全文获取类型
收费全文 | 13466篇 |
免费 | 2446篇 |
国内免费 | 2469篇 |
专业分类
化学 | 11094篇 |
晶体学 | 211篇 |
力学 | 718篇 |
综合类 | 201篇 |
数学 | 1627篇 |
物理学 | 4530篇 |
出版年
2024年 | 12篇 |
2023年 | 154篇 |
2022年 | 255篇 |
2021年 | 321篇 |
2020年 | 442篇 |
2019年 | 523篇 |
2018年 | 432篇 |
2017年 | 362篇 |
2016年 | 704篇 |
2015年 | 703篇 |
2014年 | 855篇 |
2013年 | 1008篇 |
2012年 | 1098篇 |
2011年 | 1225篇 |
2010年 | 961篇 |
2009年 | 980篇 |
2008年 | 1165篇 |
2007年 | 999篇 |
2006年 | 890篇 |
2005年 | 743篇 |
2004年 | 680篇 |
2003年 | 586篇 |
2002年 | 775篇 |
2001年 | 622篇 |
2000年 | 475篇 |
1999年 | 300篇 |
1998年 | 195篇 |
1997年 | 137篇 |
1996年 | 142篇 |
1995年 | 110篇 |
1994年 | 98篇 |
1993年 | 96篇 |
1992年 | 52篇 |
1991年 | 51篇 |
1990年 | 29篇 |
1989年 | 23篇 |
1988年 | 29篇 |
1987年 | 23篇 |
1986年 | 18篇 |
1985年 | 22篇 |
1984年 | 14篇 |
1983年 | 13篇 |
1982年 | 4篇 |
1981年 | 9篇 |
1980年 | 8篇 |
1979年 | 10篇 |
1978年 | 6篇 |
1975年 | 3篇 |
1974年 | 3篇 |
1936年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
41.
Sung‐Fu Hsu Tzong‐Ming Wu Chien‐Shiun Liao 《Journal of Polymer Science.Polymer Physics》2006,44(23):3337-3347
Poly(3‐hydroxybutyrate) (PHB)/layered double hydroxides (LDHs) nanocomposites were prepared by mixing PHB and poly(ethylene glycol) phosphonates (PEOPAs)‐modified LDH (PMLDH) in chloroform solution. Both X‐ray diffraction data and TEM micrographs of PHB/PMLDH nanocomposites indicate that the PMLDHs are randomly dispersed and exfoliated into the PHB matrix. In this study, the effect of PMLDH on the isothermal crystallization behavior of PHB was investigated using a differential scanning calorimeter (DSC) and polarized optical microscopy. Isothermal crystallization results of PHB/PMLDH nanocomposites show that the addition of 2 wt % PMLDH into PHB induced more heterogeneous nucleation in the crystallization significantly increasing the crystallization rate and reducing their activation energy. By adding more PMLDH into the PHB probably causes more steric hindrance of the diffusion of PHB, reducing the transportation ability of polymer chains during crystallization, thus increasing the activation energy. The correlation among crystallization kinetics, melting behavior and crystalline structure of PHB/PMLDH nanocomposites can also be discussed. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3337–3347, 2006 相似文献
42.
Yah ZHAO Xiao Qing LIU Hong You ZHU Zi Ming YANG Rong HUANG 《中国化学快报》2006,17(12):1543-1546
Bridged bis(β-cyclodextrin)s (CDs), as a very important family of CD derivatives, have been known that they can significantly alter the molecular binding ability and selectivity toward a variety of guests in comparison with parent cyclodextrin. Their two… 相似文献
43.
Yong LU Hong WANG Ye LIU Ming Yuan HE 《中国化学快报》2006,17(10):1397-1400
Recently, miniature H2 generator to power fuel cells for portable/micro electronic devices and passenger propulsion has been the focus of intense research activities1-3. One of the strategies is to find simple CO-free H2 production with novel microreactor… 相似文献
44.
以己二酸酐和邻羟基苯甲酸为原料,制备了己二酸单(2-羧苯酚)酯,并以它为单体聚合得到了相应的聚酯酸酐.研究了温度、真空度对聚合物分子量的影响,得到了最佳的聚合条件:真空度66.66Pa,聚合温度200℃.在此条件下聚合2.5h,得到的聚己二酸单(2-羧苯酚)酯重均分子量达6498.另外,还对聚合物在不同pH值条件下的体外降解行为进行了研究. 相似文献
45.
Jian Ming ZHAN Bijan DAVVAZ K. P. SHUM 《数学学报(英文版)》2007,23(8):1345-1356
We describe the relationship between the fuzzy sets and the algebraic hyperstructures. In fact, this paper is a continuation of the ideas presented by Davvaz in (Fuzzy Sets Syst., 117: 477- 484, 2001) and Bhakat and Das in (Fuzzy Sets Syst., 80: 359-368, 1996). The concept of the quasicoincidence of a fuzzy interval value with an interval-valued fuzzy set is introduced and this is a natural generalization of the quasi-coincidence of a fuzzy point in fuzzy sets. By using this new idea, the concept of interval-valued (α,β)-fuzzy sub-hypermodules of a hypermodule is defined. This newly defined interval-valued (α,β)-fuzzy sub-hypermodule is a We shall study such fuzzy sub-hypermodules and sub-hypermodules of a hypermodule. generalization of the usual fuzzy sub-hypermodule. consider the implication-based interval-valued fuzzy 相似文献
46.
47.
A new chemiluminescence method for the determination of carbamazepine (CBZ) has been developed. The method is based on the chemiluminescence produced in the reaction of tris(2,2'-bipyridine)ruthenium(III) and CBZ in an acidic medium. The chemiluminescence intensity was enhanced by organic solvents in the reaction system. Under the optimum experimental conditions, the calibration curve was linear over the range 4.0 x 10(-3)-8.6 x 10(-7) mol/L for CBZ. The detection limit (S/N = 3) was 2.5 x 10(-7) mol/L and the relative standard deviation of six replicate measurements was 2.6% for 4.0 x 10(-4) mol/L of CBZ. The possible reaction mechanism were also discussed. The chemiluminescence method was successfully applied to assay the CBZ contents in pharmaceutical tablets. 相似文献
48.
Hai Huyen Dam Hans-Jürgen Zepernick Sven Nordholm Jörgen Nordberg 《Annals of Operations Research》2005,133(1-4):249-264
The performance of a code division multiple access system depends on the correlation properties of the employed spreading
code. Low cross-correlation values between spreading sequences are desired to suppress multiple access interference and to
improve bit error performance. An auto-correlation function with a distinct peak enables proper synchronization and suppresses
intersymbol interference. However, these requirements contradict each other and a trade-off needs to be established. In this
paper, a global two dimensional optimization method is proposed to minimize the out-of-phase average mean-square aperiodic
auto-correlation with average mean-square aperiodic cross-correlation being allowed to lie within a fixed region. This approach
is applied to design sets of complex spreading sequences. A design example is presented to illustrate the relation between
various correlation characteristics. The correlations of the obtained sets are compared with correlations of other known sequences. 相似文献
49.
HaiHuiXIE XiaoYiWEI JiDongWANG MeiFangLIU RenZhouYANG 《中国化学快报》2003,14(6):588-590
A New Annonaceous acetogenin,squamostolide(1),was isolated from the seeds of Annona squamosa.Its structure was elucidated based on spectroscopic methods and comparison with known compounds.It is the first example of Annonaceous acetogenin with each of the two ends of the aliphatic chain bearing a γ-lactone.Thenew compound exhibited cytotoxic activity in vitro against bel-7402 and CNE2 human tumor cell lines. 相似文献
50.