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101.
102.
R. Singh R. M. Misra D. C. Gupta D. D. Shukla M. N. Sharma M. P. Madan 《Zeitschrift für Physik B Condensed Matter》1985,58(2):83-89
The parameterC
1=[(1/K
T
)/P]
T
, which describes the pressure variation of the compressibility, has been examined correlating the thermodynamical and interatomic potential approaches employing fewer approximations than has been usual heretofore. General expressions have been derived forC
1 by including the thermal correction terms, which have generally been ignored in previous studies concerning thermal properties of ionic crystals. The parameterC
1 has also been related to the Grüneisen parameter, , using a relation given earlier. The applicability of the derived equations is investigated and discussed for alkali halides employing few realistic potential forms. A good general accord is found with the available experimental data, which exhibits an essential improvement over other theoretical determinations. 相似文献
103.
The technique of three-phase partitioning (TPP) was used to purify the green fluorescent protein (GFP) in a single step. TPP uses a combination of ammonium sulphate and tert-butanol to precipitate proteins from their crude extracts. In the first round of TPP with 20% ammonium sulphate saturation at the ratio of crude to tert-butanol 1:1 (v/v), most of the GFP remains in the lower aqueous phase. When subjected to a second round of TPP with 60% ammonium sulphate saturation at the ratio of crude to tert-butanol 1:2 (v/v) gives 78% recovery of GFP with a 20-fold purification. The sodium dodecyl sulphate-polyacrylamide gel electrophoretic (SDS-PAGE) analysis of purified preparation shows single band. The fluorescence excitation and emission spectra agreed with values reported in literature. 相似文献
104.
Zusammenfassung Die Nickel- und Zinkkomplexe der Adipinsäure werden polarographisch untersucht. Es zeigt sich, daß Zink reversibel reduziert wird, wogegen Nickel eine irreversible Stufe ergibt. Die Stabilitätskonstanten des Zink—Adipinsäurekomplexes werden nachDeFord undHume berechnet. Der Einfluß des pH-Wertes auf die Zink- und die Nickelstufe wird untersucht. Zink und Nickel werden in Gegenwart vieler störender Kationen halbquantitativ bestimmt.
Mit 7 Abbildungen 相似文献
The said complexes have been studied by polarography. Zn is found to be reversibly reduced while Ni gives an irreversible wave. Stability constants of the Zn complex are calculated byDeFord andHume method. Effect of pH on Zn and Ni wave are reported. Estimations of Zn or Ni are carried out separately or in presence of interfering cations.
Mit 7 Abbildungen 相似文献
105.
Ashok K. Singh Amar Singh Ranjana Gupta Madhu Saxena Bharat Singh 《Transition Metal Chemistry》1992,17(5):413-416
The kinetics of oxidation of three aldoses (glucose, mannose and galactose) byN-bromoacetamide (NBA) in the presence of an alkaline solution of RuO4 as catalyst and Hg(OAc)2 as co-catalyst and as a scavenger for bromide have been investigated. The main products of the oxidation are the corresponding
aldonic acids. The reaction is zero order with respect to aldose and OH−. First order dependence of the reaction on both NBA and RuO4 at low concentrations shifts to zero order at higher concentrations. Addition of acetamide decreases the reaction rate, while
addition of Hg(OAc)2 has the opposite effect. No significant effect of ionic strength was observed. OBr− is postulated as the reactive oxidising species and a mechanism involving co-catalysis by RuO4 and HgII is proposed.
TMC 2588 相似文献
106.
White biotechnology is a fast emerging area that concerns itself with the use of biotechnological approaches in the production
of bulk and fine chemicals, biofuels, and agricultural products. It is a truly multidisciplinary area and further progress
depends critically on the role of chemists. This article outlines the emerging contours of white biotechnology and encourages
chemists to take up some of the challenges that this area has thrown up. 相似文献
107.
108.
R. K. Kuchhal P. V. Dogra K. G. Sharma K. S. Jauhri P. L. Gupta 《Fresenius' Journal of Analytical Chemistry》1977,286(3-4):219-221
Summary A simple gas-liquid chromatographic method has been developed for determining 3-sulfolene in sulfolane. The method involves thermal decomposition of sulfolene and determination of the 1.3-butadiene evolved, by GLC. Influence of the operating parameters on quantitative decomposition of sulfolene has been studied. The accuracy of the method as studied in the concentration range from 0.05 to 4.0 % (w/v) of 3-sulfolene in sulfolane is found to be within ±3.0%. It is rapid and sensitive down to 10 ppm and has potentialities for on-line applications also.
Bestimmung von 3-Sulfolen in Sulfolan durch Reaktions-Gas-Chromatographie
Zusammenfassung Eine einfache gas-chromatographische Methode wurde entwickelt, die auf der thermischen Zersetzung der Probe und der Bestimmung des dabei aus 3-Sulfolen gebildeten 1,3-Butadiens beruht. Der Einfluß der einzelnen Parameter wurde untersucht. Innerhalb eines Konzentrationsbereichs von 0,05–4,0% 3-Sulfolen ergaben sich Fehler von ±3%. Das Verfahren ermöglicht bis herab zu 10 ppm eine schnelle und empfindliche Bestimmung und eignet sich auch zum on-line Betrieb.相似文献
109.
Gupta HK Stradiotto M Hughes DW McGlinchey MJ 《The Journal of organic chemistry》2000,65(12):3652-3658
Tetracyclone, 2a, reacts with C(6)F(5)Li to yield 2-pentafluorophenyl-2,3,4,5-tetraphenylcyclopent-3-en-1-one, 7, and 5-hydroxy-5-pentafluorophenyl-1,2,3,4-tetraphenylcyclopentadiene, 8, as the result of 1,6 and 1,2 additions, respectively. In contrast, treatment of 3-ferrocenyl-2,4,5-triphenylcyclopentadienone, 2b, with lithiopentafluorobenzene leads to 4-ferrocenyl-4-pentafluorophenyl-2, 3,5-triphenylcyclopent-2-en-1-one, 9, and 5-hydroxy-5-pentafluorophenyl-2-ferrocenyl-1,3, 4-triphenylcyclopentadiene, 10, the products of 1,4 and 1,2 addition, respectively. The structures of 7-9 have been established by X-ray crystallography, and the barriers to rotation (19-21 kcal mol(-)(1)) of the pentafluorophenyl groups in 8-10 have been studied by variable-temperature (19)F NMR. Nucleophilic attack at the ferrocenyl-bearing carbon in 2b is rationalized in terms of a zwitterionic structure in which the positive charge of the "cyclopentadienyl cation" is delocalized onto the iron atom in the organometallic substituent. 相似文献
110.
Summary Thorium and zirconium can be quantitatively precipitated by quinaldinic acid atph 2.7 and 3, respectively. As the precipitates are of nonstoichiometric composition they are to be ignited to oxides. By this reagent thorium can be quantitatively separated from arsenic (As3+), mercury (Hg2+), rare earths, manganese, magnesium and alkaline earths and zirconium from all the aforesaid ions excepting rare earths which contaminate to a slight extent. 相似文献