卟啉和金属卟啉的荧光研究

本文研究了四-(邻氯苯基)卟吩,几种天然卟啉以及它们的金属络合物的室温荧光光谱,荧光量子产额和计算了辐射寿命。初次得到了Mg(OClTPP)和Cd(OClTPP)的量子产额,Cd(OClTPP)的荧光产额比Cd(TPP)的数值大很多。出现了类似文献已报导过的Zn(OClTPP)的反常现象,此现象解释为邻氯取代基削弱了锌的重原子效应.     

动态特性的参数设计在差示光度法测金中的应用

本文提出对动态特性参数设计使用相关系数与信噪比作为内表指标进行分析 ,并使用该分析方法优化了差示光度法测较高浓度金矿样的试验条件。     

荧光粉相对亮度测量的色修正

由于很难将光接收器的相对光谱灵敏度S(λ)调到与CIE标准观察者V(λ)完全一致,不同荧光份又具有不同的相对光谱功率分布,因此测量荧光粉的相对亮度与测量其它光度量一样,必须进行色修正。本工作针对实际使用的光接收器和相对光谱功率分布不同的几种荧光粉的相对亮度计算了色修正系数。     

A genetic resampling particle filter for freeway traffic-state estimation

On-line estimation of the state of traffic based on data sampled by electronic detectors is important for intelligent traffic management and control.Because a nonlinear feature exists in the traffic state,and because particle filters have good characteristics when it comes to solving the nonlinear problem,a genetic resampling particle filter is proposed to estimate the state of freeway traffic.In this paper,a freeway section of the northern third ring road in the city of Beijing in China is considered as the experimental object.By analysing the traffic-state characteristics of the freeway,the traffic is modeled based on the second-order validated macroscopic traffic flow model.In order to solve the particle degeneration issue in the performance of the particle filter,a genetic mechanism is introduced into the resampling process.The realization of a genetic particle filter for freeway traffic-state estimation is discussed in detail,and the filter estimation performance is validated and evaluated by the achieved experimental data.     

表面极化对弱锚定向列液晶盒饱和特性的影响

以修正后的Rapini-Papoular锚定能公式为基础, 用理论分析和数值计算相结合的方法, 详细研究表面极化对液晶盒饱和特性的影响. 得出了求解指向矢分布的数学方程, 推导出了计算正常二级转变饱和电压的解析式, 同时结合最新报道, 给出了异常一级转变饱和电压的数值计算方法. 此外, 本文引入了反映指向矢分布特征的参量, 讨论了表面极化对此参量的影响. 结果表明, 指向矢最大倾角的位置随表面极化的增大将远离中央平面向基板移动. 一级转变饱和电压随弱锚定基板表面极化的增大而减小, 随强锚定基板表面极化的增大而增大. 而对二级转变, 饱和电压随表面极化的变化与一级转变恰恰相反. 本文所得结论对液晶表面物理的理解及液晶实际应用都具有重要的指导意义.     

Analysis and optimization of a new photonic crystal filters in near ultraviolet band

Transmission characteristics of one-dimensional (1D) photonic crystals (PCs) heterostructures containing defective are studied using the transfer matrix method. The key is to search the best combination style for different 1D PCs to form heterostructures. It is shown that the non-transmission range over near ultraviolet and visible range can be substantially enlarged and the phenomenon of narrow band PC filter in near ultraviolet can be realized by adjusting the repeat cycle counts of various photonic crystals. The theoretical results on multiple heterostructures containing TiO₂/SiO₂ multilayer films are presented. With a perfect omni-directional and high peak transmission filters for TE modes, this structure opens a promising way to fabricate ultra-narrow band PC filters with wide non-transmission range in near ultraviolet and visible range.     

Discovery of structurally diverse natural product antagonists of chemokine receptor CXCR3

The chemokines (CXCL9, CXCL10 and CXCL11) and associated CXCR3 receptor are expressed during the inflammatory process from multiple sclerosis, atherosclerosis or organ transplantation resulting in the recruitment of lymphocytes leading to tissue damage. It is hypothesized that blocking of the ligand/CXCR3 receptor interaction has potential to provide opportunity for development of agents that would block tissue rejection. In this paper, four classes of natural product inhibitors (IC₅₀ ranging 0.1–41 M) have been described that block the CXCR3 receptor interaction of IP-10 ligand. These include a cyclic thiopeptide (duramycin), polyketide glycosides (roselipins), steroidal glycosides (hypoglausin A and dioscin) and a novel alkyl pyridinium alkaloid that were isolated by bioassay-guided fractionation of the organic extracts derived from actinomycete, fungal, plant and marine sources and discovered using ¹²⁵ I IP-10/CXCR3 binding assay. Duramycin was the most potent with an IC₅₀ of 0.1 M. Roselipins 2A, 2B and 1A showed IC₅₀ values of 14.6, 23.5, and 41 M, respectively. Diosgenin glycosides dioscin, hypoglaucin A and kallstroemin D exhibited IC₅₀ values of 2.1, 0.47 and 3 M, respectively. A novel cyclic 3-alkyl pyridinium salt isolated from a sponge displayed a binding IC₅₀ of 0.67 M.     

Preliminary test results of LAr prototype detector

Liquid argon (LAr) is an attractive target for the direct detection of WIMPs. A LAr prototype detector was designed to study the technology and properties of LAr detectors. The prototype detector had an active volume containing 0.65 kg of liquid argon. A liquid nitrogen (LN) cooling system allowed the temperature fluctuation of the liquid argon to be controlled within less than 0.1 K during a one month run. In the ²²Na calibration run, the LAr prototype obtained 1.59±0.02 p.e./keV light yield for 511 keV gamma rays using a domestic-made argon purification system.     

Recursive weighted treelike networks

We propose a geometric growth model for weighted scale-free networks, which is controlled by two tunable parameters. We derive exactly the main characteristics of the networks, which are partially determined by the parameters. Analytical results indicate that the resulting networks have power-law distributions of degree, strength, weight and betweenness, a scale-free behavior for degree correlations, logarithmic small average path length and diameter with network size. The obtained properties are in agreement with empirical data observed in many real-life networks, which shows that the presented model may provide valuable insight into the real systems.     

Electrostatic discharge effect on safe distance determination for 500 kV ac power line's helicopter inspection

The effect of electrostatic discharge on safe distance determination for 500 kV ac transmission line's helicopter inspection is investigated. Potential difference exists while helicopter is near the power transmission line, which is harmful to the inspection persons. The electric field in the helicopter cabin is calculated when it is near the power line. The result indicates that the potential difference becomes higher with the decrease of the distance between the helicopter and transmission line. Considering the discharge energy and the guarantee of the persons' safety, the safe distance for 500 kV ac transmission lines is determined as d ≥ 15 m.