全文获取类型
收费全文 | 8372篇 |
免费 | 1878篇 |
国内免费 | 3407篇 |
专业分类
化学 | 6234篇 |
晶体学 | 375篇 |
力学 | 572篇 |
综合类 | 457篇 |
数学 | 1388篇 |
物理学 | 4631篇 |
出版年
2024年 | 14篇 |
2023年 | 76篇 |
2022年 | 303篇 |
2021年 | 304篇 |
2020年 | 255篇 |
2019年 | 273篇 |
2018年 | 288篇 |
2017年 | 437篇 |
2016年 | 286篇 |
2015年 | 454篇 |
2014年 | 516篇 |
2013年 | 687篇 |
2012年 | 664篇 |
2011年 | 701篇 |
2010年 | 755篇 |
2009年 | 762篇 |
2008年 | 902篇 |
2007年 | 827篇 |
2006年 | 816篇 |
2005年 | 599篇 |
2004年 | 514篇 |
2003年 | 414篇 |
2002年 | 406篇 |
2001年 | 440篇 |
2000年 | 478篇 |
1999年 | 268篇 |
1998年 | 139篇 |
1997年 | 110篇 |
1996年 | 103篇 |
1995年 | 67篇 |
1994年 | 93篇 |
1993年 | 111篇 |
1992年 | 87篇 |
1991年 | 62篇 |
1990年 | 66篇 |
1989年 | 57篇 |
1988年 | 45篇 |
1987年 | 58篇 |
1986年 | 39篇 |
1985年 | 31篇 |
1984年 | 23篇 |
1983年 | 24篇 |
1982年 | 19篇 |
1981年 | 15篇 |
1980年 | 15篇 |
1979年 | 21篇 |
1978年 | 6篇 |
1977年 | 7篇 |
1976年 | 4篇 |
1974年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 156 毫秒
951.
Isovaleroyl oxokadsurane, a novel dibenzocyclooctadiene lignan pos-sessing a spirobenzofuranoid skeleton was isolated from the stems of Kadsura coccinea.Its structure and relative configuration were determined by X-ray diffraction analysis. 相似文献
952.
953.
After the separation of the donor, the aeceptor, and the σ-type bridge from the π-σ-π system, the geometries of biphenyl, biphenyl anion radical, naphthalene, and naphthalene anion radical are optimized, and then the reorganization energy for the intermolecular electron transfer (ET) at the levels of HF/4-31G and HF/DZP is calculated. The ET matrix elements of the self-exchange reactions of the π-σ-π systems have been calculated by means of both the direct calculation based on the variational principle, and the transition energy between the molecular orbitals at the linear coordinate R=0.5. For the cross reactions, the ET matrix element and the geometry of the transition state are determined by searching the minimum energy splitting △_(min) along the reaction coordinate. In the evaluation of the solvent reorganization energy of the ET in solution, the Marcus' two-sphere model has been invoked. A few of ET rate constants for the intramolecular ET reactions for the π-σ-π systems, which contain 相似文献
954.
effect、pohrencct.l-methyl-2-formvl-5-Y-substitutedpyrrole(4-nltrophenyl)Ndrazones.Correlationresultsmrthefluorescencespectraldataofsubstitutedstyrenesanda-Onthebasisof*themagnitudesofevaluatedlpm。/p、。”]valuesofEq.l,Inwhichp”a“(orPn。。/an,。)andPa(orP。』/a。。)rePresentthePolarandsPin-delocallzatloneffect,wehaverecentlyproposedthattherearefourcategoriesofpossiblecircumstancesforcorrelationanalysisofradlcalreactlvltlesandspectralpropeTtlesl.IBothpolarandsp… 相似文献
955.
合成了以苯乙烯-二乙烯苯为骨架的若干叔胺型弱碱性树脂,研究了胺化反应条件,胺化试剂及交联度等对叔胺产碱树脂功能单一性的影响,测定了强碱交换量低的叔胺树脂的滴定曲线特征,找到了适合作为热再生树脂弱碱组分的单功能基叔胺树脂的合成条件。 相似文献
957.
XU Mingcheng XU Mancai SHI Zuoqing SHI Rongfu LIU Juxiang HE Binglin 《Chinese Journal of Reactive Polymers》2000,(1)
I INTRODUCTIONGinkgo biloba L. is one of the important economic trees, which is widely distributed inChina. In recent years, medicinal and healthful preparations based on the extractS from ginkgoleaves have been rapidly developed for the treatment of peripheral circulatory and cerebralinsufficiencyl']. Such eXtracts contain flavonol glycosides and terpene lactones as thepharmacologically active compounds. Organic-solvent extraction is one of the earliest methodsto prepare the extracts o… 相似文献
958.
LI HaoJun TANG GuiFeng HE Feng WU Bin HU XiaoGong CHEN YanLing 《中国科学:物理学 力学 天文学(英文版)》2013,(8):1591-1597
A new strategy to realize precise absolute positioning for a single-frequency user is presented. In the presented strategy, the receiver clock and ambiguities are removed using the satelliteand epoch-differenced (SDED) algorithm. As a further development of the SDED algorithm, a regional augmentation network is used to generate the SDED atmospheric delays at the user. The weakened mathematic property due to the epoch-differenced operation is improved by adding the generated atmospheric delays and applying the robust estimation. To test the new approach, the 24-h data at 5 Continuous Operation Reference Station (CORS) stations in Shanghai is processed. The results show a more than 96% success rate, defined as the case where three directions achieve the desired positioning accuracy of 10 cm, when the observation is longer than 20 min. The 20-min static results show that the new method can reach an accuracy of 3.42, 4.76 and 9.26 cm in the North, East and Up directions, respectively. An experiment was carried out to assess the kinematic positioning. The results show that the kinematic positioning accuracy is 4.11, 5.31 and 4.05 cm in the north-south, east-west and height directions,respectively. 相似文献
959.
The additional symmetries of the constrained CKP (cCKP) and BKP (cBKP) hierarchies are given by their actions on the Lax operators, and their actions on the eigenfunction and adjoint eigenfunction {Φ i , Ψ i } are presented explicitly. Furthermore, we show that acting on the space of the wave operator, *k forms new centerless W cC 1+∞ and W cB 1+∞ -subalgebra of centerless W 1+∞ respectively. In order to define above symmetry flows *k of the cCKP and cBKP hierarchies, two vital operators Y k are introduce... 相似文献
960.
建立了同时测定尼卡巴嗪原料药及其制剂中4,4′-二硝基均苯二脲(DNC)和2-羟基-4,6-二甲基嘧啶(HDP)的高效液相色谱法。试样用二甲基亚砜溶解,以Hypersil BDS C18为色谱柱,乙酸/乙酸铵溶液-乙腈(体积比1∶1)为流动相,HDP和DNC的检测波长分别为290、350 nm。DNC和HDP的质量浓度分别在0.354~70.9 mg/L和0.146~29.2 mg/L范围内与色谱峰面积呈良好线性关系,标准曲线方程分别为ρ=7.307×10-5S-0.043 58和ρ=1.648×10-5S-0.084 83,相关系数(r)分别为1.000和0.999 9。用建立的方法测定尼卡巴嗪原料药中的DNC和HDP含量,测定结果与分光光度法无显著差异,DNC和HDP的相对标准偏差均小于0.5%。 相似文献