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二烯丙基二甲基氯化铵—丙烯酰胺反相乳液聚合的动力学特征研究 总被引:17,自引:1,他引:17
采用油酸失水山梨醇酯(SPAN)-壬基酚聚氧化乙烯醚(OP)复合乳化剂与K2S2O8-Na2SO3氧化还原引发剂,进行二烯丙基二甲基氯化铵-丙烯酰胺反相乳液共聚合,测得单体的竞聚率为γDADMAC=0.14±0.11,γAM=5.05±0.66;在单体浓度为25─45%,引发剂浓度0.06—0.1%,乳化剂浓度为5—9%,聚合温度303K条件下,得到了共聚反应动力学方程:Rp=k[M]0.68[I]1.31[E]0.73,文中对上述结果做了解释. 相似文献
13.
流动注射在线分离富集-火焰原子吸收光谱法测定环境水样中Cr(Ⅲ)和Cr(Ⅵ)的形态 总被引:9,自引:0,他引:9
采用单阀阴离子和阳离子交换树脂微柱并联 ,两柱交替采样逆向洗脱流动注射在线分离富集环境水样中Cr(Ⅲ )和Cr(Ⅵ ) ,分别用 15 %HNO3和 8%NH4 NO3洗脱 ,火焰原子吸收光谱法直接检测。富集 1min时Cr(Ⅲ )和Cr(Ⅵ )的特征浓度分别为 :1 5 0 μg·L- 1 和 1 39μg·L- 1 ,Cr(Ⅲ )和Cr(Ⅵ )检出限 (3σ)分别为 1 0 3μg·L- 1 和 0 5 4 μg·L- 1 ;相对标准偏差 (10 μg·L- 1 )分别为 :3 4 1%和 1 80 % ,分析样品加标回收率在 93 5 %~ 10 7 5 %之间。 相似文献
14.
Self-stabilized passive, harmonically mode-locked stretched-pulse erbium fiber ring laser 总被引:7,自引:0,他引:7
We have studied a passive, harmonically mode-locked stretched-pulse erbium fiber ring laser with net positive dispersion that is self-stabilized by gain depletion and electrostriction. Periodic pulses with supermode suppression of >75 dB and picosecond jitter are achieved. The pulses are compressible to 125 fs by external chirp compensation. The repetition rate is 220 MHz, and the average power is as high as 80 mW. 相似文献
15.
B. Ibarra-Escamilla O. Pottiez R. Zhou Q. Zhan P. E. Powers E. A. Kuzin J. W. Haus 《Laser Physics》2011,21(11):1936-1940
We experimentally demonstrated a stable, wavelength-tunable fiber laser using a polarization-maintaining, double-clad Er:Yb
doped fiber amplifier in the cavity. The output wavelength is tunable over the range from 1535 to 1567 nm using a fixed grating
and the dichroic mirror placed on a rotational mount; under rotation of the dichroic mirror the tuning ratio of 50 nm/deg
was found. We studied the wavelength tuning range dependence on the amplifier fiber length and achieved a maximal output power
of 850 mW. This configuration can be Q-switched for high peak power and its narrow bandwidth is suitable for nonlinear optics
applications, such as parametric teraherthz generator. 相似文献
16.
JEONG-HAN KANG SEUNG-YEAL HA KYUNGKEUN KANG EUNHEE JEONG 《The Journal of mathematical sociology》2014,38(1):47-71
When cultural tastes are not neutral but hierarchically matched to social status, people assimilate themselves to higher status by consuming cultural goods while distinguishing themselves from lower status by developing new tastes. Extending the Cucker-Smale model for mutual influence among agents, we examine when and how many cultural classes emerge from continuous distributions of tastes and what conditions those classes satisfy, through the assimilation-distinction mechanism. We simulate the models with different initial distributions of tastes (uniform, normal, and chi-square), given various ranges of 2 parameters: (a) the strength and (b) the range of distinction relative to assimilation. Tastes are flocking and cultural classes emerge when the range of assimilation is much larger than that of distinction. The number of classes increases with the strength of distinction, whereas the distance between classes equals the range of distinction. Some properties of emergent classes are mathematically proved. First, in a two-class system, the stronger distinction, the larger the upper class. Second, in a three-class system, the middle class is necessarily larger than the lower class and likely larger than the upper class. Third, a 3-class system cannot emerge if distinction is weaker than assimilation. These properties are universal and do not depend on the initial distribution of cultural tastes. This independence predicts homogeneous cultural classes emerging across different social conditions. Also, the cultural middle class as the largest group may explain why subjective class consciousness is often higher than objective position. Unless assimilating efforts can reach an infinite range, there emerges a cultural outcast at the lowest end of the cultural hierarchy. 相似文献
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Fritz Haake Joseph W. Haus Kazmierz Rzążewski 《Zeitschrift für Physik B Condensed Matter》1982,48(2):175-182
We study resonance fluorescence from a two-level atom illuminated by coherent and incoherent light. Especially, we treat the case of an intense incoherent component which is broad band and chaotic in character.New insights into the phenomenon of resonance fluorescence are obtained by constructing certain analogies with the precession of a classical (Bloch) vector around a classical stochastic field. The analogies are based on a representation of the density operator of the two-level atoms as a diagonal mixture of directed angular momentum states.As long as the whole light field is an imposed one the weight function of the mixture mentioned above describes a random sequence of rotations of the Bloch vector and obeys a simple Fokker Planck equation. If, however, the incoherent component of the light field acts as a zero- or finite temperature heat bath, the equation of motion for the weight function is no longer a Fokker Planck equation. Nontheless, we find the exact solution and calculate the correlation functions relevant to a discussion of the spectrum and of antibunching effects. 相似文献
19.
Collisions in dispersion-managed soliton propagation 总被引:1,自引:0,他引:1
We study collisions in dispersion-managed soliton propagation for wavelength-division multiplexing application at zero net dispersion when the Gordon-Haus timing jitter is removed. We show that the collisions can lead to group-velocity changes and spectral collapse. Large channel separation ameliorates the effects. Filters prevent spectral collapse but do not affect the velocity changes. 相似文献
20.