Plasmonic electro-optic modulator design using a resonant metal grating

A plasmonic electro-optic modulator design using an evanescently coupled resonant metal grating is numerically studied in this Letter. Owing to excitation and propagation of long-range surface plasmons between the metal grating nanowires, a deep and narrow reflection dip can be obtained. Improved modulation performance is achieved through decreased damping from large dielectric gaps between the grating nanowires. An optimized electro-optic modulator design with lower insertion loss and low operating voltage is presented.     

多道检测-激光诱导荧光光谱分析装置研究

采用Nd∶YAG激光器为激发光源,与CCD光学多道分析系统联用建立了多 道检测-激光诱导荧光光谱分析装置,并对该装置的设计进行了优化,荧光光谱测量范围35 0～1 000 nm,波长精度0.3 nm,探测器光谱响应灵敏度0.1 LX。采集和检测了若丹明6G乙 醇溶液的高信噪比荧光谱,最低检出限达到10-8 mol/L。线性范围为10-6～10-8 mol/L。将所建立的装置用于若丹明B荧光淬灭法测定水中硒的含量,获得了满意 的结果。方法的线性范围为1～10 μg/L,检出限为0.5 μg/L,加标回收率为81.3%～112.5 %。     

蒎烯衍生的有机硼化合物的合成及在不对称还原中的应用

综述了由蒎烯衍生的六种有机硼还原剂的合成方法,并讨论了这些还原剂对十类不同类型酮的还原反应及其应用。     

铝合金Whipple防护结构高速撞击实验研究

为了掌握航天器防护结构受空间碎片高速撞击的损伤破坏模式及其防护性能,采用二级轻气炮发射球形弹丸,对铝合金Whipple防护结构进行高速撞击实验研究。根据实验结果分析了铝合金Whipple防护结构的防护屏和舱壁在不同速度区间的损伤模式特征,以及薄铝板防护屏高速撞击穿孔和舱壁弹坑分布随弹丸直径、弹丸撞击速度变化的规律。通过固定弹丸直径,改变弹丸撞击速度,寻找临界撞击速度的方法获得了铝合金Whipple防护结构在0.5~5.5 km/s撞击速度区间内的撞击极限曲线,并与由Christiansen撞击极限方程得到的撞击极限曲线进行了比较,结果表明,实验最小临界弹丸直径略大于预测值。     

Synthesis and optical properties of coated nanoparticle composites

The synthesis of coated nanoparticles is a new direction in engineering, specifically in the study of physical properties of materials. We examine semiconductor coated semiconductor particles, CdS/PbS, and metal coated particles, Au₂S/Au, and the theoretical basis for their unique properties. Coated self-assembled nanoparticles are also studied and recent progress is reported.     

在线还原富集火焰原子吸收光谱法测定环境水样中Cr(Ⅲ)和Cr(Ⅵ)的形态

采用单阀双阳离子交换树脂微柱并联，设计了双路采样逆向洗脱在线分离富集系统，该系统与原子吸收测量技术相结合，实现了在线分离富集-火焰原子吸收光谱法同时测定水中Cr(Ⅲ)和Cr(Ⅵ)，富集1min时，分析速度为60样/h，测定Cr(Ⅲ)和Cr(Ⅵ)的特征浓度分别为6．08μg/L和11．58μg/L(相当于1％吸收)，线性范围分别为0～1．0μg/mL和0～2．0μg/mL，对质量浓度为100μg/L的Cr(Ⅲ)和Cr(Ⅵ)测定的相对标准偏差分别为2．9％和3．0％、检出限分别为8．70和10．8μg/L。该法对实际水样加标回收率在94．5％～104．3％之间。     

APPLICATION OF SURFACE GRAFTED POLY N-ISOPROPYL ACRYLAMIDE BY RADIATION TECHNOLOGY FOR PROTEIN SOLUTION CONCENTRATION

Poly N-isopropyl acrylamide (abbreviated as PNIPA) as a kind of thermally sensitive hydrogel is utilized to concentrate Bovin Serum Albumin (BSA) solution. In order to decrease its surface adsorption to BSA in aqueous solution, surface layer grafting of the gels by radiation technology was carried out. The results showed that hydroxyl propyl methacrylate (HPMA) grained gel exhibited a low level of BSA adsorption and still kept the original thermally sensitive properties of PNIPA hydrogels.     

聚丙烯酸酯改性水性聚氨酯的制备

在回顾聚丙烯酸酯改性水性聚氨酯的研究历史基础上，系统地介绍了聚丙烯酸酯改性水性聚氨酯乳液（PUA）的制备方法，其中包括聚氨酯（PU）和聚丙烯酯（PA）的直接掺混法、PU和PA的乳液共聚法，接枝法，互穿网络法，核壳聚合法，对这些方法做了简单的评述，对其应用范围及前景进行了初步探讨。     

STUDIES ON IPE OF POLYACRYLAMIDE INVERSE EMULSION AND MODIFIDE UREA-FORMALDEHYDE RESIN

The selective water plugging agent was prepared by heating the blends of the polyacry-lamide inverse latex, modified urea formaldehyde resin, crosslinking agent and catalysts.The results show that using different types of polymers and additives or changing in theirproportion of the blends, the gelling viscosity, starting point of gelling and other propertiesof the IPN can be controlled.     

建筑用单组分湿固化聚氨酯密封胶的发展概况

综述了国内外建筑用单组分湿气固化聚氨酯密封胶的发展状况,并针对其面临的主要问题指出了今后发展的主要趋势。