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71.
Two hundred ninety experimental absolute intensities of nu(1) and nu(3) transitions of ozone have been measured, with good accuracy (<2%). They are used to derive the transition-moment parameters for these bands. The agreement between our observed and calculated line intensities is satisfactory. This work shows that the intensities of these two bands are on average 4% smaller than those used in the literature. In addition, 20 intensities of the nu(2) + nu(3) - nu(2) band confirm this value. Also, 42 line intensities of the 2nu(1)-nu(3) band are reported. Copyright 2001 Academic Press. 相似文献
72.
We present a new and complete analysis of the n-bounce resonance and chaotic scattering in solitary-wave collisions. In these phenomena, the speed at which a wave exits a collision depends in a complicated fractal way on its input speed. We present a new asymptotic analysis of collective-coordinate ordinary differential equations (ODEs), reduced models that reproduce the dynamics of these systems. We reduce the ODEs to discrete-time iterated separatrix maps and obtain new quantitative results unraveling the fractal structure of the scattering behavior. These phenomena have been observed repeatedly in many solitary-wave systems over 25 years. 相似文献
73.
One popular approach to cloaking objects from electromagnetic waves at moderately long wavelengths is the scattering cancelation technique. This mechanism is based on the use of a single homogeneous thin layer to cover an object of interest in order to provide scattering suppression in a given frequency band. This approach has also been recently extended to acoustic waves. This paper provides an investigation of the physical nature of scattering cancelation by a uniform thin layer for both electromagnetic and acoustic waves in inviscid fluids. Two distinct scattering cancelation regions are obtained within the available parameter space: a non-resonant plasmonic cloaking region and an anti-resonant cloaking region, which are identified and compared in both the electromagnetic and acoustic domains. Although both types of operations allow for the suppression of the dominant scattering orders, the resulting internal fields and physical functionality of the cloaks present distinct differences between the two domains. We discuss analogies and differences between these functionalities and their implications in electromagnetic and acoustic cloaking problems, with an insight into their practical implementation. 相似文献
74.
Valeria D’Amato Steven Haberman Gabriella Piscopo Maria Russolillo 《Computational Management Science》2014,11(1-2):111-137
Longevity risk threatens the financial stability of private and government sponsored defined benefit pension systems as well as social security schemes, in an environment already characterized by persistent low interest rates and heightened financial uncertainty. The mortality experience of countries in the industrialized world would suggest a substantial age-time interaction, with the two dominant trends affecting different age groups at different times. From a statistical point of view, this indicates a dependence structure. It is observed that mortality improvements are similar for individuals of contiguous ages (Wills and Sherris, Integrating financial and demographic longevity risk models: an Australian model for financial applications, Discussion Paper PI-0817, 2008). Moreover, considering the dataset by single ages, the correlations between the residuals for adjacent age groups tend to be high (as noted in Denton et al., J Population Econ 18:203–227, 2005). This suggests that there is value in exploring the dependence structure, also across time, in other words the inter-period correlation. In this research, we focus on the projections of mortality rates, contravening the most commonly encountered dependence property which is the “lack of dependence” (Denuit et al., Actuarial theory for dependent risks: measures. Orders and models, Wiley, New York, 2005). By taking into account the presence of dependence across age and time which leads to systematic over-estimation or under-estimation of uncertainty in the estimates (Liu and Braun, J Probability Stat, 813583:15, 2010), the paper analyzes a tailor-made bootstrap methodology for capturing the spatial dependence in deriving confidence intervals for mortality projection rates. We propose a method which leads to a prudent measure of longevity risk, avoiding the structural incompleteness of the ordinary simulation bootstrap methodology which involves the assumption of independence. 相似文献
75.
Previous studies have shown that fractal scatterings in weak interactions of solitary waves in the generalized nonlinear Schrödinger (NLS) equations are described by a universal second-order separatrix map. In this paper, this separatrix map is analyzed in detail, and hence a complete characterization of fractal scatterings in these weak interactions is obtained. In particular, scaling laws of these fractals are derived analytically for different initial conditions, and these laws are confirmed by direct numerical simulations. In addition, an analytical criterion for the occurrence of fractal scatterings is given explicitly. 相似文献
76.
S. Sankar MR. Manikandan S.D. Gopal Ram T. Mahalingam G. Ravi 《Journal of Crystal Growth》2010,312(19):2729-2733
The microbial free single crystals of α and γ glycine were grown from gel at room temperature in a new chemical route. These crystals showed a superior quality than the solution grown crystals. The metastable α-form and the stable γ-form of glycine were crystallized in silica gel by solubility reduction method. The form of crystallization is confirmed by single crystal and powder X-ray diffraction analyses. The crystals of α and γ glycine were found to crystallize in monoclinic and hexagonal crystal systems, respectively. For analyzing the functional group and thermal stability of α and γ glycine crystals, spectroscopic and thermal analyses have been carried out. The dielectric studies were performed to find the dielectric constant of the grown crystals and the results are discussed. Second harmonic generation efficiency of the crystal was measured by Kurtz’s powder method using Nd:YAG laser and it was found to be 2.68 times that of potassium dihydrogen phosphate crystals. 相似文献