VISCOELASTICITY AND IONIC CONDUCTIVITY OF TWO-COMPONENT EPOXY NETWORK CONTAINING LITHIUM PERCHLORATE*

Polymeric solid electrolyte system composed of triglycidyl ether of glycerol (TGEG), diglycidyl ether of polyethylene glycol (DGEPEG)and LiClO_4 salt were synthesized. In this" system the electrolyte has a pecularity that not merely can the LiClO_4 provide ionic carriers, but also catalyze the crosslinking reaction without adding an usual curing agent. The effect of salt content and degree of crosslinking on the viscoelasticity and ionic conductivity were studied. Both WLF and VTF equations were used to treat the experimental data in order to elucidate the mechanism of ionic conduction. It was found that the ionic conductivity of the system is carded out through the segmental motion mechanism. However, the data must be treated with care. For example, in evaluating WLF parameters, the contribution concerned with ionic carrier generation with temperature to the conductivity must be differentiated from that concerned with segmental motion. Besides, the temperature range suitable to WLF equation must also be considered. For VTF equation, it might be inapplicable ff the temperature is too low and close to the glass transition temperature of the specimen. Further study is needed in order to have a quantitative information on the limitation of these equations.     

Enhanced detection of seven glucoconjugated and hydroxylated porphyrins and chlorins by nonaqueous capillary electrophoresis combined with stacking

The nonaqueous capillary electrophoresis mode which includes a preconcentration step based on a transient pseudo-isotachophoresis to the simultaneous separation of seven glucoconjugated and hydroxylated porphyrins and chlorins, exhibiting very close structures, is reported. A high methanol content, of the buffer solution, was necessary in order to prevent self-assembly of the compounds and to enhance their solubility during separation. With the addition of 66% (v/v) methanol and 1% (w/v) NaCl in the aqueous sample solution, large volumes could be injected (44% capillary volume) without a loss in resolution. Sensitivity of detection was therefore improved by a 100-fold factor with regard to the method employing normal injection (2% capillary volume). Optimum electrophoretic conditions, in terms of sensitivity and performance, were obtained by using 20 mM phosphoric acid buffer, pH 2.2 and 50% methanol. The method was validated and applied to qualitative analysis of glucoconjugates in serum samples.     

New Preparation Methodology of Functionalized Picolines

Under the organomagnesium complex n‐Bu₂CH₃MgLi conditions, picoline compounds provide a new entry to a broad range of polyfunctional picoline derivatives, after reaction with various electrophiles.     

碱土金属硫化物光激励材料在辐射剂量测量中的应用

采用碳还原法合成了掺杂两种稀土金属离子的碱土金属硫化物光激励发光材料,并对光激励发光材料的辐射剂量特性进行了研究。将材料做成PMMA剂量片在60Coγ源下接受辐照,然后用自己搭建的在线实时测试系统对剂量片发出的荧光信号进行测量。实验发现碱土金属硫化物光激励发光材料在0.01～1 000 Gy内,有很好的辐射剂量响应范围(5个剂量级),荧光信号峰值强度与辐照剂量线性关系良好,说明碱土金属硫化物光激励发光材料在辐射剂量测量中有着很好的应用前景。文章主要探讨了碱土金属硫化物光激励发光材料在辐射剂量测量中的应用。     

脉冲电流作用下LY12铝合金的微观结构和合金元素分布

研究了在凝固过程中施加脉冲电流对LY12铝合金微观结构和合金元素分布的影响.实验结果表明,在脉冲电流作用下,LY12合金的微观结构发生了明显变化,聚集在晶界和枝晶网的共晶组织大大减少,网络变得不连续,在晶内和晶界附近存在弥散的近似球状的共晶质点.另外,脉冲电流能有效地改善合金中Cu和Mg的成分偏析,其中对Cu在Al合金中的负偏析现象的改善更为显著,使Cu较均匀地分布于整个试样. 关键词： LY12铝合金 脉冲电流 显微结构 偏析     

单组分桥联茂基二异丙胺基钕配合物催化甲基丙烯酸甲酯聚合

催化聚合;茂稀土胺化物;单组分桥联茂基二异丙胺基钕配合物催化甲基丙烯酸甲酯聚合     

化学教学中应如何培养学生的问题意识

当前,中学生问题意识较差,不能发现并提出问题。这种状况不能适应新课程改革的需要。笔者总结自己在化学教学中培养学生问题意识的几种做法：唤醒“问”的意识,使学生想问;营造“问”的氛围,使学生敢问;创设“问”的情境,使学生能问;传授“问”的技巧,使学生会问;教师要正确面对学生的提问。     

Bi3.25Nd0.75Ti3O12纳米结构: 可控合成及其可见光催化活性

用水热法制备不同形貌的掺钕钛酸铋(Bi3.25Nd0.75Ti3O12,BNdT)纳米粉体.透射电子显微镜(TEM)结果表明,通过控制OH-浓度可以得到不同形貌的纳米粉体.基于不同条件下制备的样品微结构分析,提出了这些不同形貌的形成机制.紫外-可见漫反射光谱(UV-Vis DRS)表明BNdT样品的带隙能(Eg)约为1.984 eV.利用可见光照射下甲基橙降解实验评价了BNdT样品的光催化性能.结果表明,BNdT的光催化活性比商用TiO2催化剂P25和掺氮TiO2高得多.OH-浓度为10 mol·L-1时制备的BNdT纳米线光催化效率最高,经可见光照射360min,浓度为0.01 mmol·L-1甲基橙溶液的降解率可达到93.0%,且循环使用4次后,其光催化活性并没有明显降低,表明BNdT是一种稳定有效的可见光催化剂.