全文获取类型
收费全文 | 782篇 |
免费 | 54篇 |
国内免费 | 4篇 |
专业分类
化学 | 579篇 |
力学 | 12篇 |
数学 | 103篇 |
物理学 | 146篇 |
出版年
2023年 | 9篇 |
2022年 | 14篇 |
2021年 | 9篇 |
2020年 | 18篇 |
2019年 | 22篇 |
2018年 | 8篇 |
2017年 | 12篇 |
2016年 | 38篇 |
2015年 | 31篇 |
2014年 | 27篇 |
2013年 | 45篇 |
2012年 | 41篇 |
2011年 | 70篇 |
2010年 | 38篇 |
2009年 | 42篇 |
2008年 | 49篇 |
2007年 | 26篇 |
2006年 | 42篇 |
2005年 | 31篇 |
2004年 | 36篇 |
2003年 | 20篇 |
2002年 | 19篇 |
2001年 | 13篇 |
2000年 | 15篇 |
1999年 | 11篇 |
1998年 | 7篇 |
1997年 | 6篇 |
1996年 | 9篇 |
1995年 | 5篇 |
1992年 | 5篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1985年 | 3篇 |
1983年 | 4篇 |
1982年 | 3篇 |
1980年 | 4篇 |
1978年 | 4篇 |
1977年 | 10篇 |
1976年 | 4篇 |
1975年 | 6篇 |
1969年 | 3篇 |
1934年 | 4篇 |
1927年 | 3篇 |
1926年 | 3篇 |
1925年 | 3篇 |
1924年 | 3篇 |
1923年 | 5篇 |
1899年 | 4篇 |
排序方式: 共有840条查询结果,搜索用时 62 毫秒
101.
102.
Hill NJ Reeske G Moore JA Cowley AH 《Dalton transactions (Cambridge, England : 2003)》2006,(40):4838-4844
The new Ar-BIAN complexes [(mes-BIAN)InCl(3)(THF)] (1), [(mes-BIAN)(2)Tl][PF(6)] (2), [(dipp-BIAN)SnCl(4)] (3), [(dipp-BIAN)SbCl(3)] (4), [(dipp-BIAN)BiCl(3)] (5) and [(mes-BIAN)BiCl(3)] (6) have been prepared by treatment of the neutral mes- and dipp-substituted BIAN ligands with the p-block reagents InCl(3), TlPF(6), SnCl(4), SbCl(3), and BiCl(3). The molecular structures of complexes 1-6 have been determined by single-crystal X-ray diffraction methods. However, only the atom connectivity was established for 5. 相似文献
103.
Reduction of AsCl3 with SnCl2, followed by treatment of the "AsCl" with a 1,4-diimine results in electron transfer and formation of an arsenic(III) salt, while treatment of this arsenic(I) reagent or AsI3 with an alpha,alpha'-diiminopyridine ligand forms an arsenic(I) salt. 相似文献
104.
105.
We provide a characterization in terms of Fatou closedness for weakly closed monotone convex sets in the space of \({\mathcal P}\)-quasisure bounded random variables, where \({\mathcal P}\) is a (possibly non-dominated) class of probability measures. Applications of our results lie within robust versions the Fundamental Theorem of Asset Pricing or dual representation of convex risk measures. 相似文献
106.
Floreano L Cossaro A Cvetko D Bavdek G Morgante A 《The journal of physical chemistry. B》2006,110(10):4908-4913
We studied the growth of pentacene (C22H14) on the Au(110) surface by means of He atom scattering and Synchrotron X-ray photoemission. We found that two-dimensional commensurate growth only occurs in the monolayer range for a substrate temperature, T(s), higher than approximately 370 K. Larger amounts of deposited molecules forms three-dimensional uncorrelated clusters on the wetting layer. The desorption of second layer molecules occurs at T(s) > or = 420 K. The highest coverage ordered phase displays a (6 x 8) symmetry and corresponds to the saturation coverage at T(s) = 420 K. The (3 x 6) symmetry phase, recently reported for a multilayer planar film [Ph. Guaino, et al. Appl. Phys. Lett. 2004, 85, 2777], is only found at a coverage slightly lower than the (6 x 8) one. The (3 x 6) phase corresponds to the saturation coverage of the first layer at T(s) = 470 K. 相似文献
107.
108.
Gregor Svindland 《Mathematics and Financial Economics》2010,3(1):39-43
We study continuity properties of law-invariant (quasi-)convex functions \({f:L^\infty(\Omega, \mathcal{F}, \mathbb{P}) \to (-\infty,\infty]}\) over a non-atomic probability space \({(\Omega, \mathcal{F}, \mathbb{P})}\). This is a supplementary note to Jouini et al. (Adv Math Econ 9:49–71, 2006). 相似文献
109.
110.
Simon Smolders Tom Willhammar Andra Krajnc Kadir Sentosun Michael T. Wharmby Kirill A. Lomachenko Sara Bals Gregor Mali Maarten B. J. Roeffaers Dirk E. DeVos Bart Bueken 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(27):9258-9263
While titanium‐based metal–organic frameworks (MOFs) have been widely studied for their (photo)catalytic potential, only a few TiIV MOFs have been reported owing to the high reactivity of the employed titanium precursors. The synthesis of COK‐47 is now presented, the first Ti carboxylate MOF based on sheets of TiIVO6 octahedra, which can be synthesized with a range of different linkers. COK‐47 can be synthesized as an inherently defective nanoparticulate material, rendering it a highly efficient catalyst for the oxidation of thiophenes. Its structure was determined by continuous rotation electron diffraction and studied in depth by X‐ray total scattering, EXAFS, and solid‐state NMR. Furthermore, its photoactivity was investigated by electron paramagnetic resonance and demonstrated by catalytic photodegradation of rhodamine 6G. 相似文献