全文获取类型
收费全文 | 332467篇 |
免费 | 7587篇 |
国内免费 | 3387篇 |
专业分类
化学 | 183843篇 |
晶体学 | 4613篇 |
力学 | 14121篇 |
综合类 | 125篇 |
数学 | 38912篇 |
物理学 | 101827篇 |
出版年
2021年 | 2387篇 |
2020年 | 2807篇 |
2019年 | 2704篇 |
2018年 | 2637篇 |
2017年 | 2524篇 |
2016年 | 4806篇 |
2015年 | 4180篇 |
2014年 | 5483篇 |
2013年 | 15405篇 |
2012年 | 12339篇 |
2011年 | 15040篇 |
2010年 | 9439篇 |
2009年 | 9300篇 |
2008年 | 13539篇 |
2007年 | 13633篇 |
2006年 | 13129篇 |
2005年 | 12005篇 |
2004年 | 10703篇 |
2003年 | 9433篇 |
2002年 | 9343篇 |
2001年 | 10621篇 |
2000年 | 8118篇 |
1999年 | 6515篇 |
1998年 | 5224篇 |
1997年 | 5026篇 |
1996年 | 5083篇 |
1995年 | 4640篇 |
1994年 | 4342篇 |
1993年 | 4098篇 |
1992年 | 4591篇 |
1991年 | 4446篇 |
1990年 | 4127篇 |
1989年 | 3923篇 |
1988年 | 4173篇 |
1987年 | 3838篇 |
1986年 | 3747篇 |
1985年 | 5361篇 |
1984年 | 5425篇 |
1983年 | 4402篇 |
1982年 | 4768篇 |
1981年 | 4804篇 |
1980年 | 4549篇 |
1979年 | 4664篇 |
1978年 | 4665篇 |
1977年 | 4644篇 |
1976年 | 4597篇 |
1975年 | 4510篇 |
1974年 | 4356篇 |
1973年 | 4524篇 |
1972年 | 2569篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
221.
The development of the poly(3‐hydroxybutyrate) (PHB) morphology in the presence of already existent poly(vinylidene fluoride) (PVDF) spherulites was studied by two‐stage solidification with two separate crystallization temperatures. PVDF formed irregular dendrites at lower temperatures and regular, banded spherulites at elevated temperatures. The transition temperature of the spherulitic morphology from dendrites to regular, banded spherulites increased with increasing PVDF content. A remarkable amount of PHB was included in the PVDF dendrites, whereas PHB was rejected into the remaining melt from the banded spherulites. When PVDF crystallized as banded spherulites, PHB could consequently crystallize only around them, if at all. In contrast, PHB crystallized with a common growth front, starting from a defined site in the interfibrillar regions of volume‐filling PVDF dendrites. It formed by itself dendritic spherulites that included a large number of PVDF spherulites. For blends with a PHB content of more than 80 wt %, for which the PVDF dendrites were not volume‐filling, PHB first formed regular spherulites. Their growth started from outside the PVDF dendrites but could later interpenetrate them, and this made their own morphology dendritic. These PHB spherulites melted stepwise because the lamellae inside the PVDF dendrites melted at a lower temperature than those from outside. This reflected the regularity of the two fractions of the lamellae because that of those inside the dendrites of PVDF was controlled by the intraspherulitic order of PVDF, whereas that from outside was only controlled by the temperature and the melt composition. The described morphologies developed without mutual nucleating efficiency of the components. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 873–882, 2003 相似文献
222.
A one-dimensional bulk reaction model for the oxidation of nickeltitanium is formulated, with preferential oxidation of titaniumbeing included. The modelling is directed at the better understandingof the dominant mechanisms involved in the oxidation processand their significance for the biocompatibility of the alloy.Two different regimes for the relative diffusivities of oxygenand the metals are investigated. By assuming fast bulk reactions,different asymptotic structures emerge in different parameterregimes and the resulting models take the form of moving boundaryproblems. Different profiles of nickel concentration are obtained:in particular a nickel-rich layer (observed in practice) ispresent below the oxide/metal interface for the case when oxygenand the metals diffuse at comparable rates. 相似文献
223.
线性泛函方程解的振动性的新结果 总被引:1,自引:0,他引:1
本文研究高阶泛函方程x(g(t))=P(t)x(t)+Q1(t)x(g2(t))+…+Qk(t)x(gk+1(t))解的振动性,得到了一些新的振动条件.改进和推广了已有结果. 相似文献
224.
225.
226.
227.
E. Rodriguez E. Jimenez G.J. Jacob A.A.R. Neves C.L. Cesar L.C. Barbosa 《Physica E: Low-dimensional Systems and Nanostructures》2005,26(1-4):361
Multilayer PbTe quantum dots (QDs) and SiO2 were grown by pulsed laser deposition (PLD) and Plasma enhanced chemical vapor deposition (PECVD) techniques. The crystalline structure, QD size and size dispersion were observed by high-resolution transmission electron microscopy (HRTEM) measurements. This technique allows one to grow PbTe QDs as small as 1.8 nm diameter and 0.6 nm size dispersion. The whole structure can be used in a Fabry–Perot cavity for an optical device operating at the mid-infrared region. 相似文献
228.
J. Stankowski 《Applied magnetic resonance》2004,27(1-2):251-258
Microwave nonresonant dissipation observed around zero field makes a powerful method in characterizing superconducting state (to determineT C,H C1,H CJ parameters). This review shows several successful applications of magnetically modulated microwave absorption (MMMA). MMMA enables to study MgB2 superconducting nanoregions embedded in the Mg host structure. Application of MMMA to study intercalation of fullerence enabled the observation of a new superconducting phase. The pressure effect dT C/dp has been studied below the percolation threshold in YBaCuO/PST composites. The local temperature of the Josephson junction measured by the MMMA technique showed that a granular superconductor consists of two phases: host phase and Josephson junction system. MMMA has been applied lately to separate the giant magnetoresistance from the magnetization effect in differential hysteresis loops. 相似文献
229.
Band bending at the Ni/Si(100)-2×1 interface has been monitored by using Si 2p core level photoemission spectra. Two nickel-induced Si 2p components appear in the initial interaction between Ni and Si(100)-2×1, which is confined at the top surface and the first subsurface layers. At Ni coverage less than 0.0375 ML, Ni atoms prefer the adamantane interstitial sites on the first subsurface, but switch to the pedestal sites on Si dimer rows at higher Ni coverage. The change in the preferred occupation sites of Ni atoms on the Si(100)-2×1 surface strongly affects the amount of band bending shift. The shift towards higher binding energy, when Ni atoms occupy the adamantane interstitial sites, is attributed to metal-induced-gap states. While Ni atoms occupy the pedestal sites, the band bending shift is reduced which is attributed to the passivation of surface states. 相似文献
230.
Fundamentals of the direct measurement of sound intensity and practical applications 总被引:1,自引:0,他引:1
Sound intensity is a measure of the magnitude and direction of the flow of sound energy. Developments in sound intensity measurement capabilities in the last quarter century have occurred because of several reasons. The main ones include the derivation of the cross-spectral formulation for sound intensity and developments in digital signal processing. This paper begins with a brief historical introduction of sound intensity measurements. Then elementary theory for sound intensity is presented. A section on sound intensity measurements is then included. The next section of the paper discusses sources of measurement error; the major sources of error are described in some detail. The paper continues with a discussion of the main applications of sound intensity measurements: sound power determination, noise source identification, and transmission loss measurements. The paper concludes with a discussion of ISO and ANSI intensity related standards and relevant references. 相似文献