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901.
Williams S  Pardue HL  Uhegbu CE  Smith AM  Studley J 《Talanta》1996,43(8):1379-1385
This paper describes alternative measurement and data-processing approaches that can reduce effects of experimental variables on results obtained with a membrane-based sensor for oxygen. In the new approaches, the membrane-based sensor is first equilibrated with the sample solution, after which a polarizing voltage is applied and current vs. time data are recorded as the response decays toward a steady-state condition. Current vs. time data are then processed by a fixed-time option and an integration option designed to determine the charge corresponding to the total amount of oxygen inside the membrane when a polarizing voltage is applied. The current measured at a fixed time and the total charge varied linearly with oxygen concentration between 0.05 and 0.26 mmol l(-1). Pooled relative standard deviations (N = 35) for the measurement/data-processing step were near 0.4% for the new pre-equilibrium options compared to a value of 0.3% for the steady-state option. Dependencies of the pre-equilibrium options on membrane thickness and stirring rate in the most sensitive regions were at least two orders of magnitude smaller than for the steady-state option.  相似文献   
902.
The spectrum of inhomogeneous turbulence is modeled by an approach that is not limited to regimes of large Reynolds numbers or small mean-flow strain rates. In its simplest form and applied to incompressible flow, the model depends on five phenomenological constants defining the strength of turbulence coupling to mean flow, turbulence transport in physical and wave-number space, and mixing of stress-tensor components. The implications for homogeneous isotropic turbulence are investigated in detail and found to correspond well to the conclusions from more fundamental theories. Under appropriate limiting conditions, a turbulent system described by the model will relax over time into a state of approximate spectral equilibrium permitting a reduction to a one-point model for the system that is substantially like the familiar K- model. This yields preliminary estimates of the present model's parameters and points to the way to improved modeling of flows beyond the applicability of the K- method.  相似文献   
903.
A closed subsetM of a Hausdorff locally convex space is called d.c. representable if there are an extended-real valued lsc convex functionf and a continuous convex functionh such that $$M = \{ x \in X:f(x) - h(x) \leqslant 0\} .$$ Using the existence of a locally uniformly convex norm, we prove that any closed subset in a reflexive Banach space is d.c. representable. For d.c. representable subsets, we define an index of nonconvexity, which can be regarded as an indicator for the degree of nonconvexity. In fact, we show that a convex closed subset is weakly closed when it has a finite index of nonconvexity, and optimization problems on closed subsets with a low index of nonconvexity are less difficult from the viewpoint of computation.  相似文献   
904.
905.
906.
907.
Results for an inhomogeneously broadened60CoFe NMRON sample have been obtained for gamma detected single pulse (nutation) and two pulse (free induction decay) experiments in the region of intermediate-to-lowR(=1/). Here 1 is the angular frequency measure of the strength of the ferromagnetically enhanced RF field at the nucleus and is the HWHM of the inhomogeneously broadened line. Comparisons of the oscillatory FID signals obtained are made with the theoretical predictions of the following paper [6].  相似文献   
908.
    
Three hail-formation phases in a cloud may be detected, by means of MM and SubMM wave propagation analysis in Convective clouds. These phases are size increase of super-large(85 to 1500m in radius, and larger) droplets, their transition into supercooled state, and immediate droplets transition into ice or small hail, or their coating by ice Crust. Ice transparency window in absorption index, existing in SubMM wave band, is shown to serve as indicator of ice creation in a cloud. Radar reflection coefficient is shown to be increased by two orders of magnitude in the ice transparency window under super-large droplets transition into ice.  相似文献   
909.
Two detection methods of hail embryons in a cloud are discussed in the paper: combined passive/active and purely active sensing of a convective cloud from board of air or space carrier. The first method makes it possible to determine the spectral dependence of absorption coefficient by oversized drops in convective cloud in the millimeter (MM) and submillimeter (SbMM) wavebands. With this purpose a highly sensitive 16-channel Dicke radiometer is used. In the second method a multiwave (12 wavelength) active radar is used to determine the spectral dependence of backscatter coefficient in the same wavebands. Variation of these spectral characteristics in time makes possible the detection of physical processes taking place in a cloud, such as drops drowth and evaporation, as well as transition of oversized drops into the overcooled state. The instant of water/ice phase transition in oversized drops is determined in both methods by means of active radar in SbMM waveband (in the transparency window of ice and atmosphere, 0.64 mm). Corresponding hardware, antennas, and wavelengths are considered for active/passive and purely active sensind of clouds. The effect of antenna beamwidth in SbMM on anomalous backscatter is discussed.Finally the authors would like to acknowledge the helpful discussions and assistance of Dr. K.E.Karapetyan in calculation of the antenna E characteristics.  相似文献   
910.
We consider a class of vertex models describing directed lines on a lattice in arbitraryd dimensions, and solve the model exactly for the Cartesian lattice and in the case that each loop of lines carries a fugacity - 1. Our analysis, which can be carried out for arbitrary lattices, is based on an equivalence of the vertex model with a dimer problem. The dimer problem is, in turn, solved using the method of Pfaffians. It is found that the system is frozen below a critical temperatureT cwith the critical exponent = (3 –d)/2.  相似文献   
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