Investigation on FR(LT)–FR(HT) phase transition and pyroelectric properties of pulsed laser deposited Pb(Zr0.93Ti0.07)O3 thin films

The preparation process, crystallinity and electrical properties of pulse laser deposited Pb(Zr_xTi_1−x)O₃ (PZT) thin films were investigated in this paper. PZT (x = 0.93) thin film samples deposited at different substrate temperatures were prepared. Si (1 1 0) was the substrate; Ag and YBCO were the top electrode and the bottom electrode respectively. The bottom electrode YBCO was deposited on the Si substrate by pulsed laser deposition (PLD), and then PZT was epitaxially deposited on YBCO also by PLD. After annealing, the top electrode Ag was prepared on PZT by thermal evaporation, and then the Ag/PZT/YBCO/Si structured thin films were obtained. The XRD and the analysis of their electrical characters showed that, when the substrate temperature was elevated from 600 °C to 800 °C, the crystallinity and electrical properties of PZT thin films became better and better, and the F_R(LT)–F_R(HT) phase transition of PZT (x = 0.93) thin films occurred at 62 °C. The PZT film deposited at 800 °C had the best pyroelectric properties, and when the F_R(LT)–F_R(HT) phase transition of this film occurred, the peak value of pyroelectric coefficient (p) was obtained, with a value of 1.96 × 10⁻⁶ C/(cm² K). The PZT film deposited at 800 °C had the highest remnant polarization (P_r) and the lowest coercive field (E_c), with the values of 34.3 μC/cm² and 41.7 kV/cm respectively.     

HNO分子基态的结构与解析势能函数研究

应用群论及原子分子反应静力学的方法, 导出了HNO分子基态电子态和合理的离解极限.利用优选出的密度泛函理论B3LYP方法结合6-311G **优化计算了HNO分子基态的平衡结构和谐振频率.计算结果表明基态HNO分子稳定态为C_S构型,电子组态为X¹A',平衡核间距分别为R_H-N=0.1065 nm,R_N-O=0.1200 nm,键角∠H-N-O=108.60°,离解能D_e=15.379 eV.基态简正振动频率分别为:弯曲振动频率ν₁=1575.6351 cm^-1,对称伸缩振动频率ν₂=1673.2890 cm^-1,反对称伸缩振动频率ν₃=2837.7856 cm^-1.在此基础上,应用多体项展式理论导出了基态HNO分子的全空间解析势能函数,该势能函数等值势能图准确再现了HNO分子平衡结构和离解能. 关键词： 势能函数 光谱常数 密度泛函方法     

本体聚合反应过程中聚甲基丙烯酸甲酯增长自由基的ESR研究

采用TM₁₁₀谐振腔和φ2mm样品管,在17℃室温条件下成功地记录了MMA本体聚合反应过程中增长自由基的ESR谱。当把DMA加入到MMA和BPO中后,立即抽取0.17ml混合液到φ2mm样品管并记谱。以后每隔2分钟记谱一次,波谱从13(5+8)条线逐渐变成9(5+4)条线。我们用阻碍振荡模型和构象重叠模型作了模拟。从全部谱图看,前者似更合理些。ESR实验表明:在聚合过程前期,自由基浓度基本保持不变,但从聚合中期的某一时刻开始,浓度剧增,它正好同步地与本体聚合反应的自加速效应相对应,而且其变化规律和单体转化率相平行。最后,我们用微波功率饱和方法观测到9线谱的协同自旋跳跃所产生的卫线,证明了主导的电子自旋晶格弛豫机理来自电子一核自旋间的偶极偶合角调制。     

液面法超声全息成象的理论分析与实验结果

本文采用傅里叶分析方法,对液面法超声全息成象原理作了较为严格的理论分析,给出了物体束的空间分布为任意函数时,液面起伏的计算公式.并给出了物体束为空间方脉冲时,液面起伏、重现之一级象（即通常称为全息象）,零级象（相应于普通的非全息象）的计算结果,讨论了影响象的强度、畸变、分辨率的因素等问题,对全息象和非全息象的优缺点作了比较。最后,还给出了部分实验结果,其结果与理论计算比较符合。     

一个具有线性约束的Goldfarb方法的改进算法

本文对具有线性约束的非线性规划问题给出一个Goldfarb方法的改进算法,并且在与[1]同样的条件下,给出了算法之超线性收敛性证明.     

On complete integrability of a hierarchy of finite-dimensional Hamiltonian systems

A hierarchy of Hamiltonian systems obtained from the Lax pair of KdV hierarchy under the constraint condition on potentialu = q, q is presented. The independent integrals for these Hamiltonian systems are constructed by using recursion operator and shown to be in involution. Thus this hierarchy of Hamiltonian systems is completely integrable in the sense of Liouville, and they commute with each other.This project is supported by the National Natural Science Foundation of China.     

Periodic Solution of a Nonautonomous Diffusive Food Chain System of Three Species with Time Delays

Abstract By using the continuation theorem of coincidence degree theory,the existence of a positive periodicsolution for a nonautonomous diffusive food chain system of three species. dx_1(t)/dt=x_1(t)[r_1(t)-a_(11)(t)x_1(t)-a_(12)(t)x_2(t)]+D_1(t)[y(t)-x_1(t)], dx_2(t)/dt=x_2(t)[-r_2(t)+a_(21)(t)x_1(t-r_1)-a_(22)(t)x_2(t)-a_(23)(t)x_3(t)], dx_3(t)/dt=x_3(t)[-r_3(t)+a_(32)(t)x_2(t-r_2)-a_(33)(t)x_3(t)], dy(t)/dt=y(t)[r_4(t)-a_(44)(t)y(t)]+D_2(t)[x_1(t)-y(t)]+D_2(t)[x_1(t)-y(t)],is established,where,r_i(t),a_(ii)(t)(i=1,2,3,4),D_i(t)(i=1,2),a_(12)(t),a_(21)(t),a_(23)(t)and a_(32)(t) are all positiveperiodic continuous functions with period w>0,T_i(i=1,2)are positive constants.     

一类非线性椭圆问题的schwarz算法

其中考虑下述泛函最小问题:求u∈W01,α(Ω),使F(u)=     

一类基于变量分离的稳定化混合有限元方法

Based on a seperated model for saddle-point problems, we develop a new sta-bilized mixed finite element method. Such a model consists of two subproblems with respect to the primal and the dual variables, respectively. We show that the new method is coercive and that optimal error bounds hold. As an application,the nearly incompressible elastic problem is analyzed with our method.     

a-CdSe超快光电探测器特性研究

本文报道淀积条件对非晶态硒化镉(a-CdSe)薄膜微区结构的影响,并对利用a-CdSe为光敏介质的超快光电探测器的特性进行了比较深入的测试研究。