STUDY ON THE DETERMINATION OF TRACE Fe(Ⅲ) BY THIN LAYER RESIN PHASE SPECTROPHOTOMETRY

A method to determine Fe(Ⅲ) by thin layer resin phase spectrophotometry has been developed in this paper. The colored complex formed by Fe(Ⅲ) and 1,2-benzendiol is concentrated on the 717# resin, then Fe(Ⅲ) can be determined directly by making thin layer. The method is sensitive with a apparent molar absorption of 4.8×104L/mol. cm, which is 16 times higher than that of liquid phase spectrophotometry, most coexisting ions do not influence the determination. The detection limit for Fe(Ⅲ) is 1.47μg/L with the precision of 3.3% [n=6, 7μg/50mL Fe(Ⅲ)]. The calibration curve is linear in the range of 0～25μg/50mL. The preposed method was applied to the determination of Fe(Ⅲ) in water sample with satisfactory results.     

100MeV负氢回旋加速器高频冷模腔的理论与实验研究

在回旋加速器中,高频系统为带电粒子加速提供能量,高频谐振腔作为高频系统中的关键部件,它性能的好坏直接决定着粒子是否能够被加速,所以,高频谐振腔的设计非常关键.在100MeV负氢回旋加速器的设计中,在空间限制的同时,要求加速电压从中心区的60kV到出引区的120kV变化,这对谐振腔的设计提出了很高的要求.基于上述条件,本工作利用有限差分法的软件CST MICR0wAVESTUDIO设计的双内杆结构的44MHz高频谐振腔初步设计完成,根据初步设计的结论,加工与实际腔体尺寸1:1模型,模型高频参数测量的结果与CST MICROWAVE STuDIO的计算相吻合,结果是可信的.     

三维Minkowski空间中的一类直线汇

研究了由三维Minkowski空间$E^3_1$中一个类空曲面$S_1$上一个单参数测地曲线族的切线所构成的直线汇$T$,它以$S_1$为一个焦曲面.证明了$T$的两个可展曲面族沿着第二个焦曲面$S_2$的正交曲线网相交的充要条件是$S_1$是可展曲面.对于$T$的两个焦曲面$S_1$和$S_2$之间沿着同一光线的对应,还证明了其保持渐近曲线网的充要条件.最后,研究了$T$的正交曲面$S$,并且证明了如果$S$是$E^3_1$中的一个极大曲面,那么,$T$的焦曲面$S_1$和$S_2$之间沿着同一光线的对     

Crystallization and Preliminary Crystallographic Analysis of β- Trichosanthin, an Isoform of Trichosanthin from the Root Tuber of Trichosanthe kirilowii

β-Trichosanthin,a type 1 ribosome-inactivating protein (RIP) isolated from the root tuber of Trichosanthe kirilowii Maxim,is an isoform of trichosanthin. Here we report its crystal-lization in two crystal forms using the hanging-drop vapor-diffusion method. The form A and form B crystals belong to the orthorhombic space group P212121 and monoclinic space group P21,respectively. X-ray data have been collected to 1.6 and 1.2 resolution for form A and form B crystals,respectively,using a synchrotron source.     

介质对高频电磁波的色散关系

根据经典力学、电磁学知识和经典色散理论导出了介质对高频电磁波的色散规律,由此色散规律可以清楚看出几乎所有介质对于高频电磁波来说都成为透明介质,并以金属铜为例进行了验证.据此人们可以容易地理解高频电磁波的某些应用.     

Isomerization of 4-Amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-one with Base

4-Amino-6-tert-butyl-3-methylthio-1, 2, 4-triazin-5 (4H)-one I, named as Metribuzin1, is an excellent selective herbicide. In the course of studying the reaction of I, we have found an unexpected reaction. We have attempted to prepare 6-tert-butyl- 4-methylamino-3-methylthio-1, 2, 4-triazin-5 (4H)-one II from I with methyl iodide in the presence of sodium hydroxide in aqueous methanol, surprisingly, instead of II the product III 4-amino-6-tert-butyl-3, 4-dihydro-2-methyl-3-thioxo-1, 2, 4-…     

氨基改性复合凝胶的制备及吸附木家具中VOCs性能研究

采用改性共溶胶-凝胶法将壳聚糖与无机相的二氧化硅制备形成氨基改性交联复合凝胶并添加入聚氨酯涂料(PU漆中)和木基材中。结果表明:制得的氨基改性交联复合凝胶孔径大小为12μm^16μm,既保留了凝胶的轻质结构和介孔特性,又含有壳聚糖所具有的活泼有机基团,对PU漆和木基材的VOCs都有一定吸附作用,其中对于杉木中VOCs吸附作用最强,达到了72.86%。说明此方法具有一定的可操作性,为木家具的污染防治增添了一种新的方法,具有规模化的应用前景。     

基于离散极大值法的太赫兹光谱特征吸收峰提取方法

太赫兹波在电磁波谱中介于微波和红外辐射之间，具有指纹特性、安全无损、强穿透性等特点，因此太赫兹光谱技术在药品成分和组成检测领域具有广泛应用价值。针对高纯度物质识别研究中存在部分弱吸收峰不易识别，以及混合物的太赫兹光谱中吸收峰强度降低而导致吸收峰位信息模糊化的问题，提出了一种基于离散极大值法的光谱吸收峰位识别方法，即伴随拐点法。伴随拐点法首先利用目标检测物太赫兹吸收系数谱图的一阶和二阶导数确定吸收峰位的伴随拐点和基线谱，其次将原始吸收光谱与基线谱进行差分运算得到差谱，最后根据离散极大值法确定吸收峰位，从而实现特征吸收峰的识别。为验证伴随拐点法的有效性，采用伴随拐点法对四种硝基呋喃类样品光谱进行吸收峰提取，并将吸收峰位识别结果与仿真结果进行比较。实验结果证明，伴随拐点法能有效识别目标检测物的强吸收峰和弱吸收峰。该方法不仅在含峰目标物的太赫兹特征吸收峰识别问题中具有广泛的应用前景，还适用于其他光谱的谱峰峰位检测。     

新型小分子抗凝血药物的合成、作用机制及构效关系研究进展

以达比加群酯为代表的Ⅱa因子抑制剂和以利伐沙班为代表的Xa因子抑制剂在抗凝血药物中起到了重要作用。本文综述了已上市的新型小分子抗凝血药物的的合成、作用机制及其构效关系,并对其进行了深入分析,同时对此类药物的发展趋势和前景进行了展望。     

Parameter Estimations in BurrⅫ Model Using Masked Data

We consider a series system of two independent and non-identical components which have different BurrⅫ distributed lifetime.The maximum likelihood and Bayes estimators of the parameters of the system＇s components are obtained based on masked system life test data.The conclusion is that the Bayes estimates are better than the maximum likelihood estimates in the sense of having smaller mean squared errors.