插层化合物LixTiS2中Li离子-空位二维有序结构稳定性的第一性原理研究

根据局域密度近似下的密度泛函理论,用第一性原理方法对TiS2,LiTiS2和LixTiS2(x=1/4,1/3,1/2,2/3,3/4)有序系统进行了几何优化和总能量计算.将计算结果与已有的实验和理论结果进行了对比,得到的归一化结构参量增量△a0和△c0随离子浓度单调地增加,与实验结果符合较好.LixTis2(x=1/4,1/3,1/2,2/3,3/4)有序结构的形成能均小于零,表明这些结构的稳定性.具有√3a0×a0有序结构的Li1/2TiS2系统的形成能最低、结构最稳定.研究结果表明,对上述系统使用局域密度近似下的密度泛函理论是合理的.     

行波光参量过程的理论与实验研究

通过对行波光参量三波耦合过程时域特性的理论计算,预示了光参量时域过程可能存在“弛豫”振荡,理论与实验相结合分析了抽运光强度、晶体长度、腔长、输出耦合系数等一系列参数对参量输出的影响,并采用一种新的棱镜环形腔进行实验,得到从０．４１～２．６ｕｍ的连续宽调谐输出和２２％折能量转换效率。     

三维有序二氧化锰大孔材料的模板技术合成及表征

Using close-packed colloidal crystals-silica as the template,a novel 3D well-ordered and long-ranged periodic macroporous material MnO2 has been prepared by colloidal crystals template methods. The prepared product has been characterized by means of X-ray diffraction（XRD）and scanning electron micrography（SEM）. The X-ray diffraction displays that the phase of MnO2 is tetragonal,and the scanning electron micrography shows that MnO2 replicates the structure of the started template and exhibits 3D long-range ordered honeycomb framework. The process of preparing the 3D order macroporous MnO2 was discussed. The effect of the infiltration times to the final morphology of MnO2 was studied and an abnormity existed in the shrinkage of the final outcome.     

微空心阴极放电推力器性能研究

微空心阴极放电推力器是一种新颖的电热式微推力器,利用纳卫星提供的1~10 W的功率可提高微推进装置的性能。为了预示该推力器的性能,结合实验中测量的气体温度值和火箭发动机原理,初步计算得出微放电推力器的推力范围为几十至上千μN,以氩气为工质比冲量级为600~1 000 N.s/kg,以氦气为工质比冲量级为3 000 N.s/kg。研究结果表明,微空心阴极放电较小的尺寸结构与强烈并可控的气体加热相结合,可以开发应用在电热式微放电推进中,作为微小卫星,尤其是纳卫星和皮卫星的动力系统。     

Fabrication of SiO2 microdisk optical resonator

The silica microdisk optical resonator which exhibits whispering-gallery-type modes with quality factors of 9.67 × 104 is fabricated with photolithographic techniques. Reactive ion beam etching (RIBE) is used to get the silica disks with photoresist masks on SiO2/Si made by standard ultraviolet (UV) photolithography,and spontaneous silicon etching by XeF2 is used to fabricate the silicon micropillars. This fabrication process can control the microcavity geometry, leading to high experiment repeatability and controllable cavity modes. These characteristics are important for many applications in which the microcavity is necessary, such as the quantum gate.     

离子束溅射和离子辅助淀积DWDM滤光片的膜厚均匀性

用离子束溅射和离子辅助淀积技术制备DWDM滤光片的关键问题是必须获得优良的膜层厚度均匀性。采用实验修正膜层厚度修正板的办法获得了较好的均匀性分布 ,给出了实验配置、实验方法和实验结果 ,并对实验结果作了分析讨论     

Global optimization method for maximizing the sum of difference of convex functions ratios over nonconvex region

A global optimization algorithm is presented for maximizing the sum of difference of convex functions ratios problem over nonconvex feasible region. This algorithm is based on branch and bound framework. To obtain a difference of convex programming, the considered problem is first reformulated by introducing new variables as few as possible. By using subgradient and convex envelope, the fundamental problem of estimating lower bound in the branch and bound algorithm is transformed into a relaxed linear programming problem which can be solved efficiently. Furthermore, the size of the relaxed linear programming problem does not change during the algorithm search. Lastly, the convergence of the algorithm is analyzed and the numerical results are reported.     

Existence and uniqueness of solutions for third-order nonlinear boundary value problems

In this paper, we present some general results of existence and uniqueness of solutions of nonlinear two-point boundary value problems for third-order nonlinear differential equations by using the Shooting method. As applications we give certain concrete sufficient conditions for the existence and uniqueness.     

基于主成分变换的图像稀疏度估计方法

压缩感知理论基于信号的稀疏性和可压缩性, 突破传统Nyquist采样频率的限制, 以较低的数据量对信号进行采样和高概率重构. 在压缩感知理论中, 信号的稀疏度确定了稀疏采样的最低数据量, 是验证采样方法及重构方法优劣的重要参数. 在实际研究过程中, 图像稀疏度通常未知, 这就可能导致过采样或欠采样的情况, 从而无法验证采样方法及重构方法的优劣. 因此, 快速而客观地估计图像的稀疏度对于压缩感知理论研究来说意义重大. 本文分析了基于小波变换的图像稀疏化表示方法, 通过遍历采样和重构得到基于小波变换方法的图像稀疏度, 但过程复杂, 而且结果的准确性依赖于小波基和变换尺度的选择. 本文通过压缩感知理论对主成分变换进行阐述, 在基于主成分变换系数近似为正态函数的假设下, 建立了图像稀疏度与系数函数方差间的线性关系, 并通过多组图像数据进行仿真验证, 结果表明线性关系的正确性. 通过分析和仿真可以看出, 基于主成分变换的稀疏度估计方法比小波变换简单、快速、客观, 对压缩感知理论研究有重要的应用价值. 关键词： 压缩感知 稀疏度 小波变换 主成分变换     

Synthesis and Bioactivities of Novel N‐(4‐(2‐Aryloxythiazol‐5‐yl)but‐3‐yn‐2‐yl)benzamides

A series of novel N‐(4‐(2‐aryloxythiazol‐5‐yl)but‐3‐yn‐2‐yl)benzamide derivatives were designed and synthesized. Their structures were identified by ¹H NMR and elemental analyses. Preliminary bioassays indicated that some title compounds provided >80% control of Sclerotinia sclerotiorum at 50 µg/mL and >70% herbicidal activities against B. campestris at 100 µg/mL. Their structure‐activities relationships were also discussed.