Synthesis of adamantane monomers and their properties

Conclusion Syntheses were reported for new adamantane monomers, namely the allyl and propargyl esters of 1-adamantanecarboxylic acid, the diallyl and dipropargyl esters of 1,3-adamantanedicarboxylic acid and di-1-adamantyl maleate. These esters are capable of undergoing thermal copolymerization with -cyanoacrylate esters.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2808–2809, December, 1986.     

Thermal isomerization of some 2-(3-chloroalkoxy)-1,3,2-azaoxaphospholanes

Conclusions The direction of the thermal isomerization of some 1-alkyl-2-(3-chloroalkoxy)-1,3,2-azaoxaphospholanes depends on the structure of the starting azaoxaphospholane and the reaction temperature.The³¹P NMR spectra were taken by É. I. Gol'dfarb, to whom the authors express their gratitude.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 869–873, April, 1974.