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991.
992.
Feng Liu Si Guo Yuan Xiao Li Wang A.E Polikarpov A.A. Shunkevich 《中国化学快报》2007,18(5):588-590
A fibrous sorbent possessing abundant micropore structure was firstly prepared via post-crosslinking reaction on the PP-ST-DVB original fiber. Its micromorphology and sorptive properties were investigated, and the results demonstrated that the novel fibrous hypererosslinked sorbent has narrow pore-size distribution, small average porous radius (1.90 nm), high specific surface area (362.31 m^2/g), and fine sorptive properties for small organic molecules. 相似文献
993.
Horseradish peroxidase catalyzed grafting of acrylamide (AM) onto Kevlar fibers has been studied. The modified fiber has been characterized with scanning electron microscopy (SEM), elemental analysis and the grafting yield. From the SEM micrographs, the surface of the grafted Kevlar fiber is rougher than that of the untreated fiber, and the elemental analysis indicated that the nitrogen content of the treated fibers is higher than that of the untreated fiber. All the results suggested that AM must have been grafted onto the Kevlar surface through HRP-mediated radical initiated grafting reaction. The probably mechanism of HRP catalyzed grafting of AM onto Kevlar surface is proposed. 相似文献
994.
An organic-phase optical phenol biosensor coupling enzymatic oxidation with chemical reduction 总被引:1,自引:0,他引:1
This paper presents a recycle amplification optical biosensor to monitor phenol in hydrophobic organic solvents. Tyrosinase was first immobilised by entrapping it in a copolymer membrane of poly(vinyl alcohol)-hydroxyethyl carboxymethylcellulose doped with octadecylsilica particles. The biosensor was then constructed by co-mixing small particles of the immobilised tyrosinase with the adduct of L-ascorbic acid-poly(vinyl alcohol) (AsA-PVA) in conjunction with an optical oxygen transducer. The biosensor was characterised by its amplifying response to phenol, stable biocatalytic activity of entrapped-tyrosinase, free of interference from o-quinone polymerisation, and large water buffer capacity in hydrophobic organic solvents. The working range of the biosensor to phenol was 0.08-40 mmol dm(-3) in the flow mode. The response times (95%) of the biosensor were 4-7 min for phenol. The operational lifetime was more than 40 assays and the shelf lifetime of the biosensor was longer than 3 months. The biosensor has been successfully applied to quantify the phenol contents in some commercial ointment samples. 相似文献
995.
Jing Xu Yibao Li Lejia Wang Xiaoyang Zhu Xunwen Xiao Yanfang Geng Ke Deng Qingdao Zeng 《中国化学快报》2019,30(3):767-770
Because of the effect of pyridine on the substituent position on the TTF group, TTF derivatives exhibit different assembly structures at the interface, which will be of great significance to the construction of functional nanostructures from the molecular design point of view. 相似文献
996.
用小角X射线散射研究了AOT/水层状溶致液晶的有序性. 通过对散射曲线的解析, 讨论了表面活性剂浓度、温度和助表面活性剂等三个方面对溶致液晶层状相结构有序性的影响. 在一定的范围内, 提高温度, 改变表面活性剂浓度和加入少量助表面活性剂可使碳氢链排列由稀疏转变为密实, 层状相也相应地由“柔性双层”过渡到更加有序化的“平面双层”. 基于形状因子和体系内分子间作用力, 提出了层状相形成与有序化的机理, 同时采用分子模拟的方法展现了不同浓度下的液晶结构. 相似文献
997.
Santi Tungprapa Tanarinthorn Puangparn Monchawan Weerasombut Ittipol Jangchud Porntiva Fakum Somsak Semongkhol Chidchanok Meechaisue Pitt Supaphol 《Cellulose (London, England)》2007,14(6):563-575
This paper reports an investigation of the effects of solvent system, solution concentration, and applied electrostatic field
strength (EFS) on the morphological appearance and/or size of as-spun cellulose acetate (CA) products. The single-solvent
systems were acetone, chloroform, N,N
-dimethylformamide (DMF), dichloromethane (DCM), methanol (MeOH), formic acid, and pyridine. The mixed-solvent systems were
acetone–DMAc, chloroform–MeOH, and DCM–MeOH. Chloroform, DMF, DCM, MeOH, formic acid, and pyridine were able to dissolve CA,
forming clear solutions (at 5% w/v), but electrospinning of these solutions produced mainly discrete beads. In contrast, electrospinning of the solution of
CA in acetone produced short and beaded fibers. At the same solution concentration of 5% (w/v) electrospinning of the CA solutions was improved by addition of MeOH to either chloroform or DCM. For all the solvent systems
investigated smooth fibers were obtained from 16% (w/v) CA solutions in 1:1, 2:1, and 3:1 (v/v) acetone–DMAc, 14–20% (w/v) CA solutions in 2:1 (v/v) acetone–DMAc, and 8–12% (w/v) CA solutions in 4:1 (v/v) DCM–MeOH. For the as-spun fibers from CA solutions in acetone–DMAc the average diameter ranged between 0.14 and 0.37 μm
whereas for the fibers from solutions in DCM–MeOH it ranged between 0.48 and 1.58 μm. After submersion in distilled water
for 24 h the as-spun CA fibers swelled appreciably (i.e. from 620 to 1110%) but the physical integrity of the fibrous structure
remained intact. 相似文献
998.
T. Datta Samanta S. Laskar D. Nayak S. Lahiri 《Journal of Radioanalytical and Nuclear Chemistry》2007,273(2):323-325
Binding ability of mercury, thallium, lead and bismuth with Erythrina variegata seed protein have been investigated using tracer packet technique. Due to the lack of standard methods, inter-comparisons
have been made among three different approaches, like trichloroacetic acid (TCA) precipitation, isoelectric precipitation
and dialysis of protein after incubation with the metals. Good agreement was observed for all the cases except that of lead. 相似文献
999.
Xiao Zhen Liu Fei Wang Dong Dong Luo Xing Guo Guang Qing Lei 《中国化学快报》2007,18(11):1339-1341
The hydroxyl group of carbocyclic nucleosides was inversed when the compounds were treated with Me_3SiCl,KCN and a catalytic amount of NaI in DMF/CH_3CN. 相似文献
1000.
用停止-流动分光光度法研究了Eu~(2+)与二甲酚橙(XO)间快速电子转移反应的动力学规律。求得了速控步骤的动力学参数。如反应级数(n=2)、几个不同温度下的速率常数(k_(278 K)=5.7×10~8 L·mol~-·s~(-1), k_(s38 K)=1.01×10~9 L·mol~(-1)·s~(-1))、活化能(E=7.6×10~3 J·mol~(-1)), 以及指前因子(A=1.5×10~(10) L·mol~(-1)·s~(-1)), 并判断出其为溶液中扩散控制型反应。根据实验现象与测试结果, 提出了Eu~(2+)与XO的反应分别在Eu~(2+)相对过量和在XO过量时的反应机理, 并判断了各反应步骤速率常数之间的相对关系。 相似文献