Reorientation of the large-scale circulation in turbulent Rayleigh-Bénard convection

We present measurements of the orientation theta0(t) of the large-scale circulation (LSC) of turbulent Rayleigh-Bénard convection in cylindrical cells of aspect ratio 1. Theta0(t) undergoes irregular reorientations. It contains reorientation events by rotation through angles delta theta with a monotonically decreasing probability distribution p(delta theta), and by cessations (where the LSC stops temporarily) with a uniform p(delta theta). Reorientations have Poissonian statistics in time. The amplitude of the LSC and the magnitude of the azimuthal rotation rate have a negative correlation.     

Plume motion and large-scale circulation in a cylindrical Rayleigh-Bénard cell

We used the time correlation of shadowgraph images to determine the angle Theta of the horizontal component of the plume velocity above (below) the center of the bottom (top) plate of a cylindrical Rayleigh-Bénard cell of aspect ratio Gamma identical with D/L=1 (D is the diameter and L approximately 87 mm is the height) in the Rayleigh-number range 7 x 10(7)相似文献   

Thermal-noise effect on the transition to Rayleigh-Bénard convection

We report measurements of fluctuation and roll patterns near the transition to Rayleigh-Bénard convection which are consistent with a fluctuation-induced first-order transition, as predicted by Swift and Hohenberg. Above onset, we find convection rolls with noise-induced fluctuations, time-dependent amplitude modulation and roll undulation, and homogeneous dislocation nucleation.     

铅蓄冷材料的二级脉冲管制冷机研究

采用多级方案是高频脉冲管制冷机获得低于20 K以下制冷温度的主要方法,以不锈钢金属丝网为蓄冷材料的二级高频脉冲管制冷机,实验已经达到了20 K以下温度.理论上讲,由于热容大,以铅为主的蓄冷材料比不锈钢更适合40～10 K温区工作,这在低频回热制冷机中得到了证明.本文介绍了我们采用不同铅球和铅网为低温蓄冷材料的研究结果.实验表明,小铅球对于高频脉冲管制冷机是不很合适的,导致制冷温度的明显升高.镀铅的不锈钢丝网和已有不锈钢丝网的性能相似,可进一步深入研究.该研究对于20 K以至更低温度的高频回热制冷机研究有一定的借鉴意义.     

Thiol‐ene photopolymerization for efficient curing of vinyl esters

Monomers for radical photopolymerization based on vinyl esters (VEs) have recently been identified as suitable alternatives to (meth)acrylates on account of their low irritancy and cytotoxicity. The drawback of most VEs with abstractable hydrogens is their relatively low reactivity compared with (meth)acrylates. Within this article, we proved by photo‐differential scanning calorimetry measurements and real‐time Fourier transform infrared spectroscopy that the thiol‐ene concept is able to improve the photoreactivity of these VEs to a large extent to a level between those of acrylates and methacrylates. Other VEs have now a reactivity of at least the level of similar acrylates. Mechanical properties as determined by Dynamic Mechanical Analysis and Charpy impact tests showed significant toughening of these materials. Furthermore, we were able to confirm low toxicity of all components by osteoblast cell culture experiments. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013     

Scheduling periodic customer visits for a traveling salesperson

The problem considered in this paper deals with determining daily routes for a traveling salesperson who provides customers in Upper Austria with product range information of a large, global food wholesaler. Each customer has to be visited at least once a year, with some customers requiring up to one visit per month. Further, some customers may not be visited each day of the week. Our decision support system uses a commercial GIS software to extract customer data for input into the optimization procedure and to visualize the results obtained by the algorithm. The optimization approach is based on the variable neighborhood search algorithm which assigns customers to days and determines routes for the salesperson for each day with the primary objective to minimize the total travel time of the salesperson. Another objective studied is to minimize the number of days needed by the salesperson to visit all customers in a given month. Further we analyze the effects of changes in the business environment like increases in the amount or flexibility of the salesperson’s working time and variations in the possible days for customer visits. Finally, we enrich the objective function by considering periodicity requirements for customer visits. Specifically, we penalize irregular schedules, where the time between two successive customer visits varies.     

CID of singly charged antioxidants applied in lubricants by means of a 3D ion trap and a linear ion trap-Orbitrap mass spectrometer

The aim of this study was to investigate the fragmentation behavior induced by low‐energy collision‐induced dissociation (LE‐CID) of four selected antioxidants applied in lubricants, by two different types of ion trap mass spectrometers: a three‐dimensional ion trap (3D‐IT) and a linear IT (LIT) Orbitrap MS. Two sterically hindered phenols and two aromatic amines were selected as model compounds representing different antioxidant classes and were characterized by positive‐ion electrospray ionization (ESI) and LE‐CID. Various types of molecular ions (e.g. [M]^+?, [M + H]⁺, [M + NH₄]⁺ or [M + Na]⁺) were used as precursor ions generating a significant number of structurally relevant product ions. Furthermore, the phenolic compounds were analyzed by negative‐ion ESI. For both IT types applied for fragmentation, the antioxidants exhibited the same unusual LE‐CID behavior: (1) they formed stable radical product ions and (2) C? C bond cleavages of aliphatic substituents were observed and their respective cleavage sites depended on the precursor ion selected. This fragmentation provided information on the type of structural isomer usually not obtainable for branched aliphatic substituents utilizing LE‐CID. Comparing the two instruments, the main benefit of applying the LIT‐Orbitrap was direct access to elemental composition of product ions enabling unambiguous interpretation of fragmentation trees not obtainable by the 3D‐IT device (e.g. loss of isobaric neutrals). It should be emphasized that the types of product ions formed do not depend on the type of IT analyzer applied. For characterizing degradation products of antioxidants, the LIT‐Orbitrap hybrid system, allowing the determination of accurate m/z values for product ions, is the method of choice. Copyright © 2011 John Wiley & Sons, Ltd.     

The role of cool-flame chemistry in quasi-steady combustion and extinction of n-heptane droplets

Experiments on the combustion of large n-heptane droplets, performed by the National Aeronautics and Space Administration in the International Space Station, revealed a second stage of continued quasi-steady burning, supported by low-temperature chemistry, that follows radiative extinction of the first stage of burning, which is supported by normal hot-flame chemistry. The second stage of combustion experienced diffusive extinction, after which a large vapour cloud was observed to form around the droplet. In the present work, a 770-step reduced chemical-kinetic mechanism and a new 62-step skeletal chemical-kinetic mechanism, developed as an extension of an earlier 56-step mechanism, are employed to calculate the droplet burning rates, flame structures, and extinction diameters for this cool-flame regime. The calculations are performed for quasi-steady burning with the mixture fraction as the independent variable, which is then related to the physical variables of droplet combustion. The predictions with the new mechanism, which agree well with measured autoignition times, reveal that, in decreasing order of abundance, H₂O, CO, H₂O₂, CH₂O, and C₂H₄ are the principal reaction products during the low-temperature stage and that, during this stage, there is substantial leakage of n-heptane and O₂ through the flame, and very little production of CO₂ with no soot in the mechanism. The fuel leakage has been suggested to be the source of the observed vapour cloud that forms after flame extinction. While the new skeletal chemical-kinetic mechanism facilitates understanding of the chemical kinetics and predicts ignition times well, its predicted droplet diameters at extinction are appreciably larger than observed experimentally, but predictions with the 770-step reduced chemical-kinetic mechanism are in reasonably good agreement with experiment. The computations show how the key ketohydroperoxide compounds control the diffusion-flame structure and its extinction.