Excitation functions of the analyzing power in elastic proton-proton scattering from 0.45 to 2.5 GeV

Excitation functions A_N(p_lab,_c.m.) of the analyzing power in elastic proton-proton scattering have been measured in an internal target experiment at the Cooler Synchrotron COSY with an unpolarized proton beam and a polarized atomic hydrogen target. Data were taken continuously during the acceleration and deceleration for proton kinetic energies T_lab (momenta p_lab) between 0.45 and 2.5 GeV (1.0 and 3.3 GeV/c) and scattering angles 30 ^° _c.m. 90^°. The results provide excitation functions and angular distributions of high precision and internal consistency. The data can be used as calibration standard between 0.45 and 2.5 GeV. They have significant impact on phase shift solutions, in particular on the spin triplet phase shifts between 1.0 and 1.8 GeV.     

Anticancer activities of manganese-based photoactivatable CO-releasing complexes (PhotoCORMs) with benzimidazole derivative ligands

Carbon monoxide is an important signaling molecule which is produced by heme oxygenase-1. CO shows antiproliferative activity against cancer cells; hence, activation of HO-1 is a significant inhibition strategy against tumor formation and survival of cancer cells. In this work, manganese-based CO-releasing molecules (CORMs) were designed and synthesized to inhibit breast cancer cell proliferation. Human invasive ductal breast cancer cells (MCF-7) were treated with the synthesized CORMs to investigate the effect of the complexes on breast cancer survival under UV light. In vitro experiments indicated that the complexes inhibited breast cancer cell proliferation, and further, the antiproliferative effects were increased under UV light. Thus, these novel CORMs may provide a drug template for the treatment of invasive ductal breast cancer.     

Urea dimethacrylates functionalized with bisphosphonate/bisphosphonic acid for improved dental materials

Incorporation of bisphosphonate/bisphosphonic acid groups in dental monomer structures should increase interaction of these monomers with dental tissue as these groups have strong affinity for hydroxyapatite. Therefore, new urea dimethacrylates functionalized with bisphosphonate (1a, 1b) and bisphosphonic acid (2a, 2b) groups are synthesized and evaluated for dental applications. Monomers 1a and 1b are synthesized from 2‐isocyanatoethyl methacrylate (IEM) and two bisphosphonated amines (BPA1 and BPA2), prepared as reported elsewhere. Selective dealkylation of the bisphosphonate ester groups of 1a and 1b using trimethylsilyl bromide (TMSBr) gives monomers (2a and 2b) with bisphosphonic acid functionality. X‐ray diffractometer (XRD), Raman spectroscopy, and X‐ray photoelectron spectroscopy (XPS) analyses of monomer‐treated HAP particles show that 2a induces formation of stable monomer‐calcium salts, similar to 10‐methacryloyloxydecyl dihydrogen phosphate (MDP), with higher chemical interaction than 2b. The photopolymerization studies indicate good copolymerizability with commercial dental monomers. In vitro studies on NIH 3T3 mouse embryonic fibroblast cells have clearly shown that the tested monomers (1b and 2b) are not toxic according to the MTT standards. All these properties make these monomers suitable as biocompatible cross‐linkers/adhesives for dental applications. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 3195–3204     

Palladium(II)?NHC complexes containing benzimidazole ligand as a catalyst for C?N bond formation

The reaction of 2‐(2‐bromoethyl)‐1,3‐dioxane with 1‐alkylbenzimidazole derivatives results in the formation of the new benzimidazolium salts (1). The reaction of Pd(OAc)₂ with 1,3‐dialkylbenzimidazolium salts (1a–c) yields palladium N‐heterocyclic carbene (NHC) complexes (2a–c). All synthesized compounds were characterized by ¹H NMR, ¹³ C NMR, IR and elemental analysis techniques which support the proposed structures. As catalysts, these new palladium complexes offer a simple and efficient methodology for the synthesis of triarylamines and secondary amines from anilines and amines and in a single step with potassium tertiary butoxide as a base. Copyright © 2010 John Wiley & Sons, Ltd.     

Asymmetric benzoin reaction catalyzed by benzoylformate decarboxylase

Aromatic aldehydes are converted into benzoins by benzoylformate decarboxylase catalyzed C–C bond formation. The reaction affords (R)-benzoins with high enantiomeric excess and in good chemical yields. A broad range of aromatic aldehydes can be used as substrates in aqueous buffer or buffer/DMSO-solutions.     

Delay equations with fluctuating delay related to the regenerative chatter

The mathematical models representing machine tool chatter dynamics have been cast as differential equations with delay. In this paper, non-linear delay differential equations with periodic delays which model the machine tool chatter with continuously modulated spindle speed are studied. The explicit time-dependent delay terms, due to spindle speed modulation, are replaced by state-dependent delay terms by augmenting the original equations. The augmented system of equations is autonomous and has two pairs of pure imaginary eigenvalues without resonance. The reduced bifurcation equation is obtained by making use of Lyapunov-Schmidt Reduction method. By using the reduced bifurcation equations, the periodic solutions are determined to analyze the tool motion. Analytical results show both modest increase of stability and existence of periodic solutions near the new stability boundary.     

On classification of four-dimensional nilpotent Leibniz algebras

Leibniz algebras are certain generalization of Lie algebras. In this paper, we give the classification of four-dimensional non-Lie nilpotent Leibniz algebras. We use the canonical forms for the congruence classes of matrices of bilinear forms and some other techniques to obtain our result.     

Effects of timber skidding on chemical characteristics of herbaceous cover, forest floor and topsoil on skidroad in an oak (Quercus petrea L.) forest

This paper examines the effects of timber harvesting by skidding on some soil properties (sand, silt, clay, pH, organic carbon, bulk density and compaction), herbaceous cover (unit mass) and forest floor (unit weight) properties. Also N (%), P, K, Na, Ca, Mg, Fe, Zn, Cu and Mn (ppm) were determined in all herbaceous cover, forest floor and two soil depth (0–5 cm and 5–10 cm) on skidroad of an oak (Quercus petrea L.) stand in Istanbul Belgrad Forest – Turkey. In this study, obtained results are; the forest floor and the herbaceous cover amount on the skidroad have been found considerably lower than undisturbed area. There were some crucial changes in the characteristics of the soil which has been investigated down to 10 cm depth. Soil bulk density was found quite high in the samples taken from the skidroad subject to compaction compared to the ones on the undisturbed area. Nevertheless, no important difference had been detected between the skidroad and the undisturbed area at both soil depths in terms of organic carbon contents. Moreover, the soil acidity (pH) values showed noteworthy differences in the analysis of soil samples taken from both soil depths on the skidroad and on the undisturbed area. Fe and Cu contents of herbaceous samples on skidroad were significantly higher than undisturbed area. Forest floor on skidroad had significantly higher K content, and significantly lower Zn, Mn and N content compared to undisturbed area. P, Fe, Zn and Mn contents were found significantly lower in 0–5 cm soil depth on skidroad than undisturbed area. In 5–10 cm soil depth, concentrations of N, P, Fe, Zn and Mn were significantly lower, while Mg and Cu contents were significantly higher than undisturbed area. Results indicate that long-term harvest using skidding techniques on these sites had adversely affected soil cation concentrations, physical soil conditions and mass of herbaceous cover and forest floor.     

Monotonicity of input-output mappings in inverse coefficient and source problems for parabolic equations

This article presents a mathematical analysis of input-output mappings in inverse coefficient and source problems for the linear parabolic equation ut=(kx(x)ux)+F(x,t), (x,t)∈ΩT:=(0,1)×(0,T]. The most experimentally feasible boundary measured data, the Neumann output (flux) data f(t):=−k(0)ux(0,t), is used at the boundary x=0. For each inverse problems structure of the input-output mappings is analyzed based on maximum principle and corresponding adjoint problems. Derived integral identities between the solutions of forward problems and corresponding adjoint problems, permit one to prove the monotonicity and invertibility of the input-output mappings. Some numerical applications are presented.