首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   21289篇
  免费   3529篇
  国内免费   2580篇
化学   15044篇
晶体学   196篇
力学   1186篇
综合类   138篇
数学   2897篇
物理学   7937篇
  2024年   88篇
  2023年   451篇
  2022年   680篇
  2021年   782篇
  2020年   921篇
  2019年   830篇
  2018年   742篇
  2017年   717篇
  2016年   1073篇
  2015年   1040篇
  2014年   1198篇
  2013年   1575篇
  2012年   1824篇
  2011年   1892篇
  2010年   1343篇
  2009年   1210篇
  2008年   1369篇
  2007年   1199篇
  2006年   1062篇
  2005年   952篇
  2004年   791篇
  2003年   688篇
  2002年   773篇
  2001年   612篇
  2000年   491篇
  1999年   463篇
  1998年   365篇
  1997年   327篇
  1996年   341篇
  1995年   296篇
  1994年   237篇
  1993年   170篇
  1992年   171篇
  1991年   163篇
  1990年   124篇
  1989年   99篇
  1988年   57篇
  1987年   57篇
  1986年   71篇
  1985年   47篇
  1984年   33篇
  1983年   26篇
  1982年   15篇
  1981年   14篇
  1980年   4篇
  1979年   4篇
  1975年   2篇
  1973年   1篇
  1969年   1篇
  1957年   4篇
排序方式: 共有10000条查询结果,搜索用时 8 毫秒
31.
By introducing an imaginary space transform curvature ρs, a complex space called Riemannian space is constructed, in which the light propagating in free space has the trajectory of straight line while propagating. Moreover, this curvature couples with that of the wave front of the paraxial beam ρw, and therefore a complex curvature ρc is constructed, which can be employed to investigate the behavior of the light transmission and to generalize the ABCD law. Project supported by the National Hi-Tech Inertial Confinement Fusion Committee, the Guangdong Natural Science Foundation the Postdoctoral Foundation of Guangdong and National Postdoctoral Foundation of China.  相似文献   
32.
稳态锁模产生4ps激光脉冲   总被引:1,自引:0,他引:1  
朱健强  陈绍和 《光学学报》1994,14(2):83-186
首次利用GaAs光电导开关,控制Nd:YLF激光器腔内Q值,实现稳态锁模,获得脉宽和能量稳定性极高的4ps激光脉冲。  相似文献   
33.
Two new ionone derivatives,named rhododendrone and rhododendronside,were isolated from the alcohoilc extract of the aerial parts of Rhododendron przwalskii Maxim.Their structures were elucidated on the basis of spectroscopic analysis.  相似文献   
34.
35.
首先将无线传感器网络的路由问题转化成求解最小Steiner树问题,然后给出了求解无线传感器网络路由的蚁群优化算法,并对算法的收敛性进行了证明.最后对找到最优解后信息素值的变化进行了分析.即在限制信息素取值的条件下,当迭代次数充分大时,该算法能以任意接近于1的概率找到最优解,并且当最优解找到后,最优树边上的信息素单调增加,而最优解以外边上的信息素在有限步达到最小值.  相似文献   
36.
The reversible addition–fragmentation chain transfer (RAFT) polymerization of acrylonitrile (AN) mediated by 2‐cyanoprop‐2‐yl dithiobenzoate was first applied to synthesize polyacrylonitrile (PAN) with a high molecular weight up to 32,800 and a polydispersity index as low as 1.29. The key to success was ascribed to the optimization of the experimental conditions to increase the fragmentation reaction efficiency of the intermediate radical. In accordance with the atom transfer radical polymerization of AN, ethylene carbonate was also a better solvent candidate for providing higher controlled/living RAFT polymerization behaviors than dimethylformamide and dimethyl sulfoxide. The various experimental parameters, including the temperature, the molar ratio of dithiobenzoate to the initiator, the molar ratio of the monomer to dithiobenzoate, the monomer concentration, and the addition of the comonomer, were varied to improve the control of the molecular weight and polydispersity index. The molecular weights of PANs were validated by gel permeation chromatography along with a universal calibration procedure and intrinsic viscosity measurements. 1H NMR analysis confirmed the high chain‐end functionality of the resultant polymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1272–1281, 2007  相似文献   
37.
38.
The kinetic behaviour of aluminum naphthenate/benzene system in the process of gelation and degradation was systematically studied. The results obtained from the kinetic experiments indicated that the gelation stage was in accordance with a kinetic model of an auto-catalytic first-order reaction, and the degradation stage was a simple first-order reaction. The rate constants in these two stages at various temperaturs were measured. And the determined apparent activation energies for the gelation stage and for the degradation stage are 27.5±2.0 and 37.7±2.3 kJ/mol, respectively.  相似文献   
39.
Characterization of ceramic PVD thin films on AZ31 magnesium alloys   总被引:1,自引:0,他引:1  
Ceramic thin films have been widely used to protect the metal substrate as coatings in the past years. In order to improve the poor corrosion resistance of AZ31 magnesium alloy, the study in this paper used the electron beam evaporation method to prepare ceramic PVD films on its surface with TiO2 and Al2O3 as donors, respectively. Atomic force microscopy (AFM), scanning electron microscope (SEM), energy dispersive X-ray spectrometer (EDS), Auger electron spectroscopy (AES) and X-ray diffraction (XRD) were used to investigate the surface morphology, composition and microstructure of the thin films. Both films deposited on AZ31 took on compact top surface morphologies and grew as amorphous structures on substrate. AES test not only showed that films compositions deviated the standard stoichiometric ratios, but also found that element Mg diffused into films and existed as magnesium oxide in the TiOx film as well as the AlOx film. In the electrochemical corrosion test, the AlOx coating on AZ31 exhibited the largest electrochemical impedance in a 3.5% NaCl solution. But it did not show better corrosion resistance than others for the poorer adhesion. Even if its thickness was small, the TiOx coating on AZ31 exhibited the best corrosion resistance in this study. According to the observation and analysis, the damage of these films on AZ31 in aggressive solutions was mainly due to the existence of pores, microcracks, vacancies and poor adhesion between coating and substrate.  相似文献   
40.
The original article to which this erratum refers was published in Communications on Pure and Applied Mathematics Comm Pure Appl Math(2006)59(5) 626 .  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号