全文获取类型
收费全文 | 111篇 |
免费 | 0篇 |
专业分类
化学 | 53篇 |
数学 | 9篇 |
物理学 | 49篇 |
出版年
2022年 | 1篇 |
2015年 | 1篇 |
2013年 | 2篇 |
2012年 | 3篇 |
2011年 | 4篇 |
2010年 | 1篇 |
2009年 | 3篇 |
2008年 | 1篇 |
2007年 | 4篇 |
2006年 | 4篇 |
2005年 | 5篇 |
2003年 | 5篇 |
2001年 | 5篇 |
2000年 | 7篇 |
1999年 | 8篇 |
1998年 | 4篇 |
1997年 | 8篇 |
1996年 | 8篇 |
1995年 | 3篇 |
1994年 | 11篇 |
1993年 | 6篇 |
1992年 | 4篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1987年 | 4篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1969年 | 1篇 |
排序方式: 共有111条查询结果,搜索用时 15 毫秒
71.
72.
73.
Alves GA Amato S Anjos JC Appel JA Bracker SB Cremaldi LM Darling CL Dixon RL Errede D Fenker HC Gay C Green DR Jedicke R Kaplan D Karchin PE Kwan S Leedom I Lueking LH Luste GJ Mantsch PM de Mello Neto JR Metheny J Milburn RH de Miranda JM da Motta Filho H Napier A d'Olivera AB Rafatian A dos Reis AC Reucroft S Ross WR Santoro AF Sheaff M Souza MH Spalding WJ Stoughton C Streetman ME Summers DJ Takach SF Wu Z 《Physical review letters》1992,69(22):3147-3150
74.
75.
76.
de Farias RF de Souza JM de Melo JV Airoldi C 《Journal of colloid and interface science》2000,227(1):147-151
Polyaniline deposited on As(2)O(3) surface resulted in a new material, which was characterized by infrared spectoscopy, thermogravimetry, differential scanning calorimetry, scanning electron microscopy, X-ray diffraction, and cyclic voltammetry. The mass percentage of polymer deposited on oxide surface is approximately 13%. The scanning electron microscopy images as well as the X-ray diffraction patterns provided conclusive evidence that the oxide surface is coated by the polymer. The cyclic voltammograms of the polyaniline adsorbed on As(2)O(3) surface showed that the adsorbate exerts remarkable effects on redox processes on this oxide. The pure oxide exhibited two oxidation/reduction peaks at 0.25/-0.06 and 0.47/-0.25 V attributed tentatively to the processes As(2)O(3)(s)+6H(+)+6e(-)=2As(s)+3H(2)O and As(s)+3H(+)+3e(-)=AsH(3)(g), respectively. The polyaniline-coated sample exhibited a better-defined voltammogram in which the first oxidation peak of the oxide had its intensity increased about four times. Copyright 2000 Academic Press. 相似文献
77.
Aitala EM Amato S Anjos JC Appel JA Ashery D Banerjee S Bediaga I Blaylock G Bracker SB Burchat PR Burnstein RA Carter T Carvalho HS Costa I Cremaldi LM Darling C Denisenko K Fernandez A Gagnon P Gerzon S Gobel C Gounder K Granite D Halling AM Herrera G Hurvits G James C Kasper PA Kondakis N Kwan S Langs DC Leslie J Lichtenstadt J Lundberg B Manacero A MayTal-Beck S Meadows B de Mello Neto JR Milburn RH de Miranda JM Napier A Nguyen A d'Oliveira AB O'Shaughnessy K Peng KC Perera LP Purohit MV 《Physical review letters》1996,76(3):364-367
78.
Vladimir Syromyatnikov Tatyana Zheltonozhskaya Jean‐Michel Guenet Iryna Rakovich Ol'ga Demchenko Nikolay Strelchuk Natalya Permyakova 《Macromolecular Symposia》2001,166(1):237-242
The interaction of phenol with graft copolymers of poly(acrylamide) to poly(vinyl alcohol) (PVA‐PAAN) forming intramolecular polycomplexes (Intra PC), and also with PAA, is investigated by the methods of gel chromatography, viscometry, UV and IR spectroscopy. It is shown, that phenol connection with polymers is weak and carried out on the equilibrium mechanism. Under phenol influence the effect of compacting of polymer macromolecules is observed. It is revealed, in particular, by change of the ratio between different H‐bonds structures in polymer films obtained at phenol presence. PVA‐PAAN connect phenol more effectively, than PAA; the quantity of bound phenol grows with N. 相似文献
79.
I review recent progress on the electroweak phase transition and baryogenesis, focusing on the minimal supersymmetric Standard
Model as the source of new physics. 相似文献
80.
JM Pakarinen H Moisio S Holopainen P Vainiotalo 《Rapid communications in mass spectrometry : RCM》1999,13(14):1485-1490
2-Methoxyethanol chemical ionization of amines, carboxylic acids and amino acids has been found to produce numerous adduct ions. The most intense adduct ions for amines are [M + H](+) and [M + 77](+), for carboxylic acids [M + 27](+), [M + 59](+) and [M + 77](+), and for amino acids [M + H](+), [M + 13](+), [M + 27](+) and [M + 77](+). Either the adduct ion [M + H](+) or [M + 77](+) was the most abundant ion found for amino acids. The proton affinities of amino acids are noticed to control the formation of the [M + H](+) and [M + 77](+) ions. The relative abundance of [M + 13](+) and [M + 27](+) ions varied for different amino acids being most intense for phenylalanine and aspartic acid. Copyright 1999 John Wiley & Sons, Ltd. 相似文献