Spin relaxation due to polar optical phonon scattering

Spin relaxation due to polar optical phonon scattering in semiconductors was investigated. The relaxation of the electron spin was found to increase with increasing the strength of the electric field. However, a high field completely depolarized the electron spin due to an increase of the spin precession frequency of the hot electrons, suggesting that high field transport conditions might not be desirable for spin-based technology with these semiconductors. It was also found that spin relaxation decreases with increasing moderately n-doping density or decreasing temperature. The results were discussed in comparison with the data available in the literature.     

Spectroscopic and redox properties of amine-functionalized K2[OsII(bpy)(CN)4] complexes

We report the first examples of amine-functionalized K(2)[Os(II)(bpy)(CN)(4)] (bpy = 2,2'-bipyridine) complexes. The tetracyanoosmate complexes were prepared by UV irradiation (λ = 254 nm) of K(4)[Os(II)(CN)(6)] and primary amine-functionalized bpy ligands in acidic aqueous media. The aqueous solution pH dependences of the spectroscopic and redox properties of 4,4'- and 5,5'-substituted complexes have been investigated. The pendant amine functional groups and coordinated cyanide ligands are basic sites that can be sequentially protonated, thereby allowing systematic tuning of electrochemical and optical spectroscopic properties.     

Homological finiteness properties of monoids, their ideals and maximal subgroups

We consider the general question of how the homological finiteness property left-(resp. right-) holding in a monoid influences, and conversely depends on, the property holding in the substructures of that monoid. This is done by giving methods for constructing free resolutions of substructures from free resolutions of their containing monoids, and vice versa. In particular, we show that left- is inherited by the maximal subgroups in a completely simple minimal ideal, in the case that the minimal ideal has finitely many left ideals. For completely simple semigroups, we prove the converse, and as a corollary, show that a completely simple semigroup is of type left- and right- if and only if it has finitely many left and right ideals and all of its maximal subgroups are of type . Also, given an ideal of a monoid, we show that if the ideal has a two-sided identity element then the containing monoid is of type left- if and only if the ideal is of type left-. Applying this result, we obtain necessary and sufficient conditions for a Clifford monoid (and more generally a strong semilattice of monoids) to be of type left-. Examples are provided showing that for each of the results all of the hypotheses are necessary.     

Generators and relations for subsemigroups via boundaries in Cayley graphs

Given a finitely generated semigroup S and subsemigroup T of S, we define the notion of the boundary of T in S which, intuitively, describes the position of T inside the left and right Cayley graphs of S. We prove that if S is finitely generated and T has a finite boundary in S then T is finitely generated. We also prove that if S is finitely presented and T has a finite boundary in S then T is finitely presented. Several corollaries and examples are given.     

Biridoside,A New Iridoid from Buddleja davidii

The methanolic extract of fresh and dried leaves of Buddleja davidii furnished a new iridoid glycoside, along with other known compounds. Spectroscopic techniques were utilized for the characterization of biridoside.     

The coalescence of polystyrene in correlated binary solvents

The solution behavior of solvophobic polymers is crucial to the development of polymer coatings and polymeric drug delivery vehicles. In this article, the role of dipolar interactions is investigated in the solvophobic coalescence of polystyrene in binary correlated polar solvent mixtures. A simple model for coalescence thermodynamics is derived from correlations between thermally rotating dipole moments in the solvent. The stabilizing correlations lost to the solvent due to a solute's presence give rise to a driving force for the coalescence of solutes. This stabilization is offset by the entropy of mixing that favors the dispersion of solutes. Predictions are compared to the measured point of coalescence of polystyrene in acetone when different alcohols are titrated. The model is shown to capture this point of coalescence and conformation for a variety of systems. Our results suggest the significant property determining the solubility of nonpolar polymers in a polar liquid is a free energy resulting from attractive dispersion interactions between thermally rotating solvent dipole moments. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 948–955     

Recommendation for The Use of The Code Letters G And H for Smectic Phases

As a result of the confused situation that has arisen over the years with regard to the nomenclature of smectic G and H phases, the above authors felt that it would be useful to publish the following letter recommending how these phases should be donominated in the future.