Red Electroluminescence and Photoluminescence from Novel Binuclear Europium Complex with Squaric Acid Ligand

Organic electroluminescent devices (OELDs) have attracted much attention for several years because of their potential application in large area, multi-colored flat panel displays1-5. The green organic EL display using Alq3 as emitter was commercialized in 19976. However, red-emitting OELD with excellent properties has not been well developed. In order to realize practical full-color OELDs, it is considered very important to develop red and blue emitting materials with excellent propert…     

Cosemisimple Coextensions and Homological Dimension of Smash Coproducts

Let H be a finite dimensional cosemisimple Hopf algebra, C a left H-comodule coalgebra and let C = C/C（H^＊）^＋ be the quotient coalgebra and the smash coproduct of C and H. It is shown that if C/C is a eosemisimple coextension and C is an injective right C-comodule, then gl. dim（the smash coproduct of C and H） = gl. dim（C） = gl. dim（C）, where gl. dim（C） denotes the global dimension of coalgebra C.     

Synthesis and characterization of fluorene‐based rod–coil liquid crystal polymers

A series of fluorene‐based rod–coil liquid crystal polymers with different lengths of the coil segments on backbones were designed and synthesized by a palladium‐catalyzed Suzuki coupling‐reaction. The thermal stability, the UV–Vis absorption and fluorescence spectra in chloroform solution and thin film, the electrochemical properties, thermal behavior, and morphology of these rod–coil polymers were investigated. The thermal stability of these polymers steadily decreased on increasing the length of the coil segments on the backbone; their optical and electrochemical properties did not exhibit noticeable dependence on the weight fraction of the coil segments. However, the shoulder emission and the full width at the half‐maximum (FWHM) in PL spectra of the films increased, whereas the oxidation onset potentials and the corresponding HOMO energy levels decreased with the increase in the weight fraction of the coil segments, which was assigned to microphase separation and formation of folded chain conformation as the weight fraction of the coil segments increased. These polymers displayed a characteristic liquid crystalline texture. The variation of the weight fraction of the coil segments obviously affected the thermal behavior and morphology of these rod–coil polymers. Copyright © 2008 John Wiley & Sons, Ltd.     

Oscillation Theorems of the Second Order Linear Matrix Differential System with Damping

By using the Riccati technique and the technique, new oscillation criteria are obtained for the second order matrix differential system(P(t)Y′(t))′ r(t)P(t)Y′(t) Q(t)Y(t) = 0, t≥t0.These results in the present paper generalize and improve many known conclusions. Furthermore, some results are different from the most known ones in the sense that they are based on the information only on a sequence of subintervals of [t0, ∞), rather than on the whole half-line. In particular, our results complement a number of existing results and handle the ease that is not covered by the known criteria.     

AN INVESTIGATION ON THE INTERACTION MECHANISM OF β-CAROTENE WITH HALOGEN ATOM PRODUCED IN HALOBENZENE BY UV IRRADIATION

ESR measurements using spin trapping technique werecarried out for β-carotene-halobenzene system under UV lightirradiation.The ESR spectra observed in the presence andin the absence of β-carotene are markedly different.Thepossible scheme of β-carotene interacting with halogen atomwas proposed.     

The Synthesis of 2‐(Chromon‐2/3‐yl)‐3‐(5‐thione‐4‐hydro‐1,3,4‐thiadiazol‐2‐yl)‐4‐oxo‐thiazolidine

2‐Formylchromones and 3‐formylchromones as the first materials singly reacted with 2‐amino‐5‐mercapto‐1,3,4‐thiadiazole to give the corresponding Schiff bases, which on cyclocondensation with mercapto‐acetic acid in 1,4‐dioxane yielded target compounds named 4‐oxo‐thiazolidines. The structures of all the synthetic compounds were confirmed by elemental analysis and IR, ¹H NMR, LC‐MS (ESI) spectral data.     

HLS新研制的束流位置探测器定标和误差分析

介绍了NSRL二期工程中,为存储环上注入段真空盒改造而新研制的8组束流位置探测器的定标和数据处理过程及其探头定标电场的拟合和误差计算结果.介绍了专门用于BPM信号处理模块的电子学系统以及它的运行性能.