首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   954篇
  免费   34篇
  国内免费   6篇
化学   653篇
晶体学   5篇
力学   15篇
数学   154篇
物理学   167篇
  2023年   16篇
  2022年   12篇
  2021年   27篇
  2020年   16篇
  2019年   22篇
  2018年   24篇
  2017年   22篇
  2016年   37篇
  2015年   25篇
  2014年   32篇
  2013年   56篇
  2012年   58篇
  2011年   77篇
  2010年   45篇
  2009年   56篇
  2008年   57篇
  2007年   59篇
  2006年   58篇
  2005年   63篇
  2004年   31篇
  2003年   38篇
  2002年   37篇
  2001年   8篇
  2000年   14篇
  1999年   8篇
  1998年   6篇
  1997年   8篇
  1996年   12篇
  1995年   9篇
  1994年   7篇
  1993年   7篇
  1992年   4篇
  1991年   3篇
  1990年   3篇
  1989年   6篇
  1988年   4篇
  1987年   2篇
  1986年   2篇
  1984年   4篇
  1983年   4篇
  1981年   1篇
  1980年   2篇
  1979年   2篇
  1977年   1篇
  1976年   1篇
  1975年   2篇
  1974年   1篇
  1971年   2篇
  1970年   1篇
  1925年   1篇
排序方式: 共有994条查询结果,搜索用时 15 毫秒
991.
We show an approximation theorem of Runge type for solutions of the generalized Vekua equation  L u = A u + B u ¯ $Lu = Au + B \overline{u}$ , where L belongs to a class of degenerate elliptic planar vector fields and A , B L p $A,B \in L^{p}$ . To prove the theorem, we make use of an integral representation for the solutions of the generalized Vekua equation valid on relatively compact sets. As an application, we study the global solvability of the equation  L u = A u + B u ¯ + f $Lu = Au + B \overline{u} + f$ with f L p $f \in L^{p}$ and some of its consequences.  相似文献   
992.
Computationally and spectroscopically assisted analytical comparative investigation into the extraction of bisphenol A using three cyclodextrins, that is, α, β, and γ respectively, were performed. A simple, self-tailored μ-solid-phase extraction podium was used to extract bisphenol A from water samples, and high-performance liquid chromatography-ultraviolet was used for the qualitative and quantitative analysis of bisphenol A. Density functional theory first principle calculations, attenuated total reflectance Fourier-transform infrared spectroscopy and Fourier-transform Raman spectroscopy data supports the analytical selection of β-cyclodextrin as the adsorbent for bisphenol A extraction. Analytical optimization of various parameters including sample volume, sample pH, eluting solvent and its volume was performed to discover the most proper conditions for maximum extraction. Under the optimized conditions, a limit of detection value of 0.70 ng/ml and a limit of quantification value of 2.31 ng/ml was achieved with β-cyclodextrin, with recovery (%) values over 98.40–102.50 in real source water samples. Overall, well assisted by comprehensive computational and spectroscopic studies, a novel, simple, sensitive and economic analytical method was developed for the extraction of bisphenol A from source water using cyclodextrin.  相似文献   
993.
Measurements of swelling pressure, neutron spin-echo scattering, and dynamic light scattering were made in an end-linked poly(dimethylsiloxane) (PDMS) gel swollen to equilibrium in a good solvent (toluene) and also in the equivalent solution. The macroscopic osmotic modulus is depressed in the gel. Neutron spin echo observations at intermediate and high values of the scattering vector Q reveal that the mobility of the monomers is unaffected by cross-linking. Elastic neutron scattering at small Q detects non-uniformities in the polymer concentration distribution, which are absent from the solution. These non-uniformities play a major role in the dynamic response of the system at lower Q, and and appear to be the cause of the observed reduction in osmotic pressure.  相似文献   
994.
Macromolecular ligands have been widely used in the past two decades with the objective of preparing structurally defined heterogeneous catalysts from soluble organometallic complexes. This activity has been largely reconsidered and focused on few specific systems. In this connection the present paper reviews recent data concerning the preparation of macromolecular metal complexes derived from transition metals which can produce active catalytic complexes for olefin polymerization and oligomerization and comparison is made about the suitability of both organic resins (crosslinked polystyrene) and inorganic materials (silica, alumina and zeolites).  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号