首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   78347篇
  免费   325篇
  国内免费   379篇
化学   24408篇
晶体学   789篇
力学   6721篇
数学   32038篇
物理学   15095篇
  2018年   10439篇
  2017年   10261篇
  2016年   6071篇
  2015年   848篇
  2014年   294篇
  2013年   337篇
  2012年   3778篇
  2011年   10509篇
  2010年   5633篇
  2009年   6052篇
  2008年   6591篇
  2007年   8769篇
  2006年   240篇
  2005年   1319篇
  2004年   1553篇
  2003年   1978篇
  2002年   1030篇
  2001年   253篇
  2000年   303篇
  1999年   156篇
  1998年   200篇
  1997年   148篇
  1996年   202篇
  1995年   117篇
  1994年   83篇
  1993年   99篇
  1992年   61篇
  1991年   70篇
  1990年   57篇
  1989年   67篇
  1988年   61篇
  1987年   58篇
  1986年   66篇
  1985年   59篇
  1984年   55篇
  1983年   42篇
  1982年   48篇
  1981年   50篇
  1980年   51篇
  1979年   52篇
  1978年   36篇
  1973年   27篇
  1919年   24篇
  1914年   45篇
  1913年   40篇
  1912年   40篇
  1909年   41篇
  1908年   40篇
  1907年   32篇
  1904年   28篇
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
61.
In this work, thermoanalytical, diffractometry, and microscopy measurements have been performed in order to characterize the effect of high energy milling on a drug active in the migraine prophylaxis and smoke cessation. We can assert that the mechanical treatment induces only a partial amorphisation of the solid phase, in particular it reduces the crystal order by producing lattice defects which propagate from the surface to the bulk crystal. For this reason, the DSC is able to detect the presence of ordered solid, while the powder X-ray diffractometry, because of its low penetration depth, does not reach the crystalline core of the particles.  相似文献   
62.
63.
This study presents a new formula for the surface tension prediction of alkenes. As a first step, an analysis of the available data of the experimental surface tension data for alkenes was performed. The experimental data were collected, after a careful literature survey, for the following pure fluids: propene, 1-hexene, 1-heptene, 1-octene, 1-decene, 1-tetradecene, and 1-pentadecene. Then, the experimental data were regressed with the most reliable semi-empirical correlating methods based on the corresponding state theory existing in the literature. As a final step, an analysis of the available data of the experimental surface tension data for alkenes was performed starting from the two recently proposed equations for the prediction of the surface tension of refrigerants based on the corresponding states principle. To minimize the deviation between the predicted data and the experimental data and to find the optimal equation coefficients for experimental data regression, a (μ + λ)-evolution strategy was adopted. The analysis showed that the equation that gave the best results for the prediction of the surface tension of alkenes was the one with a very limited number of parameters. The finally proposed equation is very simple and gives a noticeable improvement with respect to the existing equations. It is based on the corresponding state principle, containing the acentric factor, the critical temperature, and pressure.  相似文献   
64.
For dehydration of CaC2O4·H2O and thermal dissociation of CaCO3 carried out in Mettler Toledo TGA/SDTA-851e/STARe thermobalance similar experimental conditions was applied: 9–10 heating rates, q = 0.2, 0.5, 1, 2, 3, 6, 12, 24, 30, and 36 K min−1, for sample mass 10 mg, in nitrogen atmosphere (100 ml min−1) and in Al2O3 crucibles (70 μl). There were analyzed changes of typical TGA quantities, i.e., T, TG and DTG in the form of the relative rate of reaction/process intended to be analyzed on-line by formula (10). For comparative purposes, the relationship between experimental and equilibrium conversion degrees was used (for P = Pominus P = P^{{ominus}} ). It was found that the solid phase decomposition proceeds in quasi-equilibrium state and enthalpy of reaction is easily “obscured” by activation energy. For small stoichiometric coefficients on gas phase side (here: ν = 1) discussed decomposition processes have typical features of phenomena analyzable by known thermokinetic methods.  相似文献   
65.
Six lanthanide compounds [Ln(H2O)9](m-BDTH)3·9(H2O) where Ln = La (1), and [Ln(H2O)8](m-BDTH)3·9(H2O) (m-BDTH2 = 1,3-benzeneditetrazol-5-yl) where Ln = Lu (2), Yb (3), Er (4), Ho (5) and Y (6) were hydrothermally synthesized and characterized by elemental analyses, infrared spectra, powder X-ray diffraction (PXRD) and X-ray single crystal diffraction. PXRD indicates that 26 are isomorphous. Structural analyses reveal that 1 is coordinated by nine water molecules forming a capped-square antiprism, while 26 are coordinated by eight water molecules forming a simple square antiprismatic geometry. Effects of water molecules on thermal stability were also discussed by thermogravimetric (TG), DSC, and PXRD under different temperatures. TG analyses suggest that 1 loses lattice and coordinated water molecules with no diacritical boundary, and 6 removes lattice water molecules first and then coordinated water molecules. DSC and PXRD further confirm the consequence.  相似文献   
66.
67.
68.
69.
70.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号