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991.
992.
Thestudiesofpolymersolutionpropertiesfromdilatetoconcentratedsolutionbyfluorescencetechniquehaveattractedmoreattentionsinrecentdecadesl'2.InordertoinvestigateintrachainandinterchainilltCractionsindilutesolutionregion,pyrenewasusedaslabelsattachedtopolystyrene,whichwasintenselyfluorescentwithalongfluorescentlifetime3.Inthepresentwork,thepolystyreneattachedwithpyrenylgroupshadanunfavourablestrUcturetothenearestneighborexcimerformationwiththepyrenylgroupsseparatedbymorethanthreeatomsalongthechain… 相似文献
993.
YUAN Jing YAN Husheng** CHENG Xiaohui HE Binglin The State Key Laboratory of Functional Polymer Materials for Adsorption Separation Institute of Polymer Chemistry Nankai University Tianjin 《Chinese Journal of Reactive Polymers》2001,(1)
1. INTRODUCTION Biospecific affinity chromatography is a powerful technique for purification of proteins [1]. The biological affinity ligands in common use include enzyme substrates, inhibitors, cofactors, receptors, antibodies, etc. The advantage of these biological ligands is their very high recognition specialty for particular proteins. As a result, proteins can be purified in fewer steps, often to homogeneity, in a laboratory scale. However, scale-up of the analytical and laboratory p… 相似文献
994.
995.
XU Mancai OU Zhize SHI Zuoqing XU Mingcheng LI Haitao YU Shanxin HE Binglin 《Chinese Journal of Reactive Polymers》2000,(1)
1. INTRODUCTIONReduction of organic compounds by NaBH, is often used in organic synthesis. The reactiollis only proceeded in the interface between the organic phase and water phase because of the lowsolubility of NaBH. in organic compounds, and this results in the slow reaction rate and lowyield. In order to increase the reaction rate and yield, NaBH, was converted totetraalkylammonium borohydrides II' 'l, and this made the operating process complex and greatamount of quaternary ammon… 相似文献
996.
The activation of dioxygen and incorporation into hydrocarbons have been achieved under mild conditions by a methane monooxygenase (MMO)-like system using a dinuclear iron complex [Fe_2Dhist(OAc)_2]BPh_4·3H_2O as the model complex, zinc powder as the electron donor, HOAc as the proton source and methylviologen as the electron transfer agent. The results show that styrene is oxygenated predominantly to styrene oxide (1 396 mol/100 mol of the Fe_2 complex), benzaldehyde (16160) and acetophenone (986), and cyclohexane to cyclohexanol (9370) and cyclohexanone (2670). EPR studies indicate that the hypervalent ironoxo spiecs Fe~ⅣFe~Ⅳ(?)O, derived from Fe~ⅢFe~Ⅲ core via reduction, O_2-binding and protonation, is the active intermediate which inserts the activated oxygen atom into C(?)C or C—H bond giving each product. The system closely resembles MMO and its close relative hemerythrin in the aspects of reaction phenomena, EPR characteristics and product distributions. The Mn_2 analog cmplex、Fe-Zn hetero 相似文献
997.
1introductionChitosan,adeacetylatedderivativeofchitin,isnatUralpolysaccharideswithfreeaminogroups.Itcanactasanexcellentadsorbenttoadsorbnotonlyvariousorganiccompoundsincludingpolychlorinatedbiphenyls,proteinsandnucleicacids,butalsometalions[1~sl.ChitosanhasbeenwidelyemployedasaneffectivecoagulatingagentinactivatedsludgeplantSandfoodprocessingfactories,andalsoinpreparation,concentTationandpurificationofmetalionsinhydrometallurgy.Chitosanbehavesasanaturalchelatingpolymer.Chitosanundergoeschela… 相似文献
998.
本文利用光电子能谱(XPS)和质谱(MS)研究了12种有机锡化合物。通过XPS和MS讨论了化合物中取代基对锡内层电子的影响及对SnO键的影响。结果表明XPS和MS对有机锡化合物某些化学键性质的讨论具有互补性。 相似文献
1000.
XU Mancai SHI Zuoqing XIE Xianglin XU Mingcheng ZENG Ying LIANG Liyan HE Binglin 《Chinese Journal of Reactive Polymers》2000,(1)
1. INTRODUCTIONHydrogen bonding is a useful mechanism for adsorptive separation. The low enemy of thisbond ensures reversibility, while the directionality and the short range of this bond conferselectivity. The adsorption of hydrogen donating solutes onto an adsorbent capable of acceptinghydrogenedmberlite XAD-7, an adsorbent consisted of polycarboxylic ester--based onhydrogen bonding has been examined in detail 11-41. However, the adsorption of hydrogenaccepting solutes onto polymeric a… 相似文献