Synthesis, Crystal Structure and Properties of Complex VO（C12H12N2O2） （C13H10NO2）

IntroductionAsthevanadate dependentenzyme ,ahaloperox idase,andvanadiumnitrogenasehavebeenfoundinsuccession ,somescientistsareinterestedinthecoor dinationchemistryandthebiochemistryofvanadi um[1] .Thereactivecenterofvanadiumbromoperoxi dasecontainstheoxovanadiumVO3+ coordinatedbyoxygenandnitrogenatoms[2 ] .However,thestudiesaboutoxovanadiumVO3+ coordinationcompoundscontainingbioactiveligandsarerarelyfound[3— 8] .Hydroximicacidthatcanbeconsideredtobethederivativeofthecarboxylicacid ,theamide…     

含镧金属富勒烯不同溶剂的高温高压提取

将金属原子或离子置于以Ｃ６０、Ｃ８２为代表的富勒烯笼内形成金属富勒烯包合物是目前富勒烯研究的热点课题［１～３］．合成的金属富勒烯常伴随生成较难分离的空心富勒烯,传统的索氏提取法效率又较低,使得金属富勒烯的深入研究受到限制［１,２］．本文采用改进的高温...     

α-Fe_2O_3气敏纳米粉体的红外光谱

研究了不同粒径的α Ｆｅ２Ｏ３纳米粉体在红外光谱中的Ｆｅ Ｏ特征振动带,结果表明当粒径为５０ｎｍ时出现Ａ２ｕ振动,减少到１０ｎｍ时,Ｅｕ振动带劈裂为双峰。根据在不同温度下烧结的α Ｆｅ２Ｏ３粉体中残存硝酸根的红外光谱峰强度变化,首次发现残存硝酸根对其厚膜型元件的气敏性有增敏作用     

INTERFACE SHAPE AND CONCENTRATION DISTRIBUTION IN CRYSTALLIZATION FROM SOLUTION UNDER MICROGRAVITY

The influence of the gravity and interface kinetics on interface shape and interfacial concentration distribution was numerically investigated by using Galerkin finite element method.A boundary mapping technique was used for dealing with free boundary problem. A two-dimensional steady-state model of TGS crystal growth was developed. The results show that with the increase of the gravity level, the growth rate becomes faster, the growth face becomes more curved and interfacial concentration distribution more non-uniform. The consideration of interface kinetics will cause the decrease of growth rate as compared with the pure transport model. It seems that the interface shape does not change very much within two cases of k=5.7cm⁴/(mol·s) and k=∞, but its position does.     

Study on the Absorption of 10TeV γ-Rays Interacting with Soft Photons in Intergalactic Space

TeV gamma rays will be attenuated or absorbed due to the interaction with soft photons in intergalactic space. The spectra of Mrk421 and Mrk501 during their flaring have been observed by ACTs. Using the data obtained with Tibet Ⅱ/HD AS array from October of 1995 to Augest of 1997,the preliminary results of energy density of intergalactic infrared radiation field are presented in this paper. Analysis shows that no statistically significant absorption evidence of high energy gamma rays is found up to around 30 TeV.     

Angular Momentum and Energy Structure of the Coherent State of a 2D Isotropic Harmonic Oscillator

The angular momentum structure and energy structure of the coherent state of a 20 isotropic harmonic oscillator were investigated. Calculations showed that the average values of angular momentum and energy (except the zero-point energy) of this nonspreading 20 wavepacket are identical to those of the corresponding classical oscillator moving along a circular or an elliptic orbit.     

一种测量脉冲高电压的电容分压器

 研制一种测量脉冲高电压的电容分压器, 该分压器对方波脉冲的响应时间为2.8ns。已用它测量Tesla变压器型强流电子束加速器的主开关导通的脉冲电压和Tesla变压器的谐振特性曲线。     

12C快中子辐射俘获反应中的共振现象

主要研究中子辐射俘获反应中的共振现象,利用DSD模型计算激发能量在5—25MeV能区的¹²C(n,γ0)反应截面与E_n=9MeV时的角分布.所考虑的反应机制包括复合核俘获、直接和半直接俘获、复弹性和非弹性散射道的辐射俘获.计算表明,矮共振的峰值在激发能量为13MeV处;巨共振的峰值位置在激发能量21MeV处.计算结果与实验符合较好.     

微重力下溶液法晶体生长模型中晶体生长界面稳定性的研究

研究在微重力条件下溶液法晶体生长的一个二维数学模型中晶体生长界面的稳定性问题.对晶体生长界面为不同倾斜角度的平面的情况作了数值计算,计算结果表明有可能存在一个稳定的晶体生长界面,它应该是一个在Y=λ这一端向后倾的适当形状的曲面 关键词： 微重力 溶液法晶体生长 二维模型 生长界面的稳定性     

同步辐射Laminar光栅的研制

采用全息离子束刻蚀和反应离子刻蚀相结合的新工艺 ,在熔石英基片上成功地刻蚀出 2 0 0l/mm、线空比 4:6、槽深 70nm、刻划面积 60× 2 0mm2 的浅槽矩形Laminar光栅。对改进光栅线条粗糙度和线空比的方法进行了系统的研究。这一新工艺相对简单 ,降低了对干涉系统光学元件和全息曝光显影的严格要求