.     

Polarization controlled multiwavelength switchable erbium-doped fiber laser based on high birefringence few-mode fiber loop mirror

A multiwavelength switchable erbium-doped fiber laser with linear cavity is proposed and experimentally demonstrated. It is based on a fiber loop mirror incorporating a piece of high birefringence few-mode fiber and polarization controller. Due to dependence of its reflection properties on the polarization controllers, the fiber laser can operate in the random combination of three wavelengths by only adjusting the polarization controllers in the linear cavity. The wavelengths involved in the switching operation are determined by the merged Sagnac and intermodal interferences elicited in the fiber loop mirror. The optical signal to noise extinction ratio of every oscillation line is higher than 40 dB and power fluctuation less than 0.5 dB.     

高功率准连续波腔内和频全固态黄光激光器

报道了高功率准连续波腔内和频全固态黄光激光器的研究结果.为获得高功率的黄光输出,首先,激光器采用准连续方式运转,在保持抽运水平的条件下降低热效应,从而提高光束质量和光光转换效率;第二,采用热近非稳腔腔型设计,双棒串接补偿热致双折射技术,获得大基模体积高光束质量的基频光;第三,通过优化腔型,采用L型共折叠臂平-凹对称腔,使两束基频光达到空间重合且满足功率配比.通过这些方法,得到了输出功率7.6W,重复频率1.1kHz的准连续波黄光输出.据我们所知,这是目前腔内和频方案所获得的最高功率全固态黄光输出. 关键词： 黄光激光 腔内和频 Nd：YAG激光 全固态激光器     

Generation and application of twin beams from an optical parametric oscillator including an alpha-cut KTP crystal

Measurement slight amounts of absorption of light with accuracy beyond the standard quantum limit has been experimentally demonstrated. The quantum-correlated twin beams used in the measurement were generated from a nondegenerate optical parametric oscillator including an alpha-cut KTiOPO(4) crystal pumped by an intracavity frequency-doubled Nd:YAG laser. The noise in the intensity difference between the twin beams was reduced by 88% below the standard quantum limit (SQL). The signal-to-noise ratio was improved by 7 dB with respect to the SQL of the total light employed in the experiment and by 4 dB with respect to that of the signal light.     

可调谐集成光学Ti:LiNbO3光波导定向耦合滤波器

波分复用技术是当今光纤通信系统中的关键技术之一。具有增加光纤通信系统容量的巨大潜力,集成光学复用技术对于单模光纤通信系统特别重要本文给出了一种集成光学复用器件的设计和制作,这种集成光学滤波器是在之切LiNbO₃衬底上用非对称钛扩散条波导定向耦合器构成,它适于1.32μm和1.55μm波长耦合滤波。为了使单模光纤和条波导有效耦合,我们研制出了硅V型槽,并给出了一种光纤与波导的连接结构。提供了一种切实可行的途径。     

过渡金属原子团簇的电子能谱与吸收光谱

文献〔１〕从理论上阐明了金属原子团簇的公有化电子能谱具有分裂能级的特点，因而其公有化电子具有吸光的特性，并计算了Ｃｕ与Ａｌ的金属原子团簇的吸收光谱。然后，在文献〔２〕中用此理论计算了碱金属原子团簇的电子能谱与吸收光谱。现进一步推广此理论来计算过渡金属原子团簇的电子能谱与吸收光谱。