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991.
Van T. Tran Zi‐Qi Li Omar Apolinar Joseph Derosa Matthew V. Joannou Steven R. Wisniewski Martin D. Eastgate Keary M. Engle 《Angewandte Chemie (International ed. in English)》2020,59(19):7409-7413
We report that Ni(COD)(DQ) (COD=1,5‐cyclooctadiene, DQ=duroquinone), an air‐stable 18‐electron complex originally described by Schrauzer in 1962, is a competent precatalyst for a variety of nickel‐catalyzed synthetic methods from the literature. Due to its apparent stability, use of Ni(COD)(DQ) as a precatalyst allows reactions to be conveniently performed without use of an inert‐atmosphere glovebox, as demonstrated across several case studies. 相似文献
992.
Karen J. Ardila‐Fierro Stipe Lukin Martin Etter Krunoslav Uarevi Ivan Halasz Carsten Bolm Jos G. Hernndez 《Angewandte Chemie (International ed. in English)》2020,59(32):13458-13462
Recent progress in the field of mechanochemistry has expanded the discovery of mechanically induced chemical transformations to several areas of science. However, a general fundamental understanding of how mechanochemical reactions by ball milling occur has remained unreached. For this, we have now implemented in situ monitoring of a mechanochemically induced molecular rearrangement by synchrotron X‐ray powder diffraction, Raman spectroscopy, and real‐time temperature sensing. The results of this study demonstrate that molecular rearrangements can be accomplished in the solid state by ball milling and how in situ monitoring techniques enable the visualization of changes occurring at the exact instant of a molecular migration. The mechanochemical benzil–benzilic acid rearrangement is the focal point of the study. 相似文献
993.
Eder Toms‐Mendivil Marc Devillard Vianney Regnier Jacques Pecaut David Martin 《Angewandte Chemie (International ed. in English)》2020,59(28):11516-11520
Oxyallyl derivatives are typically elusive compounds. Even recently reported “stabilized” 1,3‐diaminooxyallyl species are still highly reactive and have short lifetimes at room temperature. Herein, we report the synthesis and preliminary study of mesoionic pyrimidine derivatives that feature 1,3‐bis(dimethylamino)oxyallyl patterns with an unprecedented level of stabilization. The latter are not only insensitive towards air and moisture, but they are also compatible with the formation of an ancillary stable N‐heterocyclic carbene moiety. As the oxyallyl pattern is proton‐responsive, it allows the reversible switching of the electronic properties of the carbene, as a ligand. 相似文献
994.
Alshymaa Abdel-Rahman Gomaa Usama Ramadan Abdelmohsen Markus Krischke Martin J. Mueller Amira Samir Wanas 《Natural product research》2020,34(18):2612-2615
AbstractThe present study evaluates the chemical composition of Zinnia elegans and Gazania rigens based on their metabolomic profiles using liquid chromatography coupled with high-resolution mass spectrometry (LC‐HR-MS), alongside with the anti-infective activities of their ethanol extracts, as well as, different fractions. A significant difference was observed between the LC-MS profiles of the two plants such as, coumarins, sesquiterpene lactones and phenylethanoids which were characteristic for Z. elegans, while amides and phenolic acid derivatives were characteristic for G. rigens. These results highlight the chemical potential of Z. elegans and G. rigens. Furthermore, the ethyl acetate fraction of Z. elegans showed a significant antimalarial activity with IC50 values of 21.03 and 13.72?µg/mL against Plasmodium falciparum D6 and P. falciparum W2, respectively. 相似文献
995.
BoRa Lee Anthony C. Willis Jas S. Ward Warren T. Smith Ping Lan Martin G. Banwell 《化学:亚洲杂志》2020,15(19):3059-3081
Syntheses of a range of chemically well‐defined oligopyrrole/benzenoid hybrids are described using tandem Suzuki‐Miyaura cross‐coupling/bromo‐desilyation reaction sequences for linking borylated pyrroles, halogenated pyrroles and/or dibromobenzenes to one another. By such means, including iterative variants, a range of all α‐linked, all β‐linked oligopyrroles as well as certain combinations thereof have been assembled, some of them for the first time. The conductivities of iodine‐treated thin films formed from certain such systems have been determined. 相似文献
996.
Wolfgang Lutz Helga Fichtner-Schmittler Jürgen Richter-Mendau Gudrun Becker Martin Bülow 《Crystal Research and Technology》1986,21(10):1339-1344
In the process of phase transformation of zeolite NaA to nepheline under hydrothermal conditions a special intermediate occurs. This is due to the high reaction rate of nepheline formation in the presence of water molecules. Consequently, the usually observed amorphous material with high condensed silica does not occur as separate phase. – The intermediate which is formed due to the destruction of the long-range order of zeolite is significantly short-range ordered. The phase transformation process starts at the outer surface of zeolite crystals, thus generating a diffusion barrier for sorption uptake processes. 相似文献
997.
Mei Wang Chantal Septier Hlne Brignot Christophe Martin Francis Canon Gilles Feron 《Molecules (Basel, Switzerland)》2022,27(5)
Astringency is an important sensory characteristic of food and beverages containing polyphenols. However, astringency perception in elderly people has not been previously documented. The aim of the present work was to evaluate sensitivity to astringency as a function of age, salivary flow and protein amount. Fifty-four panellists, including 30 elderly people (age = 75 ± 4.2 years) and 24 young people (age = 29.4 ± 3.8 years), participated in this study. Astringency sensitivity was evaluated by the 2-alternative forced choice (2-AFC) procedure using tannic acid solutions. Whole saliva was collected for 5 min before and after the sensory tests. The results showed that the astringency threshold was significantly higher in the elderly group than the young group. No correlation was observed between the salivary protein amount and threshold value. However, a negative correlation between salivary flow and threshold was observed in the young group only. These results showed a difference in oral astringency perception as a function of age. This difference can be linked to salivary properties that differ as a function of age. 相似文献
998.
999.
1000.
We present a new device for the measurement of the metastable zone width and related parameters. The salting-out is detected by using simultaneously seven different methods: a) visual detection, b) intensity of the transmitted laser beam, c) noise associated to (b), d) intensity of the reflected laser beam, e) noise associated to (d), f) conductivity, and g) pH. Full computerization permits an easy and quick take of data on the evolution of the nucleation and crystal growth processes. The use of this apparatus shows that the waiting time for the growth component of the induction time is minimized for the method using the noise associated to the reflected light as the recorded parameter. This comparative study shows that the maximum undercooling and maximum allowable supersaturation values obtained by the different tested methods present significant differences between each other. Meanwhile, we propose that the tabulated values of such parameters should specify the experimental way followed for the obtainment of reliable data. 相似文献