描述低周疲劳裂纹扩展速率的循环J积分新参量

探讨了低周疲劳加载条件下的应力增量．应变增量关系，提出了模拟裂纹疲劳扩展的二维模型以建立新的循环．积分参量，详细阐述了该积分参量的定义、主要特点、物理意义以及数值计算方法，并通过紧凑拉伸试样的疲劳试验检验该积分参量的有效性．结果表明：该积分参量能够较好描述恒幅低周疲劳裂纹的扩展速率．此外，基于积分参量体系，从能量的角度解释了疲劳迟滞现象．     

Stability of Rotation Relations of Three Unitaries with the Flip Action in C*-Algebras*

The authors show that if Θ = (θ_jk) is a 3 × 3 totally irrational real skewsymmetric matrix, where θ_jk ∈ [0, 1) for j, k = 1, 2, 3, then for any ε > 0, there exists δ > 0 satisfying the following: For any unital C^*-algebra A with the cancellation property,strict comparison and nonempty tracial state space, any four unitaries u₁, u₂, u₃, w ∈ A such that (1) u_ku_j - e^{2πiθjk ujukk} < δ, wu_jw^-1 = u^-1_j, w² = 1_A for j, k = 1, 2, 3; (2)τ (aw) = 0 and τ ((u_ku_ju_k^*u_j^* )ⁿ ) = e^2πinθjk for all n ∈ N, all a ∈ C^*(u₁, u₂, u₃), j, k = 1, 2, 3 and all tracial states τ on A, where C^*(u₁, u₂, u₃) is the C^*-subalgebra generated by u₁, u₂ and u₃, there exists a 4-tuple of unitaries u₁, u₂, u₃, w in A such that u_ku_j = e^2πinθjk u_ku_j, w u_j w^-1 = u^-1 _j, w² = 1A and k u_j - u_jk < ε, k w - wk < ε for j, k = 1, 2, 3. The above conclusion is also called that the rotation relations of three unitaries with the flip action is stable under the above conditions.     

STUDY ON THE SEQUENCE STRUCTURE OF SBR BY 13C—NMR METHOD Ⅰ. ASSIGNMENT FOR UNSATURAT CARBONS SPECTRA*

The sequence structures of emulsion-processed SBR and solution-processed (by lithium catalyst) SBR were investigated by ~(13)C-NMR spectroscopy. Seventeen peaks within unsaturated carbon region were recorded under the adopted experimental conditions. Assignments for these peaks were made by empirical-parameter-evaluation method.     

金属离子为探针分光光度法测定半胱氨酸

在pH 10.0的氨水-氯化铵缓冲溶液中半胱氨酸与钴(Ⅱ)或镍(Ⅱ)能生成金属络合物,其吸收峰分别位于284,274nm处;当钴(Ⅱ)的浓度为2×10-4 mol·L-1时,与之反应的半胱氨酸浓度在2.5×10-5~2.0×10-4 mol·L-1范围内与相应的吸光度之间呈线性关系,而当加入镍(Ⅱ)的浓度为1×10-4 mol·L-1时,则与之反应的半胱氨酸浓度在1.0×10-5~2.0×10-4 mol·L-1范围内与其吸光度之间呈线性关系。据此,提出可分别用钴(Ⅱ)或镍(Ⅱ)作为探针,以分光光度法测定半胱氨酸的含量。该方法可用于尿液中半胱氨酸的测定,加标回收率在95.7%~101%之间,测定值的相对标准偏差(n=5)在0.9%~3.3%之间。     

阴离子交换色谱-积分脉冲安培检测法分离测定烟草料液中的山梨醇和糖

采用阴离子交换色谱-积分脉冲安培检测法分离测定了烟草料液中山梨醇、葡萄糖、果糖、蔗糖和麦芽糖,研究了山梨醇和糖在阴离子交换色谱中的保留行为。采用优化的水和氢氧化钠二元梯度淋洗条件,CarboPac PA10阴离子交换色谱柱进行分离,积分脉冲安培检测器检测一次进样测定烟草料液样品中的山梨醇、葡萄糖、果糖、蔗糖和麦芽糖。各组分在测试条件下线性关系良好,线性范围为0.005～20 mg/L,检测限为0.2～1.0 μg/L,加标回收率为95.1%~102.4%,相对标准偏差为1.2%～1.9%。     

抗褐飞虱两系杂交稻不育系Bph68S及其组合两优234的选育

利用优良两系不育系广占63-4S为母本人工去雄与具有高抗褐飞虱材料进行杂交,多代回交,结合分子标记辅助选择技术,成功选育出败育彻底、配合力强、并具有褐飞虱抗性的新不育系Bph68S,并利用Bph68S配组选育出抗褐飞虱杂交水稻新组合两优234.两优234生育期短(全生育期在128d左右)、优势强,稻米外观品质好、食味佳,主要理化指标达到国标三级优质稻谷质量标准;在2006年和2007年飞虱大发生年份表现出良好的抗性,田间未发现明显病害.     

尿样及动物组织中甲氧苄氨嘧啶残留量的高效液相色谱-串联质谱测定法

采用微量化样品前处理技术,以固相萃取为净化方法,电喷雾正离子多反应监测方式建立了尿样及动物组织中甲氧苄氨嘧啶残留量的液相色谱-串联质谱联用测定法.检出限为0.1 ng/g,线性范围均大于3个数量级,线性方程的相关系数大于0.999,组织样品和尿样的回收率分别为89%和93%.     

基于自由基配体的Dy(Ⅲ)配合物的设计、合成、结构及磁性

以氮氧自由基为配体,合成了2例未见文献报道的氮氧自由基-稀土配合物[Dy（hfac）₃（NIT-C₃H₅）（H₂O）]与[Dy（hfac）₃（NIT-C₃H₅）]_n（hfac=六氟乙酰丙酮,NIT-C₃H₅=2-环丙烷基-4,4,5,5-四甲基-2-咪唑啉-3-氧化-1-氧基自由基）。单晶结构分析表明配合物1为单核结构,单斜晶系P2₁/c空间群;配合物2为一维结构,单斜晶系P2₁/c空间群。交流磁化率测试结果表明配合物2虚部表现出频率依赖,这表明配合物2是单链磁体。     

Stimulated Emission from a TiO2 Particle-Dispersed Dye Polymer Plane Waveguide

We report the stimulated emission from a dye doped polymer plane waveguide with TiO2 particles. This waveguide consists of a poly （methylmethacrylate） （PMMA） film containing laser dye DCM as a gain medium. The emission spectrum of the film pumped by the Nd：YAG laser is different from the amplified spontaneous emission of the dye-doped film without particles. It is shown that when the excitation intensity reaches the threshold 9.6 μJ, the broad band emission spectrum narrows into multiple separate peaks with central wavelength of 608 nm. The linewidth of the sharp peak is 0.5 nm. According to our analyses, this phenomenon is due to the multiscattering of the disordered TiO2 particles inside the gain polymer film.     

激波管中非平衡可凝结流的流动分析

理论推导激波管中相变加热的临界加热量,得到一个显式计算临界加热量公式.该式可广泛用于湿蒸汽或纯蒸汽相变加热流动计算.结果表明,考虑相变加热的临界加热量要大于外部加热的临界加热量;热壅塞时会产生一道向上游传播的凝结激波,且凝结激波位置在液相质量分率开始增长点之前.采用AUSM格式数值求解激波管中湿空气的凝结流动,理论预测与数值计算吻合良好.